Polyamide compositions

• US 5,639,819 A
• Filed: 07/09/1993
• Issued: 06/17/1997
• Est. Priority Date: 01/10/1991
• Status: Expired due to Fees

• Current Assignee: Du Pont Taiwan Limited (Corteva, Inc.), E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: Du Pont Taiwan Limited (Corteva, Inc.), E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Farkas, Nicholas, Marks, David Neil, Nemser, Stuart Marshall
• Primary Examiner(s): Michl, Paul R.
• Assistant Examiner(s): RAJGURU, UMAKANT K
• Application Number:
  US08/084,246
• Time in Patent Office: 1,439 Days
• Field of Search: 524/606, 524/425, 524/430, 524/437, 524/439, 524/441, 524/445, 524/447, 524/448, 524/449, 524/451, 524/494, 524/495, 525/423, 528/335, 528/340
• US Class Current: 524/606
• CPC Class Codes: C08G 69/265 from at least two different diamines or at least two different dicarboxylic acids

Abstract

A mouldable reinforced polyamide composition comprising;

(a) a polyamide consisting essentially of between about 0.5 and about 99.5 mol. % of aliphatic diamines having 4-12 carbon atoms and a complementary amount of 2-methyl-pentamethylene diamine copolymerized with aliphatic dicarboxylic acids having 6-12 carbon atoms; and

(b) a filler in an amount of 0.5 to 200 parts by weight per 100 parts by weight of said polyamide. The polyamide has an RV greater than about 20. Related polyamides, especially in which the acid is 1,12-dodecanedioic acid, are also disclosed. The polyamides may be used in a wide variety of end-uses, including moulding, and exhibit excellent gloss compared with nylon 6,6.

Claims

1. A mouldable reinforced polyamide composition comprising:

(a) a polyamide consisting of 2-methyl-pentamethylene diamine polymerized with an aliphatic dicarboxylic acid having 12 carbon atoms, the polyamide having formic acid RV greater than about 20 and a solubility in methanol at 65°

C. of less than 5% by weight; and

(b) a filler in an amount of 0.5 to 100 parts by weight of said polyamide.

2. The composition of claim 1 or claim 2 in which the RV of the polyamide is between about 25 and 250.

4. The composition of claim 1 which additionally contains a diepoxide cross-linking agent.

5. The composition of claim 1 in which the amount of filler is 2 to 100 parts by weight.

3. The composition of claim 3 in which the RV is between about 30 and 80.

6. A polyamide consisting of 2-methyl-pentamethylene diamine polymerized with 1,12-dodeanediodic acid, the polyamide having a formic acid RV is greater than about 20 and a solubility in methanol at 65°

C. of less than 5% by weight.

7. The polyamide of claim 6 in which the RV of the polyamide is between about 25 and 250.

8. The polyamide of claim 7 in which the RV is between 30 and 80.

9. A polyamide consisting essentially of 2-methyl-pentamethylene diamine polymerized with 1,12-dodecanediodic acid, the polyamide having an RV greater than about 20 and a solubility in methanol at 65°

C. of less than 5% by weight which additionally contains a diepoxide cross-linking agent.

10. An article formed from a polyamide consisting of 2-methyl-pentamethylene diamine polymerized with 1,12-dodecanedioic acid, the polyamide having a formic acid RV greater than about 20 and a solubility in methanol at 65°

C. of less than 5% by weight, said article being film, wire coating, pipe, tubing, thermoformed article, moulded article or powder coating.

11. An article formed from a polyamide consisting essentially of 2-methyl-pentamethylene diamine polymerized with at least one aliphatic dicarboxylic acid having 6-12 carbon atoms, the polyamide having an RV greater than about 20 said article being a film, wire coating, pipe, tubing, thermoformed article, rotomoudled article, molded article or powder coating in which the polyamide additionally contains a diepoxide cross-linking agent.