Organic electronic device comprising charge-transporting polyester and image forming apparatus

• US 5,654,119 A
• Filed: 04/05/1996
• Issued: 08/05/1997
• Est. Priority Date: 04/06/1995
• Status: Expired due to Fees

• Current Assignee: Fuji Xerox Company Limited (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Xerox Company Limited (Fujifilm Holdings Corporation)
• Inventors: Kobayashi, Tomoo, Imai, Akira, Ishii, Toru, Nukada, Katsumi, Mashimo, Kiyokazu, Ojima, Fumio, Uesaka, Tomozumi, Iwasaki, Masahiro
• Primary Examiner(s): GOODROW, JOHN L
• Application Number:
  US08/628,766
• Time in Patent Office: 487 Days
• Field of Search: 430/58, 430/59, 430/83, 430/96
• US Class Current: 430/58.7
• CPC Class Codes: G03G 5/075 obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds G03G5/078 takes precedence
• CPC Class Codes: G03G 5/0764 triarylamine
• CPC Class Codes: G03G 5/0766 benzidine
• CPC Class Codes: G03G 5/14752 Polyesters
• CPC Class Codes: G03G 5/14756 Polycarbonates
• CPC Class Codes: G03G 5/1476 Other polycondensates comprising oxygen atoms in the main chain; Phenol resins
• CPC Class Codes: G03G 5/14769 Other polycondensates comprising nitrogen atoms with or without oxygen atoms in the main chain

Abstract

An organic electronic device comprises a layer containing a charge-transporting polyester comprising a repeating unit comprising at least one of partial structural units represented by the following formulae (I-a) and (I-b) as a partial structure of repeating unit: ##STR1## where the symbols in the above formulae are defined in the specification.

Claims

1. An electrophotographic photoreceptor comprising a layer containing a charge-transporting polyester comprising a repeating unit comprising at least one of partial structural units represented by the following formulae (I-a) and (I-b):

##STR232## wherein R₁ and R₂ each independently represent a hydrogen atom, an alkyl group, an alkoxy group, a substituted amino group, a halogen atom or a substituted or unsubstituted aryl group;

X represents a substituted or unsubstituted divalent aromatic group;

T represents a branched divalent hydrocarbon group containing a C_2-10 aliphatic moiety; and

k represents an integer of 0 or 1.

2. The electrophotographic photoreceptor according to claim 1, wherein:

(1) said charge-transporting polyester comprises at least one of repeating structural units represented by the following formulae (I-a) and (I-b) as a divalent carboxylic acid component and a repeating structural unit represented by the following formula (III) as a divalent alcohol component, is terminated by the following formula (IV-a) or (IV-b) at both ends thereof, and has a polymerization degree of from 5 to 5,000;

or

(2) said charge-transporting polyester comprises at least one of repeating structural units represented by the following formulae (I-a) and (I-b) and a repeating structural unit represented by the following formula (II) as a divalent carboxylic acid component and a repeating structural unit represented by the following formula (III) as a divalent alcohol component, is terminated by the following formula (IV-a) or (IV-b) at both ends thereof, and has a polymerization degree of from 5 to 5,000;

##STR233##

space="preserve" listing-type="equation">--OC--Z--CO-- (II)

space="preserve" listing-type="equation">--O--(Y--O).sub.m -- (III)

space="preserve" listing-type="equation">--O--(Y--O).sub.m R (IV-a)

space="preserve" listing-type="equation">--O--(Y--O).sub.m --CO--Z--CO--OR'"'"' (IV-b)

wherein R₁ and R₂ each independently represent a hydrogen atom, an alkyl group, an alkoxy group, a substituted amino group, a halogen atom or a substituted or unsubstituted aryl group;

X represents a substituted or unsubstituted divalent aromatic group;

T represents a branched divalent hydrocarbon group containing a C_2-10 aliphatic moiety;

Z represents a divalent carboxylic residue;

R and R'"'"' each represent a hydrogen atom, an alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group;

Y represents a divalent alcohol residue;

k represents an integer of 0 or 1; and

m represents an integer of 1 to 5.

