Ammonia removal

• US 5,635,077 A
• Filed: 06/06/1995
• Issued: 06/03/1997
• Est. Priority Date: 04/29/1993
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Bice, Danford L., Stultz, Jeffrey H.
• Primary Examiner(s): Manoharan, Virginia
• Application Number:
  US08/469,796
• Time in Patent Office: 728 Days
• Field of Search: 210/750, 210/903, 210/613, 210/739, 210/743, 95/263, 95/265, 95/266, 203/20, 203/49, 203/39, 203/88, 203/89, 203/1, 159/48.1, 423/237, 423/356
• US Class Current: 210/750
• CPC Class Codes: B01D 3/28 Fractionating columns with surface contact and vertical guides, e.g. film action
• CPC Class Codes: C02F 1/586 by removing ammoniacal nitrogen for biological methods C02F3/00
• CPC Class Codes: Y10S 210/903 Nitrogenous

Abstract

A method for stripping ammonia from a film of digested sludge including flowing alkaline liquid sludge as a film on a tower'"'"'s interior wall and flowing an ammonia stripping gas past the film creating a vapor containing ammonia and stripping gas; then disengaging the liquid sludge from the vapor in a tower disengaging zone.

Claims

1. A method for removing ammonia from liquid sludge containing ammonia and suspended solids, the method comprising

flowing the liquid sludge to an interior wall of an interior of a hollow stripping tower forming a flowing film of sludge on the interior wall, with the tower being at a positive pressure and with liquid sludge being supplied to the tower such that a wash rate is maintained in the tower of at least 5000 pounds per hour per foot of stripping tower periphery,

flowing stripping gas past the film, stripping ammonia from the liquid sludge into the stripping gas, and

disengaging liquid sludge from the stripping gas in a disengaging zone in the stripping tower, producing disengaged liquid sludge,

flowing the stripping gas upwardly in the stripping tower, and

flowing the liquid sludge downwardly in the stripping tower.

2. The method of claim 1 further comprising prior to flowing the liquid sludge to the tower

feeding the liquid sludge to a tank which is in fluid communication with the stripping tower,

agitating the liquid sludge in the tank, and then

feeding the liquid sludge to the stripping tower.

3. The method of claim 2 further comprising

flashing the liquid sludge into the tank producing stripping gas for the stripping tower.

4. The method of claim 2 further comprising

adjusting the pH of the liquid sludge in the tank.

5. The method of claim 4 further comprising

adjusting the pH to at least 9.

6. The method of claim 2 further comprising

pumping the liquid sludge from the tank.

7. The method of claim 1 wherein the sludge is digested denatured liquid sludge.

8. The method of claim 1 further comprising

venting stripping gas containing ammonia stripped from the liquid sludge in the stripping tower, through a vent in communication with the stripping tower interior.

9. The method of claim 8 further comprising

discharging the disengaged liquid sludge from the stripping tower and

recycling the disengaged liquid sludge back to the stripping tower for further stripping of ammonia.

10. The method of claim 9 wherein at least 99% by weight of the ammonia initially present in the liquid sludge fed to the stripping tower is removed by means of the vented stripping gas.

11. The method of claim 8 wherein at least about 15% by weight of the ammonia present in the liquid sludge fed to the stripping tower is removed by means of the vented stripping gas.

12. The method of claim 1 further comprising

sensing ammonia concentration level of the disengaged liquid sludge and pH thereof.

13. The method of claim 1 further comprising

flowing the liquid sludge to the interior wall of the stripping tower with a sludge distributor, and

inhibiting foaming and sticking in the stripping tower by having no internal devices in the stripping tower below the sludge distributor.

14. The method of claim 1 which is characterized by a stripping gas residence time in the stripping tower of at least 5 seconds.

15. The method of claim 14 wherein the residence time is between about 10 to about 20 seconds.

16. A method for removing ammonia from liquid sludge containing ammonia and suspended solids, the method comprising

flowing the liquid sludge to an interior wall of an interior of a stripping tower forming a flowing film of sludge on the interior wall, with the tower being at a positive pressure and with liquid sludge being supplied to the tower such that a wash rate is maintained in the tower of at least 5000 pounds per hour per foot of stripping tower periphery,

flowing stripping gas past the film, stripping ammonia from the liquid sludge into the stripping gas, and

disengaging liquid sludge from the stripping gas in a disengaging zone in the stripping tower, producing disengaged liquid sludge,

flowing the stripping gas upwardly in the stripping tower,

flowing the liquid sludge downwardly in the stripping tower,

flowing the liquid sludge to the interior wall of the stripping tower with a sludge distributor, and

inhibiting foaming and sticking in the stripper tower by having no internal devices in the stripping tower below the sludge distributor.

17. The method of claim 16 which is characterized by a stripping gas residence time in the stripping tower of at least 5 seconds.

18. A method for removing ammonia from digested denatured liquid sludge containing ammonia and suspended solids, the method comprising

feeding the liquid sludge to a tank which is in fluid communication with an interior of a hollow stripping tower;

flashing the liquid sludge into the tank producing stripping gas which flows to the stripping tower'"'"'s interior, with the tower being at a positive pressure,

adjusting the pH of the liquid sludge in the tank to at least 9,

agitating the liquid sludge in the tank, and then

feeding the liquid sludge from the tank to the stripping tower,

flowing the liquid sludge to an interior wall of the stripping tower forming a downward flowing film of sludge on the wall interior,

flowing stripping gas upwardly past the film, stripping ammonia from the liquid sludge and forming a vapor containing ammonia and stripping gas,

disengaging liquid sludge from the vapor in a disengaging zone in the stripping tower, producing disengaged liquid sludge, and

sensing ammonia concentration level of the disengaged liquid sludge through the stripping tower to remove at least 99% by weight of the ammonia.