Fabric softener compositions with improved environmental impact

• US 5,652,206 A
• Filed: 02/26/1996
• Issued: 07/29/1997
• Est. Priority Date: 02/26/1996
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Trinh, Toan, Chung, Alex Haejoon, Bacon, Dennis Ray
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US08/605,482
• Time in Patent Office: 519 Days
• Field of Search: 510/513, 510/518, 510/521, 510/522, 510/527, 510/524, 510/101, 510/102, 510/103, 510/104, 510/105, 510/106, 510/107
• US Class Current: 510/101
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 3/001 Softening compositions
• CPC Class Codes: C11D 3/50 Perfumes

Abstract

The present invention relates to liquid and solid biodegradable fabric softener compositions combined with highly enduring substantive perfume compositions. These enduring perfume compositions comprise at least about 70% of enduring perfume ingredients. These compositions provide better perfume deposition on treated fabric, and consequently are not substantially lost during the rinse and drying cycle for less impact on the environment. Also, these perfumes improve the physical stability of the softener composition.

Claims

1. A rinse-added fabric softening composition selected from the group consisting of:

I. a solid particulate composition comprising;

(A) from about 50% to about 95% of biodegradable cationic quaternary ammonium fabric softening compound;

(B) from about 0.01% to about 15% of an enduring perfume comprising at least 70% of enduring perfume ingredients selected from the group consisting of;

ingredients having a boiling point of at least about 250°

C. and a ClogP of at least about 3, wherein ClogP is the calculated octanol/water partitioning coefficient as the logarithm to the base 10, logP, said ingredients having a boiling point of at least about 250°

C. and a ClogP of at least about 3 being less than 70% by weight of said enduring perfume so that a perfume with only ingredients having a boiling point of at least about 250°

C. and a ClogP of at least about 3 will not be an enduring perfume;

cis-jasmone;

dimethyl benzyl carbinyl acetate;

ethyl vanillin;

geranyl acetate;

alpha-ionone;

beta-ionone;

gamma-ionone;

koavone;

lauric aldehyde;

methyl dihydrojasmonate;

methyl nonyl acetaldehyde;

gamma-nonalactone;

phenoxy ethyl iso-butyrate;

phenyl ethyl dimethyl carbinol;

phenyl ethyl dimethyl carbinyl acetate;

alpha-methyl-4-(2-methylpropyl)-benzenepropanal;

6-acetyl-1,1,3,4,4,6-hexamethyl tetrahydronaphthalene;

undecylenic aldehyde;

vanillin;

2,5,5-trimethyl-2-pentyl-cyclopentanone;

2-tert-butylcyclohexanol;

verdox;

para-tert-butylcyclohexyl acetate; and

mixtures thereof;

(C) optionally, from about 0% to about 30% of dispersibility modifier; and

(D) optionally, from about 0% to about 15% of a pH modifier; and

II. a liquid composition comprising;

(A) from about 0.5% to about 80% of biodegradable cationic fabric softening compound;

(B) from about 0.01% to about 10% of an enduring perfume comprising at least 70% of enduring perfume ingredients selected from the group consisting of;

ingredients having a boiling point of at least about 250°

C. and a ClogP of at least about 3, said ingredients having a boiling point of at least about 250°

C. and a ClogP of at least about 3 being less than 70% by weight of said enduring perfume so that a perfume with only ingredients having a boiling point of at least about 250°

C. and a ClogP of at least about 3 will not be an enduring perfume;

cis-jasmone;

dimethyl benzyl carbinyl acetate;

ethyl vanillin;

geranyl acetate;

alpha-ionone;

beta-ionone;

gamma-ionone;

koavone;

lauric aldehyde;

methyl dihydrojasmonate;

methyl nonyl acetaldehyde;

gamma-nonalactone;

phenoxy ethyl iso-butyrate;

phenyl ethyl dimethyl carbinol;

phenyl ethyl dimethyl carbinyl acetate;

alpha-methyl-4-(2-methylpropyl)-benzenepropanal;

6-acetyl-1,1,3,4,4,6-hexamethyl tetrahydronaphthalene;

undecylenic aldehyde;

vanillin;

2,5,5-trimethyl-2-pentyl-cyclopentanone;

2-tert-butylcyclohexanol;

verdox;

para-tert-butlylcyclohexyl acetate; and

mixtures thereof;

(C) optionally, from about 0% to about 30% of dispersibility modifier; and

(D) the balance comprising a liquid carrier selected from the group consisting of;

water, C_1-4 monohydric alcohol;

C_2-6 polyhydric alcohol;

propylene carbonate;

liquid polyethylene glycols; and

mixtures thereof;

and wherein the dispersibility modifier affects the viscosity, dispersibility or both.

