Treatment of contaminated water in clays and the like

• US 5,641,020 A
• Filed: 05/19/1995
• Issued: 06/24/1997
• Est. Priority Date: 05/20/1994
• Status: Expired due to Term

• Current Assignee: University of Waikato
• Original Assignee: University of Waikato
• Inventors: Parker, Beth L., Cherry, John Anthony
• Primary Examiner(s): Suchfield, George A.
• Application Number:
  US08/444,676
• Time in Patent Office: 767 Days
• Field of Search: 405/128, 405/129, 166/250.1, 166/308, 166/177.5, 166/191, 166/297
• US Class Current: 166/250.1
• CPC Class Codes: B09C 1/00 Reclamation of contaminated soil
• CPC Class Codes: B09C 1/08 chemically
• CPC Class Codes: B09C 1/10 microbiologically, biologically or by using enzymes
• CPC Class Codes: B09C 2101/00 In situ
• CPC Class Codes: E21B 43/26 by forming crevices or fractures
• CPC Class Codes: E21B 49/00 Testing the nature of borehole walls; Formation testing; Methods or apparatus for obtaining samples of soil or well fluids, specially adapted to earth drilling or wells

Abstract

The treatment system involves the use of hydrofracturing in drilled boreholes over the treatment area. The hydrofracturing fluid contains treatment material, of the kind that causes chemical breakdown of the contaminant. The breakdown leads to a contaminant concentration of zero in the hydrofracks, and therefore the contaminant diffuses towards the hydrofracks, where it is in turn broken down. Calculations and measurements indicate whether natural cracks in the ground are far enough apart to make hydrofracturing worthwhile. A formula indicates, from an assessment of diffusion coefficients, etc, whether the contaminant will be rendered safe within a given time period.

Claims

1. Procedure for treating contaminated groundwater, including the steps of:

taking a sample of the ground containing the contaminated groundwater;

establishing the nature of the contaminant, and selecting a suitable treatment material;

proceeding with the following steps responsive to the selected treatment material being of the kind that will bring about a chemical breakdown of the contaminant when the contaminant is located, at a point of breakdown, in close physical proximity to the treatment material, being breakdown of the kind wherein;

(a) the contaminant is chemically converted into a relatively non-contaminating substance, (b) the concentration of the contaminant at the point of breakdown is substantially depleted by the breakdown, and (c) the effective concentration of the treatment material at the point of breakdown is unaffected or affected only very slowly by the breakdown;

determining the nature of the ground, and proceeding with the following steps responsive to a determination that the ground comprises large blocks of low permeability material (LPM), and the large LPM blocks are intercalated with cracks or other zones of higher permeability;

determining the concentration (CC-i) of the contaminant at an interior point of the LPM block, located a distance L from the nearest point on the boundary of the block;

carrying out measurements and calculations to determine the passive diffusion rate of the contaminant (PDR-C) in the LPM block, being the rate at which the concentration of the contaminant at the point changes over time as a function of the concentration gradient of the contaminant (CG-C) at that point;

providing conditions whereby passive diffusion of the contaminant towards the boundary of the block can take place;

proceeding with the following steps in response to a need to reduce the size, being the dimensions L, of the blocks;

providing a fracturing fluid, comprising a mixture of the treatment material with e carrier fluid;

establishing a concentration of treatment material (CTM-H) that can be injected into the fracks in the fracturing fluid, and forming the mixture to that concentration;

carrying out measurements and calculations to determine the extent of the treatment area, being the area of the contaminated LPM;

drilling boreholes at intervals over the treatment area;

fracturing the ground around the holes, so as to form fracks, by injecting the fracturing fluid under pressure into the boreholes;

spacing the boreholes a pitch distance apart over the treatment area such that the fracks overlap laterally;

establishing a mathematical model, based on the PDR-C, for enabling a theoretical prediction to be made of the relationship between the distance L and the time period taken for CC-i to drop to a safe concentration (CC-safe);

assigning an acceptable time period T for the CC-i to fall to CC-safe;

from the model, computing the distance L corresponding to that time period T;

forming a plurality of the fracks in the borehole, spaced a distance V apart, where V is no more than L;

after fracturing, maintaining passive conditions in the fracks at the point of breakdown;

wherein the passive conditions are such that, under the passive conditions, passive diffusion of the contaminant towards the boundaries of the LPM blocks takes place, substantially without the input of flow-inducing energy.

2. Procedure of claim 1, including the steps of:

determining, by calculation based on diffusion rates, that the breakdown of the contaminant is of the kind wherein the effective concentration of the treatment material at the point of breakdown is depleted as a rate such that the treatment material needs to be replaced or refreshed after an interval or period of time P;

proceeding with the following steps in response to the period P being shorter than the said period T;

refreshing the treatment material by a subsequent act or acts of injecting fresh treatment material into the fracks;

between refreshments, maintaining passive conditions in the fracks;

the passive conditions are such that, under the passive conditions, passive diffusion of the contaminant towards the boundaries of the LPM blocks takes place, substantially without the input of flow-inducing energy.