3. The electrophotographic photoreceptor according to claim 1, wherein X in formula (I-a) and (I-b) is a substituted or unsubstituted biphenylene group.

4. The electrophotographic photoreceptor according to claim 2, wherein X in formula (I-a) and (I-b) is a substituted or unsubstituted biphenylene group.

5. The electrophotographic photoreceptor according to claim 1, wherein said layer comprising a charge-transporting polyester further comprises at least one substantially electrically-insulating polymer which is compatible with said charge-transporting polyester.

6. The electrophotographic photoreceptor according to claim 1, wherein said electrophotographic photoreceptor has a photosensitive layer, and said charge-transporting polyester is present in the surface layer of said electrophotographic photoreceptor.

7. The electrophotographic photoreceptor according to claim 2, wherein said electrophotographic photoreceptor has a photosensitive layer, and said charge-transporting polyester is present in the surface layer of said electrophotographic photoreceptor.

8. The electrophotographic photoreceptor according to claim 3, wherein said electrophotographic photoreceptor has a photosensitive layer, and said charge-transporting polyester is present in the surface layer of said electrophotographic photoreceptor.

9. The electrophotographic photoreceptor according to claim 4, wherein said electrophotographic photoreceptor has a photosensitive layer, and said charge-transporting polyester is present in the surface layer of said electrophotographic photoreceptor.

10. The electrophotographic photoreceptor according to claim 6, wherein said photosensitive layer comprises a charge-transporting material comprising said at least one charge-transporting polyester, and a charge-generating material comprising at least one selected from the group consisting of halogenated gallium phthalocyanine crystal, halogenated tin phthalocyanine crystal, hydroxy gallium phthalocyanine crystal and titanyl phthalocyanine crystal.

11. An image forming apparatus comprising a photoreceptor, a charging apparatus, an exposing apparatus and a developing apparatus which operates to form on said photoreceptor an electrostatic image which is then developed to form a visible image, wherein said photoreceptor comprising an electrically-conductive support having thereon a photosensitive layer comprising at least one charge-transporting polyester having a repeating unit comprising at least one of partial structural units represented by the following formulae (I-1) and (I-2), and said charging apparatus is a contact-charging apparatus comprises an electrically-conductive member which comes into contact with the surface of said photoreceptor and to which member a voltage is applied:

##STR234## wherein R₁ and R₂ each independently represent a hydrogen atom, an alkyl group, an alkoxy group, a substituted amino group, a halogen atom or a substituted or unsubstituted aryl group;

X represents a substituted or unsubstituted divalent aromatic group;

T'"'"' represents a C_1-6 divalent straight-chain hydrocarbon group or a C_2-10 divalent branched hydrocarbon group; and

k represents an integer of 0 or 1.

12. The image forming apparatus according to claim 11, wherein said photosensitive layer comprises a charge-transporting polyester represented by the following formula (II) or (III):

##STR235## wherein A represents a structure represented by the above described formula (I-1) or (I-2);

R represents a hydrogen atom, an alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group;

B and B'"'"' each independently represents --O--(Y--O)_m --R or --O--(Y--O)_m --CO--Z--CO--O--R'"'"' (wherein R is as defined above, R'"'"' represents a hydrogen atom, an alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group, and m represents an integer of from 1 to

     5);

Y represents a divalent alcohol residue;

Z represents a divalent carboxylic acid residue;

m represents an integer of from 1 to 5; and

p represents an integer of from 5 to 5,000.

13. The image forming apparatus according to claim 11, wherein said photosensitive layer further comprises a polycarbonate resin having at least one repeating structural unit selected from the group consisting of those represented by the following formulae (A) to (E):

##STR236##

14. The image forming apparatus according to claim 11, wherein said photosensitive layer comprises a plurality of layers and the layer containing said charge-transporting polyester is the outermost layer of said photosensitive layer.

15. The image forming apparatus according to claim 12, wherein said photosensitive layer comprises a plurality of layers and the layer containing said charge-transporting polyester is the outermost layer of said photosensitive layer.

16. The image forming apparatus according to claim 13, wherein said photosensitive layer comprises a plurality of layers and the layer containing said charge-transporting polyester is the outermost layer of said photosensitive layer.