2. The composition of claim 1 wherein the quaternary ammonium fabric softening compound has the formula:

space="preserve" listing-type="equation">(R).sub.4-m -.sup.+ N-[(CH.sub.2).sub.n -Y-R.sup.2 ].sub.m X.sup.-

wherein;

each Y is --O--(O)C--, or --C(O)--O--;

m is 2 or 3;

n is 1 to 4;

each R is a C₁ -C₆ alkyl group, hydroxyalkyl group, benzyl group, or mixtures thereof;

each R² is a C₁₂ -C₂₂ hydrocarbyl or substituted hydrocarbyl substituent; and

X^- is any softener-compatible anion.

3. The composition of claim 2 wherein the quaternary ammonium compound is derived from C₁₂ -C₂₂ fatty acyl groups having an Iodine Value of from greater than about 5 to less than about 100, a cis/trans isomer weight ratio of greater than about 30/70 when the Iodine Value is less than about 25, the level of unsaturation of the fatty acyl groups being less than about 65% by weight.

4. The composition of claim 2 wherein the enduring perfume has less than about 65% of the total weight of ingredients with a ClogP≧

3.0 and a boiling point of ≧

250°

C.

5. The composition of claim 4 wherein the enduring perfume has at least about 75% of said enduring perfume ingredients.

6. The composition of claim 5 wherein the enduring perfume has at least about 80% of said enduring perfume ingredients.

7. The composition of claim 6 wherein the enduring perfume has at least about 85% of said enduring perfume ingredients.

8. The composition of claim 1 wherein the enduring perfume has less than about 65% of the total weight of ingredients with a ClogP≧

3.0 and a boiling point of ≧

250°

C.

9. The composition of claim 8 wherein the the enduring perfume has a least about 75% of said enduring perfume ingredients.

10. The composition of claim 9 wherein the enduring perfume has at least about 80% of said enduring perfume ingredients.

11. The composition of claim 10 wherein the enduring perfume has at least about 85% of said enduring perfume ingredients.

12. The composition of claim 1 wherein said enduring perfume is present in an amount of from about 0.05% to about 8%.

13. The composition of claim 12 wherein said enduring perfume is present in an amount of from about 0.1% to about 6%.

14. The composition of claim 13 wherein said enduring perfume is present in an amount of from about 0.15% to about 4%.

15. The composition of claim 13 wherein the enduring perfume has less than about 65% of the total weight of ingredients with a ClogP≧

3.0 and a boiling point of ≧

250°

C.

16. The composition of claim 15 wherein the enduring perfume has a least about 85% of said enduring perfume ingredients.

17. The composition of claim 12 wherein the enduring perfume has a least about 75% of said enduring perfume ingredients.

18. The composition of claim 1 wherein said dispersibility modifier is selected from the group consisting of:

single-long-chain-C₁₀ -C₂₂ alkyl, cationic surfactant;

nonionic surfactant with at least 8 ethoxy moieties;

amine oxide surfactant; and

mixtures thereof.

19. The composition according to claim 18 wherein the dispersibility modifier is a single-long-chain-C₁₀ -C₂₂ alkyl cationic surfactant at an effective level to affect the viscosity, dispersibility or both of the composition of up to about 15% of the composition.

20. The composition according to claim 19 wherein the dispersibility modifier is a quaternary ammonium salt of the general formula:

space="preserve" listing-type="equation">[R.sup.2 N.sup.+ R.sub.3 ]X.sup.-

wherein the R² group is a C₁₀ -C₂₂ hydrocarbon group, or a group with a short alkylene (C₁ -C₄) group between an ester linkage and the N, and having a C₁₀ -C₂₂ hydrocarbon group, each R is a C₁ -C₄ alkyl or substituted alkyl, or hydrogen; and

the counterion X^- is a softener compatible anion.

21. The composition according to claim 18 wherein the dispersibility modifier is C₁₂ -C₁₄ choline ester.

22. The composition according to claim 18 wherein the dispersibility modifier is a nonionic surfactant at an effective level to affect the viscosity, dispersibility or both of the composition of up to about 20% of the composition.

23. The composition according to claim 22 wherein the dispersibility modifier is C_10-14 alcohol with poly(10-18)ethoxylate.

