Adjuvants for herbicidal compositions

• US 5,658,855 A
• Filed: 09/26/1996
• Issued: 08/19/1997
• Est. Priority Date: 09/26/1996
• Status: Expired due to Term

• Current Assignee: Ndsu-Research Foundation
• Original Assignee: North Dakota State University (US Bancorp)
• Inventors: Woznica, Zenon, Matysiak, Robert, Nalewaja, John D.
• Primary Examiner(s): Clardy, S. Mark
• Assistant Examiner(s): BEMBENICK, BRIAN
• Application Number:
  US08/721,136
• Time in Patent Office: 327 Days
• Field of Search: 504/116, 504/214, 504/215, 504/253, 71/DIG. 1
• US Class Current: 504/214
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 33/08 containing oxygen or sulfur
• CPC Class Codes: A01N 47/36 containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
• CPC Class Codes: A01N 59/00 Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
• CPC Class Codes: C05G 3/50 Surfactants; Emulsifiers
• CPC Class Codes: C05G 3/60 Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants

Abstract

Adjuvant compositions for herbicides comprising amine or ammonia compounds for adjusting the pH to the alkaline range, a neutral water soluble compound to provide a fertilizer action and a non-ionic surfactant and water. Herbicidal compositions using the adjuvant in combination with the herbicide are also included as well as methods for controlling weeds or undesirable vegetation by application of those compositions thereto.

Claims

1. An adjuvant composition for use in aqueous herbicidal spray compositions comprising:

(A) an amine alkaline compound in an amount to provide an alkaline pH of above about 7 to about 9 when formulated in a final spray composition;

(B) a neutral ammonium salt compound in an amount of from 5 to 30% by weight of the adjuvant;

(C) a non-ionic surfactant having a high Hydrophilic-Lipophilic Balance (HLB), in an amount of from about 15 to 80% by weight of the adjuvant; and

(D) sufficient water to make 100 percent of the adjuvant composition.

2. An adjuvant composition according to claim 1 wherein the amine alkaline compound of component (A) comprises up to about 16% by weight of the composition.

3. An adjuvant composition according to claim 1 wherein the amine alkaline compound (A) is selected from the group consisting of ammonium hydroxide, and organic water soluble amines.

4. An adjuvant composition according to claim 1 wherein the amine alkaline compound (A) is selected from the group consisting of ammonium hydroxide, monoethanolamine, diethanolamine, triethanolamine and 2-amino-2-ethyl-1,3-propanediol and mixtures thereof.

5. An adjuvant composition according to claim 1 wherein the neutral ammonium salt compound (B) is selected from the group of ammonium nitrite, ammonium chloride, ammonium sulfate and mixtures thereof.

6. An adjuvant composition according to claim 1 wherein the non-ionic surfactant has an HLB of from about 10 to about 16.

7. An adjuvant composition according to claim 1 wherein the non-ionic surfactant (C) is a primary or secondary alcohol.

8. An adjuvant composition according to claim 1 wherein the non-ionic surfactant is a block copolymer.

9. An adjuvant composition according to claim 7 wherein the non-ionic surfactant (C) is present in an amount of from about 20 to 50% by weight of the adjuvant composition.

10. An adjuvant composition according to claim 1 wherein the alkaline compound (B) is present in an amount sufficient to provide a pH of at least about 7.25 when formulated in a final aqueous spray solution.

11. A composition according to claim 1 further characterized by the absence of significant herbicidally antagonistic amounts of calcium or sodium cations.

13. An herbicidal composition according to claim 11 wherein the herbicide (E) is selected from the group consisting of 2[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl-N,N-dimethyl-3-pyridine dicarboxyamide;

2-[4,5-dihydro-4-methyl-4-(1-methyl(ethyl)-5-oxo-1H-imidazol-2-yl]-5-ethyl-3-pyridine carboxylic acid;

N-[[(4,6-dimethoxy-2-[pyrimidinyl)-2-amino) carbonyl]-3-(ethyl sulfonyl)-2-pyridine sulfonamide; and

methyl-2-[[[[[4,6-bis(difluoromethoxy)-2-pyrimidinyl]amino]carbonyl]amino]sulfonyl]benzoate.

15. A method of controlling weeds which comprises applying an herbicidal composition of claim 13 postemergence to a weeds and/or other undesired vegetation.

18. An herbicidal spray solution comprising about 1% of an aqueous adjuvant composition according to claim 1, an effective amount of an herbicide and water to make 100% of said composition.

12. An aqueous postemergence herbicidal spray composition which comprises an adjuvant composition comprising:

(A) an amine alkaline pH regulator compound selected from the group consisting of ammonium hydroxide, monoethanolamine, diethanolamine, triethanolamine, and 2-amino-2-ethyl-1,3-propanediol and mixtures thereof in sufficient amount to provide a pH of from about 7.25 to about 9 in the final diluted aqueous composition;

(B) a neutral ammonium salt selected from the group consisting of ammonium nitrate, ammonium chloride and ammonium sulfate, in an amount of from about 5 to 50% by weight of said adjuvant composition;

(C) a non-ionic surface active agent having an HLB of from about 10 to about 16 in an amount of from about 15 to 80% by weight of said adjuvant composition;

(D) water to make 100%;

(E) an effective amount of a postemergence herbicide; and

(F) additional water to make up the final spray solution.

14. A composition according to claim 12 wherein the herbicide (E) ranges from about 0.005 to about 2% of the final diluted aqueous spray composition.

16. A post emergence herbicidal aqueous spray composition comprising from about 0.2 to 0.5% of a non-ionic surfactant having a high Hydrophylic-Lipophylic Balance (HLB);

an alkaline amine type pH regulator selected from the group consisting of ammonium hydroxide, monoethyanol amine, diethanolamine, triethanolamine and 2-amino-2-ethyl-1,3-propanediol in an amount to provide a pH of from about 7.25 to about 9 in the final aqueous solution;

from about 0.05 to 0.5% of a neutral ammonium salt selected from the group consisting of ammonium nitrate, ammonium chloride and ammonium sulfate; and

from about 0.005 to 2% of a herbicide selected from the group consisting of 2[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl-N,N-dimethyl-3-pyridine dicarboxyamide;

2-[4,5-dihydro-4-methyl-4-(1-methyl(ethyl)-5-oxo-1H-imidazol-2-yl]-5-ethyl-3-pyridine carboxylic acid;

N-[[(4,6-dimethoxy-2-[pyrimidinyl)-2-amino)carbonyl]-3-(ethyl sulfonyl)-2-pyridine sulfonamide; and

methyl-2-[[[[[4,6-bis (difluoromethoxy)-2-pyrimidinyl]amino]carbonyl]amino]sulfonyl]benzoate and water to make 100% of said aqueous spray solution.

17. A method of controlling weeds or other undesired vegetation which comprise applying to said weeds or undesired vegetation an aqueous herbicidal composition according to claim 16.