Optical oxygen concentration monitor

• US 5,650,845 A
• Filed: 05/18/1995
• Issued: 07/22/1997
• Est. Priority Date: 05/18/1995
• Status: Expired due to Term

• Current Assignee: Aerodyne Corporation
• Original Assignee: Aerodyne Corporation
• Inventors: Kebabian, Paul
• Primary Examiner(s): McGraw, Vincent P.
• Application Number:
  US08/444,820
• Time in Patent Office: 796 Days
• Field of Search: 356/307, 356/436, 356/437, 356/435, 250/339.13, 250/345
• US Class Current: 356/307
• CPC Class Codes: G01N 21/3103 Atomic absorption analysis

Abstract

A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen'"'"'s A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

Claims

1. A system for determining the concentration of oxygen in an environment of interest, the system including:

A. an argon discharge lamp for selectively supplying to the environment of interest light in a spectral line having a wavelength of approximately 763.5 nm, which is close to a spectral absorption line of oxygen; and

B. means for determining the concentration of oxygen in the environment of interest based on variations in optical flux in the light supplied by the lamp to the environment of interest.

2. The system of claim 1 further including:

A. a magnetic field source for supplying a magnetic field that splits the light supplied by the lamp into a set of upshifted components with wavelengths that are readily absorbed by the oxygen line and a set of downshifted components with wavelengths that not as readily absorbed by the oxygen line;

B. a polarization modulator for selectively passing to the environment of interest the upshifted components or the downshifted components; and

C. the means for determining the concentration of oxygen in the environment of interest determines the concentration based on variations in the transmitted optical flux of the light when the set of upshifted components is supplied to the environment of interest.

3. The system of claim 2, wherein the means for determining the concentration of oxygen includes:

i. a first photodiode for producing a signal that is proportional to the transmitted optical flux of the set of upshifted components that has not passed through the environment of interest;

ii. a second photodiode for producing a signal that is proportional to the transmitted optical flux of the set of upshifted components that has passed through the environment of interest; and

iii. means for determining, from the differences in the signals produced by the first and the second photodiodes, the concentration of oxygen in the environment of interest.

4. The system of claim 3, wherein:

iv. the first photodiode produces a signal that is proportional to the transmitted optical flux of the set of downshifted components that has not passed through the environment of interest;

v. the second photodiode produces a signal that is proportional to the transmitted optical flux of the set of downshifted components that has passed through the environment of interest; and

vi. the means for determining, based on the differences in the signals produced by the first and the second photodiodes in response to the set of downshifted components, determines corrections to be included in determining the concentration of oxygen based on the signals associated with the set of upshifted components.

5. The system of claim 4, wherein the means for determining the concentration of oxygen includes a bridge that includes the two photodiodes, the means electrically balancing the bridge when the set of downshifted components are passed to the environment of interest, the means further producing a signal that is proportional to the concentration of oxygen in the environment of interest when the set of upshifted components are passed to the environment of interest.

6. The system of claim 5, wherein the means for determining the concentration of oxygen determines if the concentration exceeds or falls below a predetermined level by determining if the output signal produced by the bridge exceeds or falls below a predetermined value.

7. The system of claim 2, wherein the means for determining the concentration of oxygen determines if the concentration exceeds or falls below a predetermined level.

8. The system of claim 2, wherein the polarization modulator includes:

i. means for linearizing a circular polarization of the upshifted and downshifted components;

ii. rotating means for selectively rotating the components, the rotating means operating in a first mode in which it refrains from rotating the components and in a second mode in which it rotates the components such that the upshifted components and downshifted components, respectively, have polarizations that are the opposite of the polarizations they had when the rotating means is operating in the first mode; and

iii. a linear polarizer for passing the components having a particular polarization and refraining from passing the components that do not have the particular polarization.

9. The system of claim 2 wherein the polarization modulator includes:

i. means for controlling the magnetic field source, such that the magnetic field source selectively reverses the polarity of the magnetic field and produces upshifted and downshifted components of reversed circular polarizations; and

ii. a circular polarizer, for passing components of a particular circular polarization and refraining from passing components that do not have the particular circular polarization.

10. The system of claim 2 wherein the polarization modulator includes means for selectively turning on and off the magnetic field source, such that the light produced by the lamp is selectively split into the sets of upshifted and downshifted components and not split into the sets of components, the polarization modulator alternately passing to the environment of interest the split components and the unsplit components.

11. A system for determining the concentration of oxygen in an environment of interest, the system including:

A. an argon discharge lamp for supplying light to the environment of interest;

B. a magnetic field source for supplying a magnetic field that splits the light supplied by the lamp into a set of upshifted components with wavelengths that are readily absorbed by an oxygen absorption spectral line and a set of downshifted components with wavelengths that are not as readily absorbed by the oxygen absorption line;

C. control means for selectively controlling the magnetic field source to provide a magnetic field of one polarity or a reverse polarity, the polarity of the magnetic field determining the circular polarizations of the sets of upshifted and downshifted components;

D. a circular polarizer for selectively passing to the environment of interest the set of upshifted components or the set the downshifted components, depending on the orientations of the circular polarizations; and

E. means for determining the concentration of oxygen in the environment of interest based on variations in the transmitted optical flux of the argon line when the set of upshifted components is supplied to the environment of interest.

12. A system for determining the concentration of oxygen in an environment of interest, the system including:

A. an argon discharge lamp for supplying light to the environment of interest;

B. a magnetic field source for supply a magnetic field that splits the light supplied by the lamp into a set of upshifted components with wavelengths that are readily absorbed by an oxygen absorption spectral line and a set of downshifted components with wavelengths that not as readily absorbed by the oxygen absorption line;

C. control means for selectively turning on the magnetic field source and turning off the magnetic field source;

D. means for determining the concentration of oxygen in the environment of interest based on variations in the transmitted optical flux of the argon line between (i) the sets of upshifted and downshifted components being supplied to the environment of interest when the magnetic field source is turned on, and (ii) unshifted light being supplied to the environment of interest when the magnetic field source is turned off.

13. A system for determining the concentration of oxygen in an environment of interest, the system including:

A. an argon discharge lamp for supplying light to the environment of interest;

B. a magnetic field source for supplying a magnetic field to the environment of interest, the magnetic field splitting an oxygen spectral line into a set of downshifted components with wavelengths that readily absorb a spectral line in the light produced by the argon lamp and a set of upshifted components with wavelengths that do not as readily absorb the spectral line;

C. control means for selectively turning on the magnetic field source and turning off the magnetic field source;

D. means for determining the concentration of oxygen in the environment of interest based on variations in the transmitted optical flux of the light between times when (i) the magnetic field source is turned on and sets of upshifted and downshifted components are present in the environment of interest, and (ii) the magnetic field source is turned off and unshifted components are present in the environment of interest.