Self-repairing, reinforced matrix materials

• US 5,660,624 A
• Filed: 09/29/1995
• Issued: 08/26/1997
• Est. Priority Date: 06/19/1990
• Status: Expired due to Term

• Current Assignee: Carolyn M. Dry
• Original Assignee: Carolyn M. Dry
• Inventors: Dry, Carolyn M.
• Primary Examiner(s): MARCHESCHI, MICHAEL A
• Application Number:
  US08/537,228
• Time in Patent Office: 697 Days
• Field of Search: 501/95, 106/672, 106/676, 106/677, 106/711, 106/724, 106/802, 106/819, 106/823, 106/805, 106/729, 106/730, 588/3, 588/252, 588/901, 252/62.51, 252/62.9, 75/300, 75/229, 428/320.2, 428/321.1, 428/321.5, 428/364, 428/375, 428/297
• US Class Current: 106/677
• CPC Class Codes: A61L 27/48 with macromolecular fillers
• CPC Class Codes: B28B 17/00 Details of, or accessories for, apparatus for shaping the material; Auxiliary measures taken in connection with such shaping moulds B28B7/00; after-treatment B28B11/00; feeding or discharging B28B13/00; arrangements for embedding elements in the material B28B23/00
• CPC Class Codes: B29C 73/163 Sealing compositions or agents, e.g. combined with propellant agents
• CPC Class Codes: B29C 73/22 the article containing elements including a sealing composition, e.g. powder being liberated when the article is damaged
• CPC Class Codes: C04B 20/0048 Fibrous materials
• CPC Class Codes: C04B 20/0056 Hollow or porous fibres
• CPC Class Codes: C04B 22/006 released by a chemical reaction, e.g. polymer condensation
• CPC Class Codes: C04B 38/0003 containing continuous channels, e.g. of the "dead-end" type or obtained by pushing bars in the green ceramic product B28B takes precedence
• CPC Class Codes: C04B 40/0007 Electric, magnetic or electromagnetic fields
• CPC Class Codes: C04B 40/0028 Aspects relating to the mixing step of the mortar preparation
• CPC Class Codes: C04B 40/0071 making use of a rise in pressure
• CPC Class Codes: C04B 40/0092 Temporary binders, mortars or concrete, i.e. materials intended to be destroyed or removed after hardening, e.g. by acid dissolution
• CPC Class Codes: C04B 40/024 Steam hardening, e.g. in an autoclave
• CPC Class Codes: C04B 40/0263 Hardening promoted by a rise in temperature C04B40/024 takes precedence
• CPC Class Codes: C04B 40/06 Inhibiting the setting, e.g. mortars of the deferred action type containing water in breakable containers ; Inhibiting the action of active ingredients
• CPC Class Codes: C04B 40/0633 Chemical separation of ingredients, e.g. slowly soluble activator
• CPC Class Codes: C04B 40/0675 Mortars activated by rain, percolating or sucked-up water; Self-healing mortars or concrete
• CPC Class Codes: C08J 3/241 Preventing premature crosslinking by physical separation of components, e.g. encapsulation
• CPC Class Codes: C08K 7/00 Use of ingredients characterised by shape
• CPC Class Codes: C08K 7/02 Fibres or whiskers
• CPC Class Codes: C08K 7/22 : Expanded, porous or hollow particles
• CPC Class Codes: Y10S 588/901 : Compositions
• CPC Class Codes: Y10T 428/249994 : Composite having a component wherein a constituent is liquid or is contained within preformed walls [e.g., impregnant-filled, previously void containing component, etc.]
• CPC Class Codes: Y10T 428/249995 : Constituent is in liquid form
• CPC Class Codes: Y10T 428/249997 : Encapsulated liquid
• CPC Class Codes: Y10T 428/2913 : Rod, strand, filament or fiber
• CPC Class Codes: Y10T 428/2933 : Coated or with bond, impregnation or core

