Foaming cleansing products

• US 5,635,469 A
• Filed: 10/10/1996
• Issued: 06/03/1997
• Est. Priority Date: 06/10/1993
• Status: Expired due to Fees

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Taniguchi, Tatsuya, Gupte, Anil J., Woodin, Frederick W. Jr., Fowler, Timothy J., Collias, Dimitris I., Deckner, George E.
• Primary Examiner(s): Caldarola, Glenn A.
• Assistant Examiner(s): Wood, Elizabeth D.
• Application Number:
  US08/729,523
• Time in Patent Office: 236 Days
• Field of Search: 239/329, 239/330, 239/343, 239/590, 239/590.3, 239/575, 510/120, 510/406, 510/475
• US Class Current: 510/406
• CPC Class Codes: A61K 2800/5422 nonionic
• CPC Class Codes: A61K 2800/5426 cationic
• CPC Class Codes: A61K 2800/87 Application Devices; Containers; Packaging
• CPC Class Codes: A61K 8/046 Aerosols; Foams
• CPC Class Codes: A61K 8/368 with carboxyl groups directly bound to carbon atoms of aromatic rings
• CPC Class Codes: A61K 8/416 Quaternary ammonium compounds A61K8/35 takes precedence
• CPC Class Codes: A61K 8/466 containing sulfonic acid derivatives; Salts
• CPC Class Codes: A61K 8/4926 having six membered rings
• CPC Class Codes: A61K 8/604 Alkylpolyglycosides; Derivatives thereof, e.g. esters
• CPC Class Codes: A61K 8/64 Proteins; Peptides; Derivatives or degradation products thereof
• CPC Class Codes: A61K 8/645 Proteins of vegetable origin; Derivatives or degradation products thereof
• CPC Class Codes: A61K 8/65 Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
• CPC Class Codes: A61K 8/731 Cellulose; Quaternized cellulose derivatives
• CPC Class Codes: A61K 8/8176 Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/84 obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
• CPC Class Codes: A61K 8/988 Honey; Royal jelly, Propolis
• CPC Class Codes: A61Q 17/04 Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
• CPC Class Codes: A61Q 19/00 Preparations for care of the skin
• CPC Class Codes: A61Q 19/10 Washing or bathing preparations
• CPC Class Codes: A61Q 5/006 Antidandruff preparations
• CPC Class Codes: A61Q 5/02 : Preparations for cleaning the hair
• CPC Class Codes: B01F 23/235 : for making foam
• CPC Class Codes: B01F 25/43141 : composed of consecutive sections of helical formed elements
• CPC Class Codes: B01F 25/4337 : Mixers with a diverging-converging cross-section
• CPC Class Codes: B01F 25/4523 : the components being pressed through sieves, screens or meshes which obstruct the whole diameter of the tube
• CPC Class Codes: B01F 25/45231 : the sieves, screens or meshes being cylinders or cones which obstruct the whole diameter of the tube, the flow changing from axial in radial and again in axial

Abstract

The present invention relates to foam producing products useful for personal cleansing. These products comprise a foamable liquid composition and a foam-producing foam dispenser. These products provide a stable homogeneous foam and good lathering and cleansing characteristics. These products are very mild to the skin and are useful for moisturizing the skin and for delivering a wide variety of active ingredients to the skin.

Claims

1. A foam producing cleansing product comprising:

(A) a foamable cleansing liquid composition comprising

(i) from about 0.1% to about 20% of a surfactant selected from the group consisting of amphoteric surfactants, nonionic surfactants, and mixtures thereof,

(ii) from about 0.1% to about 10% of a water soluble cationic or nonionic polymer,

(iii) from about 0.1% to about 25% of a humectant,

(iv) from about 0.05% to about 10% of an emollient, and

(v) from about 35% to about 99.65% water,

wherein said liquid composition has a viscosity of from about 1 cps to about 300 cps; and

(B) a foam dispenser for dispensing a final foam from an incoming intermediate foam, said dispenser comprising a reservoir to contain said liquid composition, a manually-actuated means for generating a volume of a mixture of said liquid composition and a gas, and a foam dispensing nozzle sealably attached in fluid communication with said manually-actuated means wherein the improvement comprises a nozzle comprising;

(i) an inlet conduit for receiving an intermediate foam consisting of a mixture of a liquid composition and a gas at a volumetric flow rate sufficiently high that it will produce an average incoming intermediate foam velocity which is too great to permit effective bubble bursting to put said foam in a final foam as said foam passes through at least one downstream foam refining means having a plurality of passageways therethrough; and

(ii) a velocity decreasing means placing said inlet conduit in fluid communication with a foam refining means, wherein said velocity decreasing means lowers the average velocity of said intermediate foam so when said foam passes through said foam refining means it is at a velocity no greater than 300 cm/sec.