3. Procedure of claim 2, wherein the treatment material is in the solid phase, and is in the form of grains or particles.

4. Procedure of claim 2, wherein the treatment material is in the liquid phase, which includes non-aqueous phase liquids and liquids dissolved in water.

5. Procedure of claim 4, wherein the liquid treatment material diffuses into the LPM blocks, thereby effectively reducing the distance L by a distance R, and, in response to determining that reduction, correspondingly increasing the distance V apart of the fracks.

6. Procedure for treating contaminated groundwater, including the steps of:

establishing the nature of the contaminant in the ground, and selecting a suitable treatment material;

determining the nature of the ground, and proceeding with the following steps in response to the ground comprising large blocks of low permeability material (LPM), the contaminant being present within the large LPM blocks, and the large LPM blocks are intercalated with cracks or other zones of higher permeability;

providing conditions whereby passive diffusion of the contaminant from the interior towards the boundary of the block can take place;

proceeding with the following steps in response to an assessed need to reduce the size of the blocks;

providing a hydrofracturing liquid, comprising a mixture of the treatment material with a carrier liquid;

establishing a concentration of treatment material that can be injected into the hydrofracks in the hydrofracturing fluid, and forming the mixture to that concentration;

carrying out measurements and calculations to determine the extent of the treatment area, being the area of the ground containing the contaminated LPM;

drilling boreholes at intervals over the treatment area;

hydrofracturing the ground around the holes, so as to form hydrofracks, by injecting the hydrofracturing liquid under pressure from the surface into the boreholes;

spacing the boreholes a pitch distance apart over the treatment area such that the hydrofracks overlap laterally;

forming the hydrofracks in the boreholes a distance V apart;

after hydrofracturing, and thereafter, maintaining passive conditions in the hydrofracks at the point of breakdown, wherein the passive conditions are such that, under the passive conditions, passive diffusion of the contaminant towards the boundaries of the LPM blocks takes place, substantially without the input of flow-inducing energy;

and keeping the groundwater still and unmoving within the hydrofracks.

7. Procedure for injecting a treatment material into a treatment area of ground containing a contaminant, and comprising low permeability material, wherein:

the procedure includes the step of drilling boreholes at intervals over the treatment area;

the procedure includes the step of providing hydrofracturing liquid, comprising a mixture of the treatment material with a carrier liquid;

the procedure includes the step of hydrofracturing the ground around the holes, so as to form hydrofracks, by injecting the hydrofracturing liquid, which contains the treatment material, under pressure, into the boreholes;

after hydrofracturing, and thereafter, maintaining passive conditions in the hydrofracks, wherein the passive conditions are such that, under the passive conditions, passive diffusion of the contaminant towards the boundaries of the LPM blocks takes place, substantially without the input of flow-inducing energy;

and keeping the groundwater still and unmoving within the hydrofracks.

8. Procedure for injecting a treatment material into a treatment area of ground containing a contaminant, and comprising low permeability material, wherein:

the treatment material is in the liquid phase, which includes non-aqueous phase liquids and liquids dissolved in water;

the procedure includes the step of drilling boreholes at intervals over the treatment area;

the procedure includes the step of providing fracturing fluid, comprising a mixture of the treatment material with e carrier fluid;

the procedure includes the step of fracturing the ground around the holes, so as to form fracks, by injecting the fracturing fluid, which contains the treatment material, under pressure, into the boreholes;

after fracturing, and thereafter, maintaining passive conditions in the fracks, wherein the passive conditions are such that, under the passive conditions, passive diffusion of the contaminant towards the boundaries of the LPM blocks takes place, substantially without the Input of flow-inducing energy;

and keeping the groundwater still and unmoving within the cracks.

9. Procedure of claim 8, wherein the fracturing fluid contains, mixed evenly therein, grains of a solid-phase material, so constituted as to hold the fracks propped open.

10. Procedure of claim 9, including the step, after a period of passive diffusion, of injecting a fresh charge of liquid treatment material into the propped-open fracks.

11. Procedure for treating slowly-moving contaminated groundwater, comprising the steps of:

establishing the nature of the contaminant in the ground, and selecting a suitable treatment material, the selected treatment material being of the kind that will bring about a chemical breakdown of the contaminant when the contaminant is located, at a point of breakdown, in close physical proximity to the treatment material, being breakdown of the kind wherein;

(a) the contaminant is chemically converted into a relatively non-contaminating substance, (b) the concentration of the contaminant at the point of breakdown is substantially depleted by the breakdown, and (c) the effective concentration of the treatment material at the point of breakdown is unaffected or affected only relatively slowly by the breakdown;

determining the direction end speed of movement of a plume of the contaminant in the groundwater;

establishing a treatment zone in the ground, in the path of the plume;

determining the nature of the ground in the treatment zone, and proceeding with the following steps in response to the ground comprising large blocks of low permeability material (LPM);

carrying out measurements and calculations to determine the extent of the treatment zone;

drilling boreholes at intervals over the treatment zone;

proceeding with the following steps in response to an assessed need to reduce the size of the blocks;

providing a ground-fracturing fluid;

fracturing the ground around the holes, so as to form fracks, by injecting the ground-fracturing fluid under pressure from the surface into the boreholes;

spacing the boreholes a pitch distance apart over the treatment zone, such that the fracks overlap laterally;

in each borehole, forming the fracks in the borehole a vertical distance V apart, the fracks comprising cracks, within the LPM, of relatively high permeability, whereby the large blocks of LPM are broken up;

