Method of back-washing submerged-type ceramic membrane separation apparatus

• US 5,647,988 A
• Filed: 12/02/1994
• Issued: 07/15/1997
• Est. Priority Date: 05/30/1994
• Status: Expired due to Fees

• Current Assignee: Kubota Corporation
• Original Assignee: Kubota Corporation
• Inventors: Yokoyama, Shigeki, Narukami, Yoshihisa, Shioyama, Masahiko, Tokushima, Mikiharu, Ozaki, Toshiya, Ishihara, Katsuro, Kawanishi, Toshio
• Primary Examiner(s): POPOVICS, ROBERT J
• Application Number:
  US08/349,014
• Time in Patent Office: 956 Days
• Field of Search: 210/636, 210/739, 210/741, 210/791, 210/321.69, 210/106, 210/108, 134/10
• US Class Current: 210/636
• CPC Class Codes: B01D 2201/085 using another chemical than the liquid to be filtered
• CPC Class Codes: B01D 2321/04 Backflushing
• CPC Class Codes: B01D 2321/162 Use of acids
• CPC Class Codes: B01D 2321/164 Use of bases
• CPC Class Codes: B01D 2321/168 Use of other chemical agents
• CPC Class Codes: B01D 29/114 arranged for inward flow filtration B01D29/15, B01D29/33 take precedence
• CPC Class Codes: B01D 29/606 by pressure measuring
• CPC Class Codes: B01D 29/6438 nozzles
• CPC Class Codes: B01D 29/66 by flushing, e.g. counter-current air-bumps
• CPC Class Codes: B01D 29/86 Retarding cake deposition on the filter during the filtration period, e.g. using stirrers B01D29/908 takes precedence
• CPC Class Codes: B01D 65/02 Membrane cleaning or sterilisation ; Membrane regeneration
• CPC Class Codes: Y02A 20/131 Reverse-osmosis

Abstract

A method for back-washing a submerged-type ceramic membrane separation apparatus is provided in which filtrate once removed from the apparatus and a chemical agent are forcibly supplied to filtrate passages in ceramic membrane filters to wash the ceramic membrane filters with the filtrate and with the chemical agent, wherein the water washing and chemical washing are carried out at a predetermined frequency ratio and for a predetermined time period, or wherein the frequency and time period of the chemical washing are determined on the basis of a transmembrane pressure difference, suction pressure or filtrate flux observed during a filtering operation performed by the membrane separation apparatus. This method makes it possible to avoid an excessive chemical washing, and to reduce the amounts of water and chemical agent and the time required for the chemical washing.

Claims

1. A method for back-washing a ceramic membrane separation apparatus adapted to be submerged in treatment water contained in a water treatment vessel, said method comprising the step of:

forcibly supplying filtrate from the apparatus and a chemical agent, separately, to filtrate passages in ceramic membrane filters to wash the ceramic membrane filters with the filtrate during a water washing and to wash the ceramic membrane filters with the chemical agent during a chemical washing, wherein the water washing and the chemical washing are carried out on the basis of a predetermined frequency ratio and a predetermined time period, said time period of the water washing being between approximately 0.5 seconds and 60 seconds, in order to forcibly supply the filtrate to the filtrate passages to provide an applied pressure acting on the ceramic membrane filters, and said time period of the chemical washing being between approximately 10 seconds and 300 seconds, in order for the chemical agent to be forcibly supplied to the filtrate passages to thoroughly permeate the ceramic membrane filters.

2. A method for back-washing a ceramic membrane separation apparatus as set forth in claim 1, wherein, when the chemical washing is carried out, the forcibly supplied chemical agent is retained in the filtrate passages for a time period sufficient to allow a chemical reaction to occur between said chemical agent and any deposits on a surface of the ceramic membrane filter.

3. A method for back-washing a ceramic membrane separation apparatus as set forth in claim 1, wherein, after the chemical washing, the ceramic membrane filters are rinsed with the filtrate or with a solution of a reducing agent to remove any chemical agent remaining in the membrane filters from the chemical washing.

4. A method for back-washing a ceramic membrane separation apparatus as set forth in claim 3, wherein said reducing agent is a sodium bisulfate solution.

5. A method for back-washing a ceramic membrane separation apparatus as set forth in claim 1, wherein the chemical washing is carried out using an aqueous solution of an oxidizing agent selected from the group consisting of sodium hypochlorite, chlorine and chlorine dioxide in an available chlorine concentration of between about 1 mg/l and about 10⁴ mg/l.

6. A method for back-washing a ceramic membrane separation apparatus as set forth in claim 1, wherein the chemical washing is carried out using an aqueous solution of an acid or base selected from the group consisting of hydrochloric acid, sulfuric acid, nitric acid, oxalic acid, citric acid, and sodium hydroxide in a concentration of between about 1 mg/l and about 10⁴ mg/l.

7. A method for back-washing a ceramic membrane separation apparatus as set forth in claim 1, wherein the chemical washing is carried out in multiple stages using at least two kinds of chemical agent solutions selected from the group consisting of oxidizing agent solutions, acid solutions and base solutions.