2. A product according to claim 1 wherein said composition has a viscosity of from about 20 cps to about 130 cps.

3. A product according to claim 1 wherein said composition has a viscosity of from about 50 cps to about 100 cps.

4. A product according to claim 3 wherein said foam has a density of from about 0.05 gms/cm³ to about 0.15 gms/cm³.

5. A product according to claim 3, wherein said foam has a density of from about 0.075 gms/cm³ to about 0.125 gms/cm³.

6. A product according to claim 5 comprising from about 2.0% to about 6.0% of said water soluble polymer.

7. A product according to claim 6 wherein said water soluble polymer is selected from the group consisting of lauryldimmonium hydroxypropyl oxyethyl cellulose, laurdimonium hydroxyethyl cellulose, steardimonium hydroxyethyl cellullose, cocodimonium hydroxyethyl cellulose, lauryldimoniumu hydroxypropyl hydrolyzed collagen, lauryldimmonium hydroxypropyl hydrolyzed keratin, lauryldimmonium hydroxypropyl hydrolyzed keratin, lauryldimmonium hydroxypropyl hydrolyzed silk, lauryldimmonium hydroxypropyl hydrolyzed soy protein, protonated polyethylenimine, hydrolzyed casein, hydrolyzed collagen, hydrolyzed vegetable protein, polyvinylpyrrolidone, and mixtures thereof.

8. A product according to claim 6 wherein said water soluble polymer is selected from the group consisting of laurdimmonium hydroxypropyl oxyethyl cellulose, lauryldimonium hydroxypropyl hydrolyzed collagen, hydrolzyed casein, and mixtures thereof.

9. A product according to claim 7 wherein said surfactant is selected from the group consisting of lauryl polyglucoside, decyl polyglucoside, oleyl betaine, cocamidopropyl betaine, cocamidopropyl hydroxysultaine, sodium lauryl sarcosinate, coamdiopropyl PG-dimonium chloride phosphate, and mixtures thereof.

10. A product according to claim 9 wherein said humectant is selected from the group consisting of glycerin, urea, honey extract, 1,2-butylene glycol, 1,2-hexylene glycol, propoxylated glycerol and mixtures thereof.

11. A product according to claim 9 wherein said emollient is selected from the group consisting of sodium isostearyl lactylate, lauryl pidolate, sorbitan stearate, panthenyl triacetate, and mixtures thereof.

12. A product according to claim 9 which further comprises an active ingredient selected from the group consisting of anti-acne actives, sunscreen actives, anti-dandruff actives, artificial tanning actives, nonsteroidal antiinflammatory actives, antipruritic actives, topical anesthetic actives, antimicrobial actives, and mixtures thereof.

13. A product according to claim 9 which further comprises an active ingredient selected from the group consisting of salicylic acid, erythromycin, benzoyl peroxide, dihydroxyacetone, ibuprofen, hydrocortisone, lidocaine, triclosan, zin pyrithione, selenium sulfide, chlorhexidene, 2-ethylhexyl 4-N,N-dimethyl-p-aminobenzoate, 2-ethylhexyl p-methoxycinnamate, octocrylene, octyl salicylate, homomenthyl salicylate, p-aminobenzoic acid, oxybenzone, 2-phenylbenzimidazole-5-sulfonic acid, DEA p-methoxycinnamate, 4,4'"'"'-methoxy-t-butyldibenzoylmethane, 4-isopropyl dibenzoylmethane, 3-(4-methylbenzylidene) camphor, 3-benzylidene camphor, zincoxide, titianium dioxide and mixtures thereof.

14. A product according to claim 1 which further comprises from about 0.1% to about 2.5% of an anionic surfactant.

15. A product according to claim 9 which further comprises from about 0.1% to about 2.5% of an anionic surfactant.

16. A product according to claim 15 wherein said anionic surfactant is selected from the group consisting ammonium cocoyl isethionate, sodium cocoyl isethionate, sodium lauroyl isethionate, sodium stearoyl isethionate, and mixtures thereof.

