Preparation of glass/plastic laminates having improved optical quality

• US 5,631,089 A
• Filed: 03/10/1994
• Issued: 05/20/1997
• Est. Priority Date: 07/30/1991
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Smith, Charles A., Center, Jr., Luther W.
• Primary Examiner(s): Nakarani, D. S.
• Application Number:
  US08/185,913
• Time in Patent Office: 1,167 Days
• Field of Search: 156/99, 156/102, 156/106, 156/289, 156/323, 428/436, 428/437, 428/438, 428/908.8
• US Class Current: 428/437
• CPC Class Codes: B32B 17/10018 comprising only one glass sheet
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 17/10816 by pressing
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: Y10T 428/31627 Next to aldehyde or ketone condensation product
• CPC Class Codes: Y10T 428/3163 Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.]
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers

Abstract

A glass/plastic laminate useful in glazing applications which has improved optical quality is provided by controlling the incidence of optical defects induced during manufacture by particulate contaminates by applying a soft plastic film to the outboard side of the plastic surface of the laminate and entrapping such contaminates during the lamination process in the soft plastic film.

Claims

1. A process for controlling optical defects induced by particulate contaminates during the preparation of a glass/plastic surfaced laminate wherein heat and pressure are applied to a coverplate and a receiving glass to bond elements of said laminate comprising

a) forming a composite structure having surfaces comprised of outboard surfaces of a receiving glass and an abrasion resistant polymeric film with an adhesive material there between,

b) releasably adhering a plastic film of uniform thickness to the outboard surface of said abrasion resistant polymeric film, said plastic film being softer than said abrasion resistant polymeric film and when heated and placed under pressure, deforming to receive and entrap any particulate contaminates on the outboard surface of said abrasion resistant polymeric film,

c) positioning a coverplate over said composite structure, in contact with said plastic film, and

d) applying sufficient heat and pressure to said coverplate and said receiving glass to bond the elements of said composite structure and permit deformation of said plastic film to entrap particulate contaminants present between the outboard surface of said abrasion resistant polymeric film and said coverplate in said plastic film while maintaining the optical integrity of the surface of said abrasion resistant polymeric film.

2. The process of claim 1 wherein said plastic film is releasably adhered to the outboard surface of said abrasion resistant polymeric film by a pressure sensitive adhesive.

3. The process of claim 1 wherein said plastic film is polyethylene.

4. The process of claim 1 wherein said abrasion resistant polymeric film is polyethylene terephthalate and said adhesive material is polyvinyl butyral.

5. The process of claim 1 wherein said plastic film is adhered by coating a continuous film of a plastic material onto the outboard surface of said abrasion resistant polymeric film.

6. A composite glass/plastic laminated structure comprising a layer of glass having bonded to its inboard surface an abrasion resistant polymeric film and a plastic film, said plastic film being of uniform thickness, softer than said abrasion resistant polymeric film and releasably adhered to the outboard surface of said abrasion resistant polymeric film, said plastic film when heated and placed under pressure deforming to receive and entrap any particulate contaminates present on the outboard surface of said abrasion resistant polymeric film.

7. A laminated structure of claim 6 wherein said plastic film is polyethylene.

8. A laminated structure of claim 6 wherein said abrasion resistant polymeric film is polyethylene terephthalate.

9. A laminated structure of claim 6 wherein said glass layer is bonded to said abrasion resistant polymeric film by a film of polyvinyl butyral.