Electroluminescent device comprising a chromophoric polymeric composition

• US 5,653,914 A
• Filed: 10/02/1995
• Issued: 08/05/1997
• Est. Priority Date: 12/18/1992
• Status: Expired due to Fees

• Current Assignee: IPIFS Guarantee Corp.
• Original Assignee: Cambridge Display Technology Limited (Sumitomo Chemical Company Limited)
• Inventors: Kraft, Arno, Gruener, Johannes, Friend, Richard Henry, Burn, Paul Leslie, Bradley, Donal Donat Conor, Holmes, Andrew Bruce, Brown, Adam Richard, Moratti, Stephen Carl, Cacialli, Franco, Greenham, Neil Clement, Martens, Josef Herbert Ferdinand
• Primary Examiner(s): KOSLOW, CAROL M
• Application Number:
  US08/481,379
• Time in Patent Office: 673 Days
• Field of Search: 252/301.46, 252/301.35, 313/509, 428/690
• US Class Current: 252/301.16
• CPC Class Codes: C09K 11/06 containing organic luminescent materials
• CPC Class Codes: H05B 33/14 characterised by the chemical or physical composition or the arrangement of the electroluminescent material , or by the simultaneous addition of the electroluminescent material in or onto the light source

Abstract

An electroluminescent device is provided incorporating an emissive layer comprising a processible polymer matrix such as poly(methylmethacrylate) and a chromophoric component such as an asymmetric stilbene or distyrylbenzene. The chromophoric component is blended with the polymer matrix or covalently attached thereto as a side chain and is selected to emit radiation in the region 400 nm to 500 nm when excited to luminesce.

Claims

1. An electroluminescent device incorporating an emissive layer comprising a processible polymer matrix and a chromophoric component which emits radiation in the region of 400-500 nm when excited to luminesce, wherein the chromophoric component is blended with the polymer matrix or covalently attached thereto as a side group and is selected from stilbene or distyrylbenzene, where at least one ring of stilbene or distyrylbenzene is substituted with a solubilizing group.

2. An electroluminescent device according to claim 1, wherein the chromophoric component is selected to emit radiation in the region 430 nm to 480 nm.

3. An electroluminescent device according to claim 1, wherein aromatic groups of stilbene or distyrylbenzene are linked by a double bond in trans conformation.

4. An electroluminescent device according to claim 1, wherein the stilbene or distyrylbenzene is covalently attached to the polymer matrix by a non-conjugated spacer region.

5. An electroluminescent device according to claim 1, wherein the stilbene or distyrylbenzene is asymmetric.

6. An electroluminescent device according to claim 1, wherein the polymer matrix comprises poly(methylmethacrylate).

7. An electroluminescent device according to claim 1, wherein the chromophoric component forms at least a part of a chromophoric polymer and is blended with the polymer matrix.

8. An electroluminescent device according to claim 1, wherein the polymer matrix comprises poly(methylmethacrylate), polycarbonate or polystyrene.