Injecting the treatment material, at a suitable concentration, into the fracks, whereby the treatment material is transferred into, and remains in, the fracks;

after fracturing, and thereafter, maintaining passive conditions in the fracks at the point of breakdown, wherein the passive conditions are such that, under the passive conditions, passive diffusion of the contaminant towards the boundaries of the LPM blocks takes place, substantially without the input of flow-inducing energy;

whereby the said contaminants in the slowly-moving groundwater moving naturally through the treatment zone are broken down.

12. Procedure for treating contaminated groundwater, comprising the steps of:

establishing the nature of the contaminant in the ground, and selecting a suitable treatment material, the selected treatment material being of the kind that will bring about a chemical breakdown of the contaminant when the contaminant is located, at a point of breakdown, in close physical proximity to the treatment material, being breakdown of the kind wherein;

(a) the contaminant is chemically converted into a relatively non-contaminating substance, (b) the concentration of the contaminant at the point of breakdown is substantially depleted by the breakdown, and (c) the effective concentration of the treatment material at the point of breakdown is unaffected or affected only relatively slowly by the breakdown;

establishing a treatment zone;

determining the nature of the ground in the treatment zone, and proceeding with the following steps In response to the ground comprising large blocks of low permeability material (LPM);

carrying out measurements and calculations to determine the extent of the treatment zone;

drilling boreholes at intervals over the treatment zone;

proceeding with the following steps In response to an assessed need to reduce the size of the blocks;

providing a ground-fracturing fluid;

fracturing the ground around the boreholes, so as to form fracks, by Injecting the ground-fracturing fluid under pressure from the surface into the boreholes;

spacing the boreholes a pitch distance apart over the treatment zone, such that the fracks overlap laterally;

in each borehole, forming the fracks in the borehole a vertical distance V apart, the fracks comprising cracks, within the LPM, of relatively high permeability, whereby the large blocks of LPM are broken up;

injecting the treatment material, at a suitable concentration, into the fracks, whereby the treatment material is transferred into, and remains in, the fracks;

after fracturing, end thereafter, maintaining passive conditions in the fracks at the point of breakdown, wherein the passive conditions are such that, under the passive conditions, passive diffusion of the contaminant towards the boundaries of the LPM blocks takes place, substantially without the input of flow-inducing energy;

whereby the said contaminants in the groundwater in the treatment zone are broken down.

13. Procedure of claim 12, wherein the treatment material remains present in the crack when the injection pressure is released.

14. Procedure for claim 12, wherein the body of treatment material is mixed with particles remaining in the crack that do not cause treatment but provide desired permeability in the crack.

15. Procedure for claim 12, wherein solid treatment material in the crack emits dissolved treatment materials that migrates or diffuses into the LPM to cause treatment away from the crack.

16. Procedure of claim 12, wherein:

Inserting solid particles into the crack hold the crack open to provide permeability for liquid;

injecting treatment liquids into the open crack to cause treatment in the crack and migration or diffusion of constituents from the liquid into the LPM to cause treatment away from the crack.

17. Procedure for claim 12, wherein the dissolved contaminants are caused to migrate from the LPM into the crack where they are degraded, destroyed or immobilized by the treatment material in the crack.

18. Procedure of claim 12, wherein the crack extends radially all around the borehole, whereby the treatment material injected with the injection-fluid forms a body which is substantially disc-like in shape.

19. Procedure of claim 12, wherein the procedure includes the steps of:

providing, in each borehole, a respective injection port, comprising inflatable packers or other means of sealing the hole and an injection pipe;

lowering the port down the borehole hole, inflating the packers when the port is at the desired depth or otherwise sealing the hole, forming a notch in the walls of the borehole near the injection port, and injecting the fluid and reaction materials therefrom so as to create a disc of injection-fluid in the LPM;

after injection, releasing the injection pressure, and releasing the inflatable packers;

moving the port up/down the hole to a new depth, re-inflating the packers, and creating a new disc at that depth.

20. Procedure of claim 19, wherein several discs are created per borehole, stacked vertically.

21. Procedure of claim 19, wherein many boreholes are positioned over the extent of the contaminated area, each having at least one disc.

22. Procedure of claim 12, wherein many boreholes are provided, pitched around a contaminated area so as to provide a treatment curtain, such that contaminated groundwater cannot migrate from the area without passing through the treatment curtain.

23. Procedure of claim 12, wherein the reactive material injected into the borehole forms vertical spirals;

and such spirals are positioned close together to form a wall of permeable material to treat contaminated groundwater that moves through the wall.

24. Procedure for claim 12, wherein the discs are positioned so as to form a horizontal or nearly horizontal zone in the LPM beneath a contaminated zone to treat contaminants that move downward from the zone.