Method and composition for removing semi-permanent color from human hair

• US 5,651,960 A
• Filed: 09/22/1995
• Issued: 07/29/1997
• Est. Priority Date: 09/22/1995
• Status: Expired due to Term

• Current Assignee: Helene Curtis Inc. (Unilever PLC)
• Original Assignee: Helene Curtis Inc. (Unilever PLC)
• Inventors: Chan, Alexander C., Pascual, Fe P.
• Primary Examiner(s): Gardner, Salle M.
• Application Number:
  US08/532,252
• Time in Patent Office: 676 Days
• Field of Search: 424/70.6, 424/62, 8/405, 132/208
• US Class Current: 424/70.6
• CPC Class Codes: A61K 8/447 containing sulfur
• CPC Class Codes: A61K 8/46 containing sulfur A61K8/44 takes precedence
• CPC Class Codes: A61Q 5/08 Preparations for bleaching the hair

Abstract

The invention is an aqueous composition for removing coloring from hair treated with semipermanent hair colorant. The composition includes a reducing agent, at least one alcohol, water and an alkaline compound. A sufficient amount of the alkaline compound is employed to maintain the pH of the composition in the range of about 9.0 to about 11.0. The invention also includes a method of removing, or bleaching, colorant from semipermanent colored hair. The method includes applying the aqueous composition to semi-permanently colored hair producing bleached hair. Lastly, the bleached hair is rinsed and shampooed.

Claims

1. A method of removing coloring from semipermanent color-treated hair comprising the steps of:

providing a composition comprising a reducing agent which is an organic compound containing at least one mercapto group capable of reducing sulfur in human hair, at least one alcohol, water and an alkaline compound which is ammonium hydroxide in an amount sufficient to maintain the pH of the composition in the range of about 8.0 to about 11.0;

providing semipermanent color-treated hair having a predetermined concentration of dye;

applying the composition to the color-treated hair producing a color-stripped hair; and

rinsing or shampooing the color-stripped hair after a time sufficient to remove a portion of the dye producing a de-colored hair.

2. The method of claim 1 wherein the reducing agent is a member selected from the group consisting of thioglycolic acid, a salt of thioglycolic acid, 2-mercaptopropionic acid, a salt of 2-mercaptopropionic acid, β

-mercaptopropionic acid, a salt of β

-mercaptopropionic acid, 2-mercaptoethanol, 3-mercapto-1,2-propanediol, 1,3-dimercapto-2-propanol, 1,4-dimercapto-2-butanol, 1,3-dimercapto-2-methoxypropane, 1,3-dimercapto-2-aminopropane, 1,4-dimercapto-2,3-diaminobutane, glycerol monomercaptoacetate, cysteamine, an acid salt of cysteamine and combinations thereof.

3. The method of claim 2 wherein the reducing agent is an ammonium salt of thioglycolic acid or cysteamine HCl salt.

4. The method of claim 1 wherein the reducing agent comprises in the range of 0.1 to 10.0% by weight of the composition and the alcohol comprises in the range of 0.1 to 25% by weight of the composition.

5. The method of claim 1 wherein the reducing agent comprises in the range of 1.0 to 4.0% by weight of the composition and the alcohol comprises in the range of 1.0 to 10.0% by weight of the composition.

6. The method of claim 1 wherein the alcohol is an alcohol having a C_1-6 straight or branched chain, or combinations thereof.

7. The method of claim 1 wherein the alcohol is selected from the group consisting of ethyl alcohol, isopropyl alcohol, benzyl alcohol, hexyl alcohol and combinations thereof.

8. The method of claim 1 wherein the composition further includes a soap, a solvent, a conditioner, a surfactant, a thickener, an alkalizing agent, a fragrance, a buffer, or a combination thereof compatible with the reducing agent.

9. The method of claim 8 wherein the soap is sodium lauryl sulfate or sodium stearyl sulfate, the water is deionized, and the alkaline compound is a solution of ammonium hydroxide in an amount sufficient to maintain the pH of the composition in the range of about 9.0 to about 10.0.

10. A method of removing coloring from semipermanent color-treated hair comprising the steps of:

providing a composition comprising thioglycolic acid or a salt thereof, at least one alcohol, sodium lauryl sulfate or sodium stearyl sulfate, deionized water and an alkaline compound which is ammonium hydroxide in an amount sufficient to maintain the pH of the composition in the range of about 9.0 to about 10.0;

providing semipermanent color-treated hair having a predetermined concentration of dye;

applying the composition to the color-treated hair producing a color-stripped hair; and

shampooing the color-stripped hair after a time sufficient to remove a portion of the dye producing a de-colored hair; and

,

rinsing the de-colored hair with water.