Sorption of acidic gases by solid residue from sugar refining

• US 5,635,150 A
• Filed: 09/26/1995
• Issued: 06/03/1997
• Est. Priority Date: 09/26/1995
• Status: Expired due to Fees

• Current Assignee: Robert W. Coughlin
• Original Assignee: Robert W. Coughlin
• Inventors: Coughlin, Robert W.
• Primary Examiner(s): Bos, Steven
• Assistant Examiner(s): DI MAURO, PETER T
• Application Number:
  US08/533,766
• Time in Patent Office: 616 Days
• Field of Search: 423/242.5, 423/244.07, 423/173, 423/175, 423/243.08, 423/239.1, 423/240 S, 423/210, 127/50, 252/189
• US Class Current: 423/244.07
• CPC Class Codes: B01D 53/508 by treating the gases with solids
• CPC Class Codes: B01D 53/565 by treating the gases with solids
• CPC Class Codes: B01D 53/685 by treating the gases with solids

Abstract

Solid residues formed as byproducts during the refining of sugars (e.g., beet sugar or cane sugar) are employed to sorb acidic gases such as oxides of sulfur or nitrogen. Calcines of the solid residues can also be used. Sorption of acidic gases from gaseous mixtures containing acidic gases is thus accomplished.

Claims

1. A method of removing an acidic component of a gaseous mixture containing said acidic component comprising the steps:

a) adding oxides or hydroxides of calcium to a sugar juice produced by aqueous extraction of a plant material,

b) recovering from said sugar juice a solid residue that contains at least a portion of the calcium added in step a,

c) contacting said solid residue from step b with said gaseous mixture in order to purify said gaseous mixture by removing said acidic component therefrom by reaction of said acidic component with said solid residue at a temperature of from about 900°

C. up to about 1316°

C.,

d) conducting the reaction of step c under such conditions that said solid residue increases in weight on a dry basis, and

e) separating said solid residue from the purified gaseous mixture produced in step c.

2. The method according to claim 1 wherein the mixture from step a is carbonated with CO₂ before recovery of the solid residue in step b.

3. The method according to claim 2 wherein the residue recovered in step b is at least partially de-sugared before contacting it with the gaseous mixture in step c.

4. The method according to claim 2 wherein said solid residue is calcined before or during step c.

5. The method according to claim 3 wherein said solid residue is calcined before or during step c.

6. The method according to claim 4 wherein said plant material is chosen from the group consisting of sugar beets and sugar cane.

7. The method according to claim 5 wherein said plant material is chosen from the group consisting of sugar beets and sugar cane.

8. A process for producing a product useful for sorbing or reacting with acidic gases comprising the steps:

a) adding oxides or hydroxides of calcium to a sugar juice produced by aqueous extraction of a plant material,

b) recovering from said sugar juice a solid residue that contains at least a portion of the calcium added in step a, and

c) contacting the solid residue recovered in step b with a gaseous mixture containing an acidic gas at a temperature of from about 900°

C. up to about 1316°

C. so as to calcine said solid residue.

9. The process according to claim 8 wherein said process comprises the additional step of at least partially desugaring the solid residue recovered in step b before calcining in step c.

10. The process according to claim 8 wherein said plant material is chosen from the group consisting of sugar beets and sugar cane.

11. A method of removing an acidic component of a gaseous mixture containing said acidic component comprising the steps:

a) adding oxides or hydroxides of calcium to a sugar juice produced by aqueous extraction of a plant material,

b) recovering from said sugar juice a solid residue that contains at least a portion of the calcium added in step a,

c) contacting said solid residue from step b with said gaseous mixture in order to purify said gaseous mixture by removing said acidic component therefrom by reaction of said acidic component with said solid residue,

d) conducting the reaction of step c at a temperature within the approximate range of from about 900°

C to about 1316°

C.,

e) separating said solid residue from the purified gaseous mixture produced in step c.

12. The method according to claim 11 wherein the mixture from step a is carbonated with CO₂ before recovery of the solid residue in step b and the residue recovered in step b is at least partially desugared before contacting it with the gaseous mixture in step c.

13. The method according to claim 12 wherein said plant material is chosen from the group consisting of sugar beets and sugar cane.