Inflators which store premixed fluid fuel and oxidizer in a porous matrix

• US 5,649,720 A
• Filed: 11/30/1995
• Issued: 07/22/1997
• Est. Priority Date: 11/30/1995
• Status: Expired due to Fees

• Current Assignee: Autoliv ASP Incorporated (Autoliv Incorporated)
• Original Assignee: Morton International Incorporated (Autoliv Incorporated)
• Inventors: Green, David J., Rink, Karl K., Letendre, Guy R.
• Primary Examiner(s): Johnson, Brian L.
• Assistant Examiner(s): English, Peter C.
• Application Number:
  US08/565,331
• Time in Patent Office: 600 Days
• Field of Search: 280/736, 280/737, 280/741, 280/740, 280/742, 222/3, 222/5, 137/68.13, 137/68.19, 137/68.23, 137/68.3, 102/530, 102/531
• US Class Current: 280/737
• CPC Class Codes: B60R 2021/2725 using a fluid fuel gas generator
• CPC Class Codes: B60R 21/264 using instantaneous generation of gas, e.g. pyrotechnic B60R21/268 takes precedence
• CPC Class Codes: B60R 21/272 with means for increasing the pressure of the gas just before or during liberation, e.g. hybrid inflators
• CPC Class Codes: C06B 45/00 Compositions or products which are defined by structure or arrangement of component of product explosive charges of particular form or shape F42B1/00, F42B3/00
• CPC Class Codes: C06B 47/00 Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
• CPC Class Codes: C06D 5/00 Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets explosive compositions containing an oxidizer, fuels for rocket engines intended for reaction with an oxidant other than air C06B

Abstract

The storage of combustible mixed fluid fuel and oxidizer in a porous matrix provides for enhanced control of fluid fueled inflators such as are used in automotive passive restraint airbag systems. By storing such in mixtures in a porous matrix having pores smaller than the quenching distance of the stored mixture the flammability of the mixture is suppressed. Storage of the mixture in a porous matrix having larger pores provides a mechanism for controlling the rate of release of the mixture, as well as providing a heat sink which helps moderate the temperature of the mixture during the filling operation, during long term storage and during the combustion process. Several inflator embodiments, with particularly advantageous structures for storing and releasing the mixture, are disclosed.

Claims

1. In an inflator for producing gas to inflate an inflatable apparatus, comprising:

an initiator;

a storage chamber containing a combustible mixture of a fluid fuel and an oxidant; and

at least one discharge outlet from the interior to the exterior of the inflator;

wherein;

activation of said initiator produces heated initiator products and results in the ignition of said combustible mixture producing a volume of combusted gas which passes through said discharge outlet to be made available to said inflatable apparatus;

the improvement comprising a solid porous matrix adapted to contain a portion of said combustible mixture is located in said storage chamber.

2. The inflator of claim 1, wherein:

a sufficient volume of said solid porous matrix is provided in said storage chamber that said matrix is capable of suppressing flame propagation in said stored combustible mixture.

3. The inflator of claim 1, wherein:

said solid porous matrix fully occupies said storage chamber.

4. The inflator of claim 3, wherein:

said solid porous matrix comprises two sections,

a first section wherein the pore size of the matrix is larger than the quenching distance of the combustible mixture, and

a second section wherein the pore size of the matrix is smaller than the quenching distance of the combustible mixture.

5. The inflator of claim 4, wherein:

said storage chamber has at least one gas outlet, which gas outlet is in fluid communication with said discharge outlet when said inflator is activated, and

said second section of said solid porous matrix is located adjacent said at least one gas outlet.

6. The inflator of claim 1, further comprising:

an auxiliary gas chamber containing an inert gas located between said storage chamber and said discharge outlet, whereby;

said combusted gas flows through said auxiliary gas chamber and mixes with said inert gas as it flows to said discharge outlet.

7. The inflator of claim 1, wherein:

the size of the pores in said porous matrix are larger than the quenching distance of said combustible mixture.

8. The inflator of claim 1, wherein:

the size of the pores in said porous matrix are smaller than the quenching distance of said combustible mixture.

9. The inflator of claim 1, wherein:

said solid porous matrix is formed from a reticulated ceramic.

10. The inflator of claim 1, wherein:

said storage chamber has at least one gas outlet, which gas outlet is in fluid communication with said discharge outlet when said inflator is activated, and

said solid porous matrix is located directly adjacent said gas outlet.

11. The inflator of claim 1, further comprising:

a combustion chamber; and

an opening means capable of providing flow communication between said storage chamber and said combustion chamber when said initiator is activated;

wherein activation of said initiator causes said opening means to provide flow communication between said storage chamber and said combustion chamber, and said heated initiator products ignite said combustible mixture in said combustion chamber.

12. The inflator of claim 11, wherein the pore size of said porous matrix is smaller than the quenching distance of said combustible mixture.

13. The inflator of claim 12, wherein said porous matrix occupies all of the space within said storage chamber.

14. The inflator of claim 11, wherein said storage chamber has an outlet in flow communication with said combustion chamber by way of said opening means, and said porous matrix is located adjacent said outlet.