Abstract

Self-repairing, fiber reinforced matrix materials include a matrix material including inorganic as well as organic matrices. Disposed within the matrix are hollow fibers having a selectively releasable modifying agent contained therein. The hollow fibers may be inorganic or organic and of any desired length, wall thickness or cross-sectional configuration. The modifying agent is selected from materials capable of beneficially modifying the matrix fiber composite after curing. The modifying agents are selectively released into the surrounding matrix in use in response to a predetermined stimulus be it internal or externally applied. The hollow fibers may be closed off or even coated to provide a way to keep the modifying agent in the fibers until the appropriate time for selective release occurs. Self-repair, smart fiber matrix composite materials capable of repairing microcracks, releasing corrosion inhibitors or permeability modifiers are described as preferred embodiments in concrete and polymer based shaped articles.

Claims

1. A shaped article comprising:

a shaped matrix material having at least one hollow fiber disposed therein, said hollow fiber having a releasable modifying agent contained therein, means for maintaining the modifying agent within the fiber until released and means for permitting release of the modifying agent from the hollow fiber into matrix material in response to at lease one external stimulus.

2. A shaped article as defined in claim 1, wherein said matrix material is a construction material.

3. A shaped article as defined in claim 1, wherein said matrix material is a cementitious material.

4. A shaped article as defined in claim 1, wherein said hollow fiber comprises polypropylene, polyamide, ceramic and cellulose.

5. A shaped article as defined in claim 1, wherein said hollow fiber is elastomeric.

6. A shaped article as defined in claim 1, wherein said hollow fiber is porous polypropylene.

7. A shaped article as defined in claim 1, wherein said modifying agent is a liquid.

8. A shaped article as defined in claim 1, wherein said modifying agent comprises impregnators, sealants, adhesives, water barriers, anti-corrosion agents, anti-freeze agents or fiber protection modifying agents.

9. A shaped article as defined in claim 1, wherein said means for maintaining the modifying agent within the fibers comprises a coating material disposed on said fibers.

10. A shaped article as defined in claim 1, including a plurality of modifying agent filled hollow fibers present in an amount of less than about 10 volume percent of said matrix material.

11. A shaped article as defined in claim 1, wherein said matrix material is inorganic.

12. A shaped article as defined in claim 1, wherein said hollow fiber organic.

13. A shaped article as defined in claim 1, wherein said hollow fiber is inorganic.

14. A shaped article as defined in claim 1, wherein said modifying agent is a solid.

15. A shaped article as defined in claim 11, wherein said inorganic matrix material is selected from cement, concrete, ceramic or metal matrix materials.

16. A shaped article as defined in claim 15, wherein said ceramic matrix material is selected from the group consisting of carbide, oxide and hydroxyapatite materials.

17. A shaped article as defined in claim 15, wherein said metal matrix material comprises aluminum, iron, lead, copper, steel, bronze phosphor bronze, or brass.

18. A shaped article as defined in claim 1, wherein said hollow fiber is a glass fiber.

19. A shaped article as defined in claim 1, wherein said hollow fiber is an optical fiber.

20. A shaped article as defined in claim 1, wherein said hollow fiber is a piezoelectric fiber.

21. A shaped article as defined in claim 9, wherein said coating is selected from chemically sensitive, electrically sensitive or radiation sensitive coatings.

22. A shaped article as defined in claim 21, wherein said chemically sensitive coating is selected from moisture sensitive, pH sensitive, ion sensitive or solvent sensitive coatings.

23. A shaped article as defined in claim 21, wherein said electrically sensitive coating is selected from the group consisting of current sensitive and voltage sensitive coatings.

24. A shaped article as defined in claim 21, wherein said radiation sensitive coating is selected from the group consisting of light sensitive, temperature sensitive and radioactivity sensitive coatings.

25. A shaped article as defined in claim 1, wherein said modifying agent comprises a dye material.

26. A shaped article as defined in claim 1, wherein