Vacuum extraction sampling system

• US 5,637,809 A
• Filed: 06/02/1995
• Issued: 06/10/1997
• Est. Priority Date: 11/12/1991
• Status: Expired due to Fees

• Current Assignee: Teledyne Monitor Labs, Inc. (Teledyne Technologies Incorporated)
• Original Assignee: United Sciences LLC
• Inventors: Myers, Richard, Traina, John E.
• Primary Examiner(s): Chilcot, Richard
• Assistant Examiner(s): Noori, Max H.
• Application Number:
  US08/456,650
• Time in Patent Office: 739 Days
• Field of Search: 73/864, 73/864.12, 73/864.22, 73/864.34, 73/864.35, 73/29.01
• US Class Current: 73/864.12
• CPC Class Codes: G01N 1/2252 in a vehicle exhaust
• CPC Class Codes: G01N 1/2258 in a stack or chimney
• CPC Class Codes: G01N 1/24 Suction devices G01N1/22 - G01N1/2294 take precedence
• CPC Class Codes: G01N 2001/2261 preventing condensation (heating lines)
• CPC Class Codes: G01N 2001/2264 with dilution
• CPC Class Codes: G01N 2001/244 using critical flow orifices
• CPC Class Codes: G01N 33/0011 Sample conditioning preparing specimens for investigation G01N1/28
• CPC Class Codes: G01N 33/0016 by regulating a physical variable, e.g. pressure or temperature

Abstract

A gas sampling system utilizes small sample vacuum transport to reduce the dew point of the sample. A vacuum pump maintains a substantial vacuum on the sampling system causing a sample, drawn at a rate less than a liter per minute, to be drawn and transported under partial vacuum for analysis. A dryer can be placed near the sampling probe to further reduce the dew point prior to the vacuum transport. The dew point of the sample is affected by both the dryer and the degree of vacuum transporting the gas mixture. As such, the dew point can be varied indefinitely by any reasonable combination of moisture removal by the dryer and vacuum pump strength.

Claims

1. An apparatus for collecting a sample stream from a system containing water vapor and at least one other gas comprising:

a) a collection probe adapted to draw the sample stream from the system;

b) a particulate filter connected to the collection probe so that the sample stream will flow therethrough;

c) a conduit connected at one end to the particulate filter and suited for connection at another end to an analyzer, the conduit having an orifice sized to permit the sample stream to flow through the conduit at a sampling rate of from 5 cc. to 250 cc. per minute; and

d) at least one pump connected to the conduit for drawing a vacuum on the sample stream.

2. The apparatus of claim 1 also comprising a dryer connected to the conduit prior to the orifice for removing water from the sample stream before the sample stream is transported to an analyzer.

3. The apparatus of claim 2 wherein the dryer contains a copolymer of tetrafluoroethylene and perfluoro-3,6-dioxa-4-methyl-7-octene-sulfonic acid.

4. The apparatus of claim 2 also comprising a dryer purge line connected to the dryer and having a critical orifice therein, the critical orifice positioned within the conduit and the critical orifice positioned within the purge line being sized so that a known stable ratio is formed between purge flow and sample flow.

5. The apparatus of claim 4 also comprising means for supplying a dry air stream having a known moisture content to the dryer into which dry air stream moisture removed from the sample stream by the dryer is exhausted thereby forming a dryer exhaust stream and means for measuring moisture content of the dryer exhaust stream, both means being connected to the dryer, such that moisture content in the sample stream may be calculated from the moisture content of the dryer exhaust stream and the known stable ratio of sample flow and purge flow rates.

6. The apparatus of claim 5 wherein the means for supplying a dry air stream having a known moisture content to the dryer is at least one of a dryer having an ambient air input and a desiccant.

7. The apparatus of claim 1 also comprising an analyzer connected to the conduit.

8. The apparatus of claim 7 wherein the analyzer is able to measure at least one property of the sample stream which property is one of O₂ level, NOx, SO₂, CO₂ and dew point.

9. The apparatus of claim 1 wherein the at least one pump creates a pressure in the sample stream not greater than 0.40 atmospheres.

10. The apparatus of claim 1 wherein the filter is a replaceable cartridge type filter.

11. The apparatus of claim 1 wherein at least a portion of the conduit is tetrafluoroethylene.

12. The apparatus of claim 1 also comprising a pressure transducer connected to the conduit.

13. The apparatus of claim 1 also comprising a calibration gas source connected through a calibration gas conduit to the filter in a manner so that calibration gas may flow through the filter into the conduit.

14. The apparatus of claim 13 also comprising a pressure transducer connected to the calibration gas conduit.

15. The apparatus of claim 13 also comprising an accumulator connected to the calibration gas conduit.

16. A method of extractive sampling from a system containing water vapor and at least one other gas comprising the steps of:

a) placing a sampling probe in the system;

b) drawing a vacuum on the sampling probe to collect a sample and to induce the sample to flow from the system at a sampling rate of from 5 cc. to 250 cc. per minute;

c) transporting the sample to at least one analyzer through an elongated conduit and

d) further adjusting the vacuum on the sample to maintain a dew point of the sample within a preselected temperature range.

17. The method of claim 16 wherein the sample drawn from the system does not exceed 150 cc./min.

18. The method of claim 16 also comprising the step of measuring a dew point of the sample.

19. The method of claim 16 also comprising the step of removing moisture from the sample prior to drawing the vacuum.

20. The method of claim 19 wherein moisture is removed from the sample by a dryer having a purge line having a purge line critical orifice therein and the sample is drawn through a sample critical orifice, the purge line critical orifice and the sample critical orifice being sized so that a stable ratio is formed between purge flow and sample flow.

21. The method of claim 19 also comprising the step of measuring the moisture removed from the sample.

22. The method of claim 19 wherein at least 99% of the moisture in the sample is removed.

23. The method of claim 19 also comprising the step of measuring a dew point of the sample.

24. The method of claim 16 wherein the sample is transported under vacuum at an absolute pressure of less than 20 millimeters of mercury.

25. The method of claim 24 wherein at least one analyzer is used to withdraw a portion of the sample from the vacuum conduit and to measure at least one constituent of the sample.

26. The method of claim 25 wherein the at least one analyzer is a mass spectrometer.