Magnetic strips and methods for making the same

• US 5,653,824 A
• Filed: 02/26/1996
• Issued: 08/05/1997
• Est. Priority Date: 08/30/1993
• Status: Expired due to Fees

• Current Assignee: The Arnold Engineering Co. (The Kattegat Trust Co. Ltd.)
• Original Assignee: The Arnold Engineering Co. (The Kattegat Trust Co. Ltd.)
• Inventors: Anderson, Richard L., Manning, Neil R.
• Primary Examiner(s): Wyszomierski, George
• Application Number:
  US08/605,463
• Time in Patent Office: 526 Days
• Field of Search: 148/306, 148/307, 340/551, 340/572
• US Class Current: 148/306
• CPC Class Codes: C21D 1/18 Hardening C21D1/02 takes precedence; Quenching with or without subsequent tempering quenching devices C21D1/62
• CPC Class Codes: C21D 2211/008 Martensite
• CPC Class Codes: C21D 6/002 containing Cr C21D6/004 takes precedence
• CPC Class Codes: C21D 8/12 during manufacturing of articles with special electromagnetic properties
• CPC Class Codes: C21D 8/1255 with diffusion of elements, e.g. decarburising, nitriding
• CPC Class Codes: C23C 8/22 of ferrous surfaces
• CPC Class Codes: G08B 13/2408 using ferromagnetic tags
• CPC Class Codes: G08B 13/244 Tag manufacturing, e.g. continuous manufacturing processes
• CPC Class Codes: G08B 13/2442 Tag materials and material properties thereof, e.g. magnetic material details
• CPC Class Codes: H01F 1/147 Alloys characterised by their composition treatment thereof for enhancing their electromagnetic properties C21D8/12
• CPC Class Codes: H01F 1/14775 in the form of sheets
• CPC Class Codes: H01F 1/16 in the form of sheets H01F1/147 takes precedence

Abstract

Methods for preparing magnetic strips are provided in which the strips are manufactured to a thickness of less than about 0.005 inches and are made of a ferrous alloy having a carbon content of from about 0.4 to about 1.2 weight percent. The strips can be prepared by first manufacturing an alloy having a carbon content below about 0.5 weight percent to the desired thickness and then subjecting the strip to a carburizing step to raise the carbon content in the strip. The strips can also be prepared by controlling the chemistry of the initial alloy and controlling the processing of that alloy until the desired thickness and requisite magnetic properties are obtained. The strips are particularly useful in EAS systems.

Claims

1. A thin magnetic strip that is readily slit and that exhibits superior magnetic properties, comprising a ferrous alloy strip having a thickness of between about 0.0005 and 0.003 inches, said strip consisting essentially of at least about 85 weight percent iron, from about 0.45 to about 0.7 weight percent carbon, from about 3 to about 6 weight percent chromium, from about 0.1 to about 2 weight percent molybdenum, and optionally from about 0.05 to about 1 weight percent vanadium, from about 0.2 to about 2 weight percent manganese, and from about 0.2 to about 2 weight percent silicon, said strip having a coercive level of at least 40 oersteds, a residual induction of at least 7,000 gauss, and a flux of at least about 65 maxwells.

2. The thin magnetic strip of claim 1 wherein the strip comprises from about 3.5 to about 5 weight percent chromium and from 0.3 to about 1.5 weight percent molybdenum.

3. The thin magnetic strip of claim 2 wherein the thickness of the strip is less than 0.002 inches.

4. The thin magnetic strip of claim 1 wherein the residual induction is at least 9,000 gauss.

5. The thin magnetic strip of claim 4 wherein the coercive level is at least about 45 oersteds.

6. The thin magnetic strip of claim 5 wherein the strip comprises from about 3.5 to about 5 weight percent chromium and from 0.3 to about 1.5 weight percent molybdenum.

7. The thin magnetic strip of claim 6 wherein the strip is essentially free of cobalt.

8. The thin magnetic strip of claim 6 wherein the thickness of the strip is less than 0.002 inches.

9. A marker for use in an electronic article surveillance system, comprising:

(a) a semi-hard magnetic element comprising a ferrous alloy strip having a thickness of between 0.0005 and 0.003 inches, said strip consisting essentially of at least about 85 weight percent iron, from about 0.45 to about 0.7 weight percent carbon, from about 3 to about 6 weight percent chromium, from about 0.1 to about 2 weight percent molybdenum, and optionally from about 0.05 to about 1 weight percent vanadium, from about 0.2 to about 2 weight percent manganese, and from about 0.2 to about 2 weight percent silicon, said strip having a coercive level of at least 40 oersteds, a residual induction of at least 7,000 gauss, and a flux of at least about 65 maxwells; and

(b) a soft magnetic element disposed adjacent to said semi-hard magnetic element.

10. The marker of claim 9 wherein said ferrous alloy strip has a residual induction of at least 9,000 gauss.

11. The marker of claim 10 wherein said ferrous alloy strip is essentially free of cobalt.

12. An electronic article surveillance system for detecting the presence of a tag in a detection zone comprising:

(a) a marker comprising;

(i) a semi-hard magnetic element comprising a ferrous alloy strip having a thickness of between 0.0005 and 0.003 inches, said strip consisting essentially of at least about 85 weight percent iron, from about 0.45 to about 0.7 weight percent carbon, from about 3 to about 6 weight percent chromium, from about 0.1 to about 2 weight percent molybdenum, and optionally from about 0.05 to about 1 weight percent vanadium, from about 0.2 to about 2 weight percent manganese, and from about 0.2 to about 2 weight percent silicon, said strip having a coercive level of at least 40 oersteds, a residual induction of at least 7,000 gauss, and a flux of at least about 65 maxwells;

(ii) a soft magnetic element disposed adjacent to said semi-hard magnetic element; and

(b) means for detecting the presence of said marker in said detection zone.