Binder composition for use in three dimensional printing

• US 5,660,621 A
• Filed: 12/29/1995
• Issued: 08/26/1997
• Est. Priority Date: 12/29/1995
• Status: Expired due to Fees

• Current Assignee: Massachusetts Institute of Technology
• Original Assignee: Massachusetts Institute of Technology
• Inventors: Bredt, James F.
• Primary Examiner(s): BRUNSMAN, DAVID M
• Application Number:
  US08/581,319
• Time in Patent Office: 606 Days
• Field of Search: 106/287.34, 106/287.23, 106/287.25, 106/600, 106/634, 106/636, 106/638, 106/802, 106/808, 106/816
• US Class Current: 106/287.34
• CPC Class Codes: B29C 41/003 characterised by the choice of material
• CPC Class Codes: B29C 64/153 using layers of powder being selectively joined, e.g. by selective laser sintering or melting
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 70/00 Materials specially adapted for additive manufacturing
• CPC Class Codes: B41M 3/16 Braille printing typewriters or selective printing mechanisms for Braille printing B41J3/32
• CPC Class Codes: Y10S 264/72 Processes of molding by spraying

Abstract

A binder composition for three dimensional printing of parts is disclosed which is stable during storage and passage through a printhead, yet able to gel under the conditions existing in a powder bed. The binder composition comprises colloidal silica, a catalyst able to promote gelation of the composition when the composition is below a predetermined pH value, and a base able to maintain the pH of the composition above the predetermined value at which the composition gels. Preferably, the catalyst is polyethylene glycol or another ethylene oxide-derived polymer, and the base is triethanolamine. Upon impact with a powder bed, the pH of the binder composition is reduced, as by adding an acid such as citric acid to the powder, thereby causing the binder to gel in the powder.

Claims

1. A binder composition for use in three dimensional printing comprising:

a fluid dispersing medium;

silica in a solid particulate form dispersed in the fluid dispersing medium;

a catalyst able to promote gelation of the binder composition when the binder composition is below a predetermined pH value;

a base able to maintain the pH of the binder composition above the predetermined value at which the binder composition gels.

2. The binder composition of claim 1, wherein the fluid dispersing medium comprises distilled water.

3. The binder composition of claim 1, wherein the base comprises triethanolamine.

4. The binder composition of claim 3, wherein the concentration of the triethanolamine is approximately 2 percent by weight.

5. The binder composition of claim 1, wherein the base comprises triethanolamine, tetramethylammonium hydroxide;

ammonia, or morpholine.

6. The binder composition of claim 5, wherein the concentration of the base is approximately 0.5 percent by weight.

7. The binder composition of claim 1, wherein the base is able to maintain the pH of the binder composition above 7.5.

8. The binder composition of claim 1, wherein the base is able to maintain the pH of the binder composition between 9 and 9.5.

9. The binder composition of claim 1, wherein the base comprises an organic base.

10. The binder composition of claim 1, wherein the silica is amorphous.

11. The binder composition of claim 1, wherein the silica comprises at least 10 percent by volume of the binder composition.

12. The binder composition of claim 1, wherein the silica comprises at least 17.5 percent by weight of the binder composition.

13. The binder composition of claim 1, wherein the silica comprises approximately 30 percent by weight of the binder composition.

14. The binder composition of claim 1, wherein the particle size of the silica is approximately 100 nm.

15. The binder composition of claim 1, wherein the catalyst comprises a polymer made from an ethylene oxide.

16. The binder composition of claim 15, wherein the polymer made from ethylene oxide comprises polyethylene glycol.

17. The binder composition of claim 15, wherein the polymer made from ethylene oxide is provided at a concentration of at least 100 ppm.

18. The binder composition of claim 15, wherein the molecular weight of the polymer made from ethylene oxide is between 400 and 35,000.

19. The binder composition of claim 15, wherein the molecular weight of the polymer made from ethylene oxide is at least 14 000.

20. The binder composition of claim 15, wherein the molecular weight of the polymer made from ethylene oxide is approximately 20,000.

21. The binder composition of claim 15, wherein the concentration of the polymer made from ethylene oxide is approximately 0.1 percent by weight.

22. The binder composition of claim 1, further comprising a pH indicator.

23. The binder composition of claim 22, wherein the pH indicator comprises thymol blue.

24. The binder composition of claim 1, further comprising a humectant.

25. The binder composition of claim 24, wherein the humectant comprises ethylene glycol or propylene glycol.

26. The binder composition of claim 1, further comprising a solvent to inhibit precipitation of impurities.

27. The binder composition of claim 26, wherein the solvent comprises butyl carbitol.

28. The binder composition of claim 27, wherein the butyl carbitol is provided at a concentration of approximately 1 percent by weight.

29. The binder composition of claim 26, wherein the solvent comprises an emulsion comprising methylated silica and polydimethylsiloxane.