Protective coatings for sensitive materials

• US 5,654,084 A
• Filed: 07/22/1994
• Issued: 08/05/1997
• Est. Priority Date: 07/22/1994
• Status: Expired due to Term

• Current Assignee: Martin Marietta Energy Systems, Inc. (Martin Marietta Corporation)
• Original Assignee: Martin Marietta Energy Systems, Inc. (Martin Marietta Corporation)
• Inventors: Egert, Charles M.
• Primary Examiner(s): Nakarani, D. S.
• Application Number:
  US08/278,836
• Time in Patent Office: 1,110 Days
• Field of Search: 428/422, 428/423.1, 428/446, 428/457, 428/458, 428/460, 428/461, 428/463, 428/474.4, 428/933, 428/688, 428/689, 428/696, 428/697, 428/699, 428/701, 428/213, 428/215 , 428/216, 428/332, 428/334, 106/14.05, 106/14.34, 106/14.41
• US Class Current: 428/215
• CPC Class Codes: B05D 1/60 Deposition of organic layers from vapour phase vapour phase deposition in general C23C14/00, C23C16/00
• CPC Class Codes: B05D 7/58 No clear coat specified
• CPC Class Codes: Y10S 428/933 Sacrificial component
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/26 Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/263 Coating layer not in excess of 5 mils thick or equivalent
• CPC Class Codes: Y10T 428/31544 Addition polymer is perhalogenated
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
• CPC Class Codes: Y10T 428/31688 Next to aldehyde or ketone condensation product
• CPC Class Codes: Y10T 428/31692 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31699 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31725 Of polyamide

Abstract

An enhanced protective coating to prevent interaction between constituents of the environment and devices that can be damaged by those constituents. This coating is provided by applying a synergistic combination of diffusion barrier and physical barrier materials. These materials can be, for example, in the form of a plurality of layers of a diffusion barrier and a physical barrier, with these barrier layers being alternated. Further protection in certain instances is provided by including at least one layer of a getter material to actually react with one or more of the deleterious constituents. The coating is illustrated by using alternating layers of an organic coating (such as Parylene-C™) as the diffusion barrier, and a metal coating (such as aluminum) as the physical barrier. For best results there needs to be more than one of at least one of the constituent layers.

Claims

1. A protective coating for preventing corrosion by deleterious interaction between constituents of an environment and a substrate material placed within that environment, said coating comprising:

a plurality of continuous layers of a diffusion barrier material that is solid in the environment to deter diffusion of the constituents toward the substrate material;

a plurality of continuous layers of a physical barrier material interleaved with said continuous layers of diffusion barrier material to deter transport of the constituents toward the substrate material; and

at least one continuous layer of a getter material disposed between one of said plurality of continuous layers of said diffusion barrier material and one of said plurality of continuous layers of said physical barrier material to interact with at least one of the constituents of the environment.

2. The protective coating of claim 1 wherein said physical barrier material is selected from the group consisting of metals and ceramics.

3. The protective coating of claim 2 wherein said physical barrier material is a metal selected from the group consisting of aluminum, gold, silicon and molybdenum.

4. The protective coating of claim 2 wherein said physical barrier material is a ceramic selected from the group consisting of silicon dioxide, silicon carbide, aluminum oxide and magnesium fluoride.

5. The protective coating of claim 1 wherein said diffusion barrier material is selected from the group consisting of polyamides, polyethylenes, poly (p-xylylene)s, fluoropolymers, polyacrylates, silicone polymers, polyurethanes, a carbon exhibiting properties similar to diamond, amorphous carbon and silicon.

6. The protective coating of claim 1 wherein said plurality of continuous layers of said diffusion barrier material and said plurality of continuous layers of said physical barrier material are formed in situ upon the substrate.

7. The protective coating of claim 1 wherein said plurality of continuous layers of said diffusion barrier material and said physical barrier material are preformed for subsequent encapsulation of the substrate.

8. The protective coating of claim 1 wherein each said diffusion barrier layer and said physical barrier layer has a thickness of about 0.5 to about 100 micrometers.

9. The protective coating of claim 1 further comprising a plurality of continuous layers of a getter material interleaved between said plurality of continuous layers of said diffusion barrier material and said plurality of continuous layers of said physical barrier material.

10. The protective coating of claim 1 wherein said diffusion barrier material is a poly(p-xylylene) and said physical barrier material is aluminum.

11. A protective coating for preventing corrosion by deleterious interaction between constituents of an environment and a substrate material placed within that environment, said coating comprising;

a plurality of continuous layers of a diffusion barrier material that is solid in the environment to deter diffusion of the constituents toward the substrate material;

a plurality of continuous layers of a physical barrier material to deter transport of the constituents toward the substrate material, said physical barrier material being a ceramics selected from the group consisting of silicon dioxide, silicon carbide, aluminum oxide and magnesium fluoride.

12. The protective coating of claim 11 wherein each said diffusion barrier layer and each said physical barrier layer has a thickness from about 0.5 to about 100 micrometers.

13. The protective coating of claim 11 wherein said plurality of continuous layers of said diffusion barrier material and said physical barrier material are formed in situ upon the substrate.

14. The protective coating of claim 11 wherein said plurality of continuous layers of said diffusion barrier material and said physical barrier material are preformed for subsequent encapsulation of the substrate.

15. The protective coating of claim 11 wherein said diffusion barrier material is selected from the group consisting of polyamides, polyethylenes, poly (p-xylylenes)s, fluropolymers, polyacylates, silicon polymers, polyurethanes, a carbon exhibiting properties similar to diamond, amorphous carbon and silicon.

16. The protective coating of claim 15 wherein said diffusion barrier material is a poly(p-xylylene).