24. The composition of claim 1 wherein said enduring perfume contains at least 5% of materials selected from the group consisting of:

cis-jasmone;

dimethyl benzyl carbinyl acetate;

ethyl vanillin;

geranyl acetate;

alpha-ionone;

beta-ionone;

gamma-ionone;

koavone;

lauric aldehyde;

methyl dihydrojasmonate;

methyl nonyl acetaldehyde;

gamma-nonalactone;

phenoxy ethyl iso-butyrate;

phenyl ethyl dimethyl carbinol;

phenyl ethyl dimethyl carbinyl acetate;

alpha-methyl-4-(2-methylpropyl)-benzenepropanal;

6-acetyl-1,1,3,4,4,6-hexamethyl tetrahydronaphthalene;

undecylenic aldehyde;

vanillin;

2,5,5-trimethyl-2-pentyl-cyclopentanone;

2-tert-butylcyclohexanol;

verdox;

para-tert-butylcyclohexyl acetate; and

mixtures thereof.

25. The composition of claim 1 wherein the composition is a solid particulate composition comprising:

(A) from about 60% to about 90% of biodegradable cationic quaternary ammonium fabric softening compound;

(B) from about 0.05% to about 8% of an enduring perfume comprising at least 70% of enduring perfume ingredients selected from the group consisting of;

ingredients having a boiling point of at least about 250°

C. and a ClogP of at least about 3, said ingredients having a boiling point of at least about 250°

C. and a ClogP of at least about 3 being less than 70% by weight of said enduring perfume so that a perfume with only ingredients having a boiling point of at least about 250°

C. and a ClogP of at least about 3 will not be an enduring perfume;

cis-jasmone;

dimethyl benzyl carbinyl acetate;

ethyl vanillin;

geranyl acetate;

alpha-ionone;

beta-ionone;

gamma-ionone;

koavone;

lauric aldehyde;

methyl dihydrojasmonate;

methyl nonyl acetaldehyde;

gamma-nonalactone;

phenoxy ethyl iso-butyrate;

phenyl ethyl dimethyl carbinol;

phenyl ethyl dimethyl carbinyl acetate;

alpha-methyl-4-(2-methylpropyl)-benzenepropanal;

6-acetyl-1,1,3,4,4,6-hexamethyl tetrahydronaphthalene;

undecylenic aldehyde;

vanillin;

2,5,5-trimethyl-2-pentyl-cyclopentanone;

2-tert-butylcyclohexanol;

verdox;

para-tert-butylcyclohexyl acetate; and

mixtures thereof;

(C) from 3% to about 15% of dispersibility modifier; and

(D) optionally, from 0% to about 10% of pH modifier.

26. The composition of claim 1 wherein the composition is a liquid composition comprising:

(A) from about 1% to about 35% of biodegradable cationic quaternary ammonium fabric softening compound;

(B) from about 0.05% to about 6% of an enduring perfume comprising at least 70% of enduring perfume ingredients selected from the group consisting of;

ingredients having a boiling point of at least about 250°

C. and a ClogP of at least about 3, said ingredients having a boiling point of at least about 250°

C. and a ClogP of at least about 3 being less than 70% by weight of said enduring perfume so that a perfume with only ingredients having a boiling point of at least about 250°

C. and a ClogP of at least about 3 will not be an enduring perfume;

cis-jasmone;

dimethyl benzyl carbinyl acetate;

ethyl vanillin;

geranyl acetate;

alpha-ionone;

beta-iononie;

gamma-ionone;

koavone;

lauric aldehyde;

methyl dihydrojasmonate;

methyl nonyl acetaldehyde;

gamma-nonalactone;

phenoxy ethyl iso-butyrate;

phenyl ethyl dimethyl carbinol;

phenyl ethyl dimethyl carbinyl acetate;

alpha-methyl-4-(2-methylpropyl)-benzenepropanal;

6-acetyl-1,1,3,4,4,6-hexamethyl tetrahydronaphthalene;

undecylenic aldehyde;

vanillin;

2,5,5-trimethyl-2-pentyl-cyclopentanone;

2-tert-butylcyclohexanol;

verdox;

para-tert-butylcyclohexyl acetate; and

mixtures thereof;

(C) from about 0.5% to about 10% of dispersibility modifier wherein the dispersibility modifier affects the composition'"'"'s viscosity, dispersibility in a laundry process rinse cycle, or both; and

(D) the balance comprising a liquid carrier selected from the group consisting of water;

C₁ -C₄ monohydric alcohols;

C₂ -C₆ polyhydric alcohols;

propylene carbonate;

liquid polyalkylene glycols; and

mixtures thereof.