15. The inflator of claim 11, wherein the pore sizes within said porous matrix are larger than the quenching distance of said combustible mixture.

16. The inflator of claim 11, wherein said porous matrix comprises a structure having at least two different zones, a first zone wherein the pore size of the porous matrix is smaller than the quenching distance of the combustible mixture, and a second zone wherein the pore size of the porous matrix is larger than the quenching distance of the combustible mixture.

17. The inflator of claim 16, wherein said storage chamber has an outlet in flow communication with said combustion chamber through said opening means, and said first zone of said porous matrix is located adjacent said outlet.

18. The inflator of claim 11, wherein said fluid fuel is selected from the group consisting of hydrogen, methane, ethane, propane, butane and mixtures thereof.

19. The inflator of claim 11, wherein said fluid fuel is selected from the group consisting of liquid alcohols, hydrocarbons, hydrocarbon derivatives and mixtures thereof.

20. The inflator of claim 11, wherein said combustible mixture contains a stoichiometric excess of the oxidant.

21. The inflator of claim 11, wherein said combustion chamber contains a fluid oxidant.

22. The inflator of claim 21, wherein said fluid oxidant comprises a mixture of oxidizing and inert gases.

23. The inflator of claim 21, wherein the combination of said combustible mixture and said fluid oxidant provides a stoichiometric excess of oxidant.

24. The inflator of claim 11, further comprising:

a structural member having an opening therein separating said storage chamber and said combustion chamber, and wherein

said opening means comprises a plug located in said opening such that activation of said initiator causes said plug to be displaced thereby establishing fluid communication between said storage chamber and said combustion chamber through said opening.

25. The inflator of claim 24, wherein a removable sealing means is provided over said opening to establish a hermetic seal.

26. The inflator of claim 25, wherein said sealing means comprises a thin metal diaphragm extending over said opening and one end of said plug.

27. The inflator of claim 24, wherein:

a rupturable seal is located between said combustion chamber and said outlet, and

said plug is located in said opening such that its displacement propels it at said rupturable seal.

28. The inflator of claim 27, wherein:

the end of said plug facing said rupturable seal is tapered.

29. The inflator of claim 11, wherein:

said combustion chamber is located in a cavity extending through said porous matrix, and

said opening means comprises a solid pyrotechnic body located in said combustion chamber.

30. The inflator of claim 29, wherein:

said solid pyrotechnic body is made of materials which are substantially consumed during ignition.

31. The inflator of claim 30, wherein:

the solid consumable pyrotechnic body essentially fully occupies said combustion chamber.

32. The inflator of claim 31, wherein:

said solid consumable pyrotechnic body extends adjacent said storage chamber whereby its consumption provides for flow communication between said storage chamber and said combustion chamber.

33. The inflator of claim 29, further comprising:

auxiliary gas chamber located adjacent said storage chamber;

a structural member containing an opening separating said storage chamber from said auxiliary gas chamber; and

a rupturable seal sealing said opening in said structural member, whereby

ignition of said solid pyrotechnic body causes said rupturable seal to break, thereby creating flow communication between said combustion chamber and said auxiliary gas chamber.

34. The inflator of claim 33, wherein:

a projectile housing extends from said opening provided in said structural member to said solid pyrotechnic body,

a projectile is provided in said projectile housing adjacent said solid pyrotechnic body, whereby

ignition of said solid pyrotechnic body causes said projectile to be propelled through said rupturable seal thereby establishing flow communication between said combustion chamber and said auxiliary gas chamber.

35. The inflator of claim 11, further comprising:

an auxiliary gas chamber containing an auxiliary gas;

said auxiliary gas chamber being located such that the combusted gas produced in the combustion chamber passes through the auxiliary gas chamber on its way to said at least one outlet.

36. The inflator of claim 35, wherein:

said auxiliary gas comprises an inert gas.

37. The inflator of claim 35, wherein:

said inert gas comprises argon.

38. The inflator of claim 35, wherein:

said auxiliary gas comprises an oxidant.

39. The inflator of claim 35, wherein:

a rupturable seal is provided between said combustion chamber and said auxiliary gas chamber.

40. The inflator of claim 35, wherein:

a rupturable seal is provided between said auxiliary gas chamber and said at least one outlet.

41. The inflator of claim 11, further comprising:

an initiator housing extending about said initiator,

a structural member separating said storage chamber from said combustion chamber, and wherein;

said opening means comprises;

a plunger mounted in said initiator housing with one end thereof adjacent said initiator, and the other end of said plunger including a protruding portion, and

a rupturable portion in said structural member;

whereby activation of said initiator causes said plunger to move in said initiator housing to a position where said protruding portion strikes and ruptures said rupturable portion thereby establishing flow communication between said storage chamber and said combustion chamber.

42. The inflator of claim 41, wherein:

said initiator housing includes an element which retains said plunger in said housing after it passes through the position at which said protruding portion strikes said rupturable portion.

43. The inflator of claim 41, wherein:

said initiator housing includes means permitting a portion of said initiator products to pass from the interior to the exterior of said initiator housing.