17. A product according to claim 1 wherein said foam refining means comprises a meshed screen having a plurality of substantially uniformly-sized, and evenly distributed passageways having a maximum dimension less than about 0.175 mm as measured perpendicular to its axis.

18. A product according to claim 17 wherein said passageways of said screen have a dimension from about 0.020 mm to about 0.120 mm.

19. A product according to claim 18 wherein the total area of the refining screen is from about 0.5 cm² to about 10 cm² and the percentage open area is from about 15% to about 50%.

20. A product according to claim 17 wherein said passageways of said screen have a dimension from about 0.035 mm to about 0.080 mm.

21. A product according to claim 18 wherein the total area of the refining screen is from about 1 cm² to about 2 cm² and the percentage open area is from about 20% to about 40%.

22. A product according to claim 1 wherein said velocity decreasing means comprises a volume expanding means.

23. A product according to claim 22 wherein the volume expanding means is an expanded conduit having a cross-sectional area at its outlet at least larger than a cross sectional area of its inlet.

24. A product according to claim 23 wherein said ratio of cross-sectional areas of the outlet to inlet is from about 2:

1 to about 8;

1.

25. A product according to claim 24 wherein said expanded conduit has a rectangular cross sectional shape having a height to width ratio from about 1:

1.5 to about 1;

2.

26. A foam producing cleansing product comprising:

(A) a foamable cleansing liquid composition comprising

(i) from about 0.1% to about 20% of a surfactant selected from the group consisting of amphoteric surfactants, nonionic surfactants, and mixtures thereof,

(ii) from about 0.1% to about 10% of a water soluble cationic or nonionic polymer,

(iii) from about 0.1% to about 25% of a humectant,

(iv) from about 0.05% to about 10% of an emollient, and

(v) from about 35% to about 99.65% water,

wherein said liquid composition has a viscosity of from about 1 cps to about 300 cps; and

(B) a manually-actuable foam dispenser for producing and dispensing a high quality final foam from a foamable liquid and a gas, said foam being comprised of bubbles having a number-average diameter of about D₁, said dispenser comprising;

(i) a manually-actuable means for mixing a quantity of said foamable liquid with a quantity of said gas to produce an intermediate foam which comprises bubbles having a number-average diameter greater than about D₁ and a wider bubble size distribution than the final foam, at a volumetric flow rate Q which is dependent upon the speed of actuation of said manually-actuable means by the user; and

(ii) a foam dispensing nozzle comprising a conduit in fluid communication with said manually-actuable means for receiving the intermediate foam from said manually-actuable means; and

at least one foam refining means located in said conduit, said foam refining means comprising a plurality of substantially uniformly-sized and evenly distributed passageways;

wherein said intermediate foam passes through said passageways at a velocity, V₂, failing within the range of a minimum velocity, V₂,min, and a maximum velocity, V₂,max, wherein the conditions needed to cause bursting of said bubbles having a diameter larger than about D₁ are met.

27. A product according to claim 26 wherein said foam refining means is a meshed screen comprising a plurality of substantially uniformly-sized and evenly distributed passageways;

each of the passageways having an axis; and

each of the passageways also having a maximum cross-sectional dimension D in the range of about 10% to about 20% of the number-average bubble diameter D₁ of the final foam, as measured perpendicular to its axis.

28. A product according to claim 27 further comprising a second foam refining means located in said inlet conduit of the said foam dispensing nozzle.

29. A product according to claim 28 wherein said second foam refining means comprises a meshed screen having a plurality of substantially uniformly-sized and evenly distributed passageways.

30. A product according to claim 28 further comprising an intermediate foam refining means located in said conduit between said second foam refining means and said foam refining means located at the discharge end of said connecting conduit of the said foam dispensing nozzle.

31. A product according to claim 30 wherein said intermediate foam refining means is selected from the group consisting of meshed screens, static mixers and combinations thereof.

32. A product according to claim 31 wherein said intermediate foam refining means comprises a meshed screen;

and wherein the dimension D of the substantially uniformly-sized and evenly distributed passageways ranges from about 5% to about 20% of the number-average bubble diameter D₁ of the final foam.

33. A product according to claim 30 wherein said intermediate foam refining means comprises a static mixer.

34. The product according to claim 31 wherein the percentage open area of said intermediate meshed screen is from about 15% to about 30%.

35. The product according to claim 26 wherein said foam dispenser is a pump foam dispenser.