Isoparaffin-olefin alkylation

• US 5,639,932 A
• Filed: 05/26/1995
• Issued: 06/17/1997
• Est. Priority Date: 05/01/1992
• Status: Expired due to Term

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Abbott, Ronald G., Randolph, Bruce B.
• Primary Examiner(s): Langel, Wayne
• Assistant Examiner(s): DUNN, THOMAS G
• Application Number:
  US08/451,806
• Time in Patent Office: 753 Days
• Field of Search: 585/724, 585/730, 585/723, 585/722, 585/721
• US Class Current: 585/724
• CPC Class Codes: B01J 2231/323 Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
• CPC Class Codes: B01J 31/0222 comprising sulfonyl groups
• CPC Class Codes: C01B 7/191 Hydrogen fluoride
• CPC Class Codes: C07C 2/62 with acids
• CPC Class Codes: C07C 2527/1206 Hydrogen fluoride

Abstract

A novel alkylation catalyst is described which is used in processes for alkylating olefin hydrocarbons with isoparaffin hydrocarbons to produce high octane alkylate products suitable for use as blending components of gasoline motor fuel. The novel catalyst comprises a mixture of a hydrogen halide, a sulfone and water and has suitable corrosion properties which permit its utilization in alkylation process systems. The novel alkylation catalyst is utilized in a novel process for alkylating olefin hydrocarbons with isoparaffin hydrocarbons.

Claims

1. A method of improving the quality of an alkylate product produced by an alkylation process including contacting a hydrocarbon mixture containing olefins and isoparaffins with a catalyst consisting essentially of hydrogen fluoride and a sulfone to thereby produce said alkylate product, the method comprising the step of:

incorporating water into said catalyst in an amount such that the octane of said alkylate product is higher than said alkylate product produced when said catalyst contains no water.

2. A method as recited in claim 1, wherein said amount of water incorporated into said catalyst is such that the concentration of water is in the range of from about 0.25 to about 10 weight percent based on the sum weight of the hydrogen fluoride and sulfone components.

3. A method as recited in claim 2, wherein the weight ratio of hydrogen fluoride to sulfone in said catalyst is in the range of from about 1:

1 to about 40;

1.

4. A method as recited in claim 3, wherein said sulfone is sulfolane.

5. A method of improving the quality of an alkylate product containing trimethylpentane produced by an alkylation process including contacting a hydrocarbon mixture containing olefins and isoparaffins with a catalyst consisting essentially of hydrogen fluoride and a sulfone to thereby produce said alkylate product, the method comprising the step of:

incorporating water into said catalyst in an amount such that the concentration of trimethylpentane in said alkylate product is higher than said alkylate product produced when said catalyst contains no water.

6. A method as recited in claim 5, wherein said amount of water incorporated into said catalyst is such that the concentration of water is in the range of from about 0.25 to about 10 weight percent based on the sum weight of the hydrogen fluoride and sulfone components.

7. A method as recited in claim 6, wherein the weight ratio of hydrogen fluoride to sulfone in said catalyst is in the range of from about 1:

1 to about 40;

1.

8. A method as recited in claim 7, wherein said sulfone is sulfolane.