44. The inflator of claim 42, wherein:

said means permitting a portion of the initiator products to pass comprise holes in the side of the initiator housing extending from the interior of the housing to the exterior of the initiator housing.

45. The inflator of claim 11, further including:

a first wall separating said storage chamber from said combustion chamber,

a piston retainer comprising a side wall extending from said first wall into said storage chamber, said piston retainer having openings in its side wall,

said opening means including a piston mounted in said piston retainer;

whereby activation of said initiator results in said piston being displaced in said retainer, said displacement of the piston providing flow communication between said storage chamber and said combustion chamber via said openings in said side wall.

46. The inflator of claim 45, wherein:

said first wall includes a rupturable portion located adjacent said piston retainer.

47. The inflator of claim 46, wherein

said initiator is located in a mounting structure which extends from said initiator towards said piston, and

said opening means includes a projectile located in said mounting structure, whereby

activation of said initiator propels said projectile toward said piston causing said piston to be displaced in said piston retainer.

48. The inflator of claim 1, further comprising:

a combustion chamber located in a cavity extending through said porous matrix; and

an opening means comprising;

a solid pyrotechnic body located in said combustion chamber,

a pressure sensitive primer located adjacent said solid pyrotechnic body,

a striker which is responsive to activation of said initiator to exert pressure on said pressure sensitive primer;

whereby;

activation of said initiator causes said striker to cause ignition of said primer and said solid pyrotechnic body, resulting in the consumption of said solid pyrotechnic body allowing said combustible mixture to flow into said combustion chamber.

49. The inflator of claim 48, wherein said opening means further comprises:

a projectile located adjacent said initiator and directed toward said striker;

whereby

activation of said initiator causes said projectile to be propelled toward and collide with said striker, causing said striker to exert said pressure on said primer.

50. The inflator of claim 1, further comprising:

an auxiliary gas chamber containing a pressurized auxiliary gas;

a rupturable seal located between said auxiliary gas chamber and said at least one discharge outlet;

a projectile located adjacent said initiator and directed toward said rupturable seal;

wherein

activation of said initiator causes said projectile to be propelled toward and to rupture said rupturable seal permitting said auxiliary gas to flow from said auxiliary gas chamber to said at least one discharge outlet.

51. In a process of producing gas, comprising:

providing a combustible mixture of a fluid fuel and an oxidant,

storing said combustible mixture in a storage container,

initiating gas production by activating an initiator which produces ignition products and causes said combustible mixture to ignite and produce a combusted mixture,

the improvement comprising;

providing a solid porous matrix in said storage container said solid porous matrix being adapted to contain a portion of the combustible mixture stored in said storage container.

52. The process of claim 51, wherein:

initiating gas production further comprises

causing said combustible mixture to pass from said porous matrix into a combustion zone, and

igniting said combustible mixture by contacting it with said ignition products in said combustion zone.

53. The process of claim 52, wherein:

initiating gas production further comprises;

transmitting an electrical signal to said initiator causing it to activate and produce said ignition products,

using said ignition products to propel a projectile,

directing said projectile to contact and break a seal separating said porous matrix from said combustion zone.

54. The process of claim 52, wherein:

initiating gas production further includes;

transmitting an electrical signal to said initiator causing it to activate and produce said ignition products,

providing a pyrotechnic body adjacent said initiator,

providing a structure between said porous matrix and said combustion zone, said structure including a rupturable seal,

igniting said pyrotechnic body by contacting it with said ignition products to produce sufficient pyrotechnic ignition products to break said rupturable seal whereby flow communication between said storage container and said combustion zone is established.

55. The process of claim 51, wherein the maximum pore diameter of said porous matrix is smaller than the quenching distance of said combustible mixture.

56. The process of claim 51, further comprising:

contacting and mixing said combusted mixture with an auxiliary gas in an auxiliary gas chamber to produce said product gases.

57. The process of claim 56, wherein:

initiating gas production further includes;

transmitting an electrical signal to said initiator causing it to ignite producing said ignition products,

igniting a consumable pyrotechnic body by contacting it with said ignition products thereby producing pyrotechnic ignition reaction products and breaking a rupturable seal separating said porous matrix from said auxiliary gas chamber.

58. The process of claim 51, further comprising:

locating a combustion zone directly adjacent said porous matrix,

providing a consumable pyrotechnic body in said combustion zone, and wherein;

initiating gas production further includes;

igniting said consumable pyrotechnic body,

permitting said combustible mixture to flow from said porous matrix into said combustion zone as said consumable pyrotechnic body is consumed, and

igniting said combustible mixture as it flows into and through said combustion zone.

59. The process of claim 51, further comprising:

inflating the cushion of a vehicle airbag system with the recovered product gases.

60. The process of claim 51, wherein:

said ignition products ignite said combustible mixture in said storage chamber, and

said solid porous matrix comprises porous material having a pore size greater than the quenching distance of said combustible mixture.

61. The process of claim 51, wherein a volume of said solid porous matrix which is capable of suppressing flame propagation in said combustible mixture is provided in said storage container.