Double loop liquid-liquid H.sub.2 S removal process

• US 5,648,054 A
• Filed: 01/31/1995
• Issued: 07/15/1997
• Est. Priority Date: 01/31/1995
• Status: Expired due to Fees

• Current Assignee: URS Corporation (Aecom Incorporated)
• Original Assignee: Gas Research Institute (GTI Energy)
• Inventors: DeBerry, David W.
• Primary Examiner(s): Jones, Deborah
• Assistant Examiner(s): HARDING, AMY MARIE
• Application Number:
  US08/381,111
• Time in Patent Office: 896 Days
• Field of Search: 423/220, 423/226, 423/228, 423/232, 423/576.2, 423/576.6
• US Class Current: 423/226
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1468 Removing hydrogen sulfide
• CPC Class Codes: C01B 17/05 by wet processes

Abstract

A process and system for removal of hydrogen sulfide from a hydrogen sulfide-containing gaseous stream comprising contacting the hydrogen sulfide-containing gaseous stream with a nonaqueous phase sorbent under conditions suitable for forming a hydrogen sulfide-laden sorbent and a clean gaseous stream. The hydrogen sulfide-laden sorbent is mixed with an aqueous phase redox coupled, regenerating the nonaqueous phase sorbent, reducing the aqueous phase redox couple, and forming sulfur. The sulfur is separated from the mixture. The reduced aqueous phase redox couple is extracted from the mixture and regenerated with an oxidizing agent or electrochemical cell.

Claims

1. A process for removal of hydrogen sulfide from a hydrogen sulfide-containing gaseous stream comprising:

contacting said hydrogen sulfide-containing gaseous stream with a nonaqueous phase sorbent comprising at least one substantially water-insoluble organic solvent under conditions suitable for forming a hydrogen sulfide-laden sorbent and a clean gaseous stream, thereby forming said hydrogen sulfide-laden sorbent and a clean gaseous stream;

mixing said hydrogen sulfide-laden sorbent with an oxidized aqueous phase redox couple under conditions suitable for forming a mixture comprising sulfur, a regenerated said nonaqueous phase sorbent, and a reduced aqueous phase redox couple, thereby forming said mixture;

separating said sulfur from said mixture; and

extracting said reduced aqueous phase redox couple from said mixture and regenerating said oxidized aqueous phase redox couple.

2. A process in accordance with claim 1, wherein said regenerated said nonaqueous phase sorbent is recirculated to contact said hydrogen sulfide-containing gaseous stream and said regenerated oxidized aqueous phase redox couple is recirculated to mix with said hydrogen sulfide-laden sorbent.

3. A process in accordance with claim 1, wherein said nonaqueous phase sorbent further comprises a redox couple.

4. A process in accordance with claim 1, wherein said oxidized aqueous phase redox couple is selected from the group consisting of chelated ferric ion, unchelated ferric ion in an acid solution, complexed ferric ions, aqueous vanadium in the 5 oxidation state (V), iodine/triiodide, sulfur dioxide, 9, 10 anthraquinone and mixtures thereof.

5. A process in accordance with claim 4, wherein said oxidized aqueous phase redox couple is ferric EDTA.

6. A process in accordance with claim 1, wherein said substantially water-insoluble organic solvent is selected from the group consisting of propylene carbonate, benzonitrile, water-insoluble amines and mixtures thereof.

7. A process in accordance with claim 1, wherein said oxidized aqueous phase redox couple is regenerated by aeration of said reduced aqueous phase redox couple.

8. A process in accordance with claim 1, wherein said oxidized aqueous phase redox couple is regenerated electrochemically.

9. A process for removal of hydrogen sulfide from a hydrogen sulfide-containing gaseous stream comprising the steps of:

absorbing said hydrogen sulfide in said hydrogen sulfide-containing gaseous stream with a nonaqueous phase sorbent comprising at least one substantially water-insoluble organic solvent thereby forming a hydrogen sulfide-laden sorbent;

mixing said hydrogen sulfide-laden sorbent with an oxidized aqueous phase redox couple thereby forming a mixture comprising sulfur, a regenerated said nonaqueous phase sorbent, and a reduced aqueous phase regenerant;

separating said sulfur from said mixture; and

extracting said reduced aqueous phase regenerant from said mixture and oxidizing said reduced aqueous phase regenerant thereby regenerating said oxidized aqueous phase redox couple.

10. A process in accordance with claim 9, wherein said regenerated oxidized aqueous phase redox couple is recirculated to said absorption step and said regenerated nonaqueous phase sorbent is recirculated to said mixing step.

11. A process in accordance with claim 9, wherein said nonaqueous phase sorbent further comprises a redox couple.

12. A process in accordance with claim 9, wherein said oxidized aqueous phase redox couple is selected from the group consisting of chelated ferric ion, unchelated ferric ion in an acid solution, complexed ferric ions, aqueous vanadium in the 5 oxidation state (V), iodine/triiodide, sulfur dioxide, 9, 10 anthraquinone and mixtures thereof.

13. A process in accordance with claim 12, wherein said oxidized aqueous phase redox couple is ferric EDTA.

14. A process in accordance with claim 9, wherein said substantially water-insoluble organic solvent is selected from the group consisting of propylene carbonate benzonitrile, water-insoluble amines and mixtures thereof.

15. A process in accordance with claim 9, wherein said reduced aqueous phase redox regenerant is oxidized by aeration.