Consolidated thermite compositions

• US 5,650,590 A
• Filed: 09/25/1995
• Issued: 07/22/1997
• Est. Priority Date: 09/25/1995
• Status: Expired due to Fees

• Current Assignee: Autoliv ASP Incorporated (Autoliv Incorporated)
• Original Assignee: Morton International Incorporated (Autoliv Incorporated)
• Inventors: Taylor, Robert D.
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US08/533,112
• Time in Patent Office: 666 Days
• Field of Search: 149/37, 149/17, 149/40
• US Class Current: 149/17
• CPC Class Codes: C06B 33/12 the material being two or more oxygen-yielding compounds
• CPC Class Codes: C06D 5/00 Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets explosive compositions containing an oxidizer, fuels for rocket engines intended for reaction with an oxidant other than air C06B

Abstract

An improved heat generating thermite composition suitable for use in an inflator of a motor vehicle airbag restraint system comprises a hard consolidated pellet, grain or wafer shaped formulation of a powdered metal fuel, a powdered metal oxide oxidizer, a binder and a supplemental oxidizing agent.

Claims

1. An improved heat generating themite composition suitable for use in an inflator for an airbag restraint system of a motor vehicle, said improved thermite composition comprising a hard consolidated shaped formulation of:

a) about 20 to about 30 weight percent of a powdered metal fuel,

b) about 40 to about 70 weight percent of a powdered metal oxide oxidizer,

c) about 5 to about 25% weight percent of an essentially non gas-producing, non hot particulate-producing binder, and

d) about 2 to about 10 weight percent of a supplemental oxidizing agent, said hard consolidated shaped thermite formulation having an ignition temperature of less than about 2200°

C.

2. The improved heat generating thermite composition of claim 1 wherein the powdered metal fuel has a particle size of about 5 to 30 microns and the powdered metal oxide oxidizer has a particle size of about 0.1 to 3 microns.

3. The improved heat generating thermite composition of claim 1 wherein the binder is hydrated calcium sulfate and the supplemental oxidizing agent is selected from the group consisting of potassium perchlorate, potassium chlorate and ammonium perchlorate.

4. The improved heat generating thermite composition of claim 2 wherein the binder is hydrated calcium sulfate and the supplemental oxidizing agent is selected from the group consisting of potassium perchlorate, potassium chlorate and ammonium perchlorate.

5. The improved heat generating thermite composition of claim 1 wherein the powdered metal fuel is aluminum metal powder and the metal oxide oxidizer is ferric oxide powder.

6. The improved heat generating thermite composition of claim 2 wherein the powdered metal fuel is aluminum metal powder and the metal oxide oxidizer is ferric oxide powder.

7. The improved heat generating thermite composition of claim 3 wherein the powdered metal fuel is aluminum metal powder and the metal oxide oxidizer is ferric oxide powder.

8. The improved heat generating thermite composition of claim 4 wherein the powdered metal fuel is aluminum metal powder and the metal oxide oxidizer is ferric oxide powder.

9. The improved heat generating thermite composition of claim 1 wherein:

a) the powdered metal fuel has a particle size of from about 5 to 30 microns and is selected from the group consisting of aluminum, titanium, titanium hydride, vanadium and boron powder,

b) the powdered metal oxide oxidizer has a particle size of from about 0.1 to 3 microns and is selected from the group consisting of ferric oxide, titanium oxide, cupric oxide, cobaltic oxide, cobaltous ferrite and manganese oxide,

c) the binder is hydrated calcium sulfate in an amount of about 5 to 10% weight percent, and

d) the supplemental oxidizing agent is selected from potassium perchlorate, potassium chlorate and ammonium perchlorate and is present in an amount of from about 5 to about 10 weight percent.

10. The improved heat generating thermite composition of claim 8 comprising about 26.94 weight percent aluminum metal powder, about 61.06 weight percent ferric oxide, about 10 weight percent hydrated calcium sulfate and about 2 weight percent potassium perchlorate.