Polymer micromold and fabrication process

• US 5,658,515 A
• Filed: 09/25/1995
• Issued: 08/19/1997
• Est. Priority Date: 09/25/1995
• Status: Expired due to Fees

• Current Assignee: Lawrence Livermore National Security LLC (Government of the United States of America)
• Original Assignee: Regents of the University of California (University of California)
• Inventors: Lee, Abraham P., Ahre, Paul E., Dupuy, Peter C., Northrup, M. Allen
• Primary Examiner(s): Tentoni, Leo B.
• Application Number:
  US08/533,425
• Time in Patent Office: 694 Days
• Field of Search: 264/219, 264/323, 249/135, 427/135, 205/70, 29/557
• US Class Current: 264/219
• CPC Class Codes: B29C 33/42 characterised by the shape of the moulding surface, e.g. ribs or grooves
• CPC Class Codes: Y10T 29/49995 Shaping one-piece blank by removing material

Abstract

A mold assembly with micro-sized features in which the hollow portion thereof is fabricated from a sacrificial mandrel which is surface treated and then coated to form an outer shell. The sacrificial mandrel is then selectively etched away leaving the outer shell as the final product. The sacrificial mandrel is fabricated by a precision lathe, for example, so that when removed by etching the inner or hollow area has diameters as small as 10'"'"'s of micros (μm). Varying the inside diameter contours of the mold can be accomplished with specified ramping slopes formed on the outer surface of the sacrificial mandrel, with the inside or hollow section being, for example, 275 μm in length up to 150 μm in diameter within a 6 mm outside diameter (o.d.) mold assembly. The mold assembly itself can serve as a micronozzle or microneedle, and plastic parts, such as microballoons for angioplasty, polymer microparts, and microactuators, etc., may be formed within the mold assembly.

Claims

1. A method for forming a mold, comprising:

providing a sacrificial mandrel having a contour on the outer surface,

depositing at least one layer of material on the outer surface of the sacrificial mandrel to form a shell, and

removing the sacrificial mandrel, leaving the contour thereof on a passageway within the thus formed shell thereby defining the mold.

2. The method of claim 1, additionally including forming a film on the sacrificial mandrel prior to depositing the shell thereon to enhance removal of the sacrificial mandrel.

3. The method of claim 2, wherein the sacrificial mandrel is removed by etching.

4. The method of claim 3, additionally including forming the sacrificial mandrel from copper, forming the film from gold, and forming the shell from nickel.

5. The method of claim 3, wherein the film is formed by a flash coating process, and wherein the shell is deposited by a process selected from the group consisting of electroplating and electroless plating.

6. The method of claim 1, additionally including forming the contour on the outer surface of the sacrificial mandrel by precision machining.

7. The method of claim 6, wherein said passageway has a contour of various dimensions in different sections thereof by forming the same contour on the outer surface of the sacrificial mandrel, the various being in the range of 10'"'"'s to 100'"'"'s μ

m.

8. The method of claim 7, wherein the shell has a thickness of about 6 mm and wherein passageway has dimensions of about 120μ

m to about 800μ

m.

9. The method of claim 6, wherein the contour on the outer surface of the sacrificial mandrel includes a plurality of circular sections interconnected by ramping slopes.

10. The method of claim 1, additionally including utilizing the thus formed mold for polymer extrusion of micro-sized devices selected from the group consisting of polymer microparts, polymer microballoons, polymer micronozzles, polymer microneedles, and polymer microactuators.

11. A micro-sized device mold, applicable for polymer extrusion therein, comprising:

a shell constructed of material selected from the group consisting of nickel, copper, iron, gold, and platinum;

said shell having a passageway extending therethrough,

said passageway having an outer contour configured to define a similar contour on at least an outer surface of a micro-sized device formed therein,

said passageway having a plurality of sections therein having a distance thereacross of from 10'"'"'s to 100'"'"'s microns.

12. The mold of claim 11, wherein said shell has a width of about 6 mm and length of about 3.5 inches, and wherein said outer contour of said passageway includes a plurality of different diameter sections interconnected by tapering sections.

13. The mold of claim 12, wherein said plurality of different diameter of said passageway have dimensions ranging from about 120 μ

m to about 800 μ

m.

14. The mold of claim 11, wherein said shell passageway has an outer diameter and a passageway diameter of a size so as to enable same to be used as a micronozzle.

15. An inverted process for forming a micromold in which a hollow extending therethrough is fabricated from a sacrificial mandrel having an outer surface precision machined to a selected contour of the hollow, the process including:

machining an outer surface of a sacrificial mandrel to a contour of an outer surface of a part to be formed in the micromold,

applying a coating of material to the contoured outer surface of the sacrificial mandrel to enhance selective etching of the mandrel,

depositing a layer of material on the thus coated sacrificial mandrel to form an outer shell of the micromold, and

etching away at least the sacrificial mandrel leaving a micromold defining a hollow extending through the shell having a contour on the surface thereof corresponding to the contour on the outer surface of the sacrificial mandrel.

16. The inverted process of claim 15, additionally including etching away the coating deposited on the sacrificial mandrel from the surface of the passageway.

17. The inverted process of claim 15, wherein the layer of material deposited to form the outer shell of the micromold is deposited by a process selected from the group consisting of electroplating and electroless plating.

18. The inverted process of claim 15, wherein the sacrificial mandrel is formed from copper, aluminum, copper nickel, or brass, wherein the coating is formed from gold, platinum, or other materials inert to an etchant of the sacrificial mandrel;

and wherein the outer shell is formed from nickel, copper, iron, gold or platinum.

19. The inverted process of claim 18, wherein the sacrificial mandrel is formed from copper, wherein the coating is formed from gold having a thickness of 1 to 10 Å

, wherein the outer shell is formed from nickel having an outer dimension of 1 to 8 mm, and wherein the hollow in the outer shell has sections with dimensions ranging from 10'"'"'s of microns to 100'"'"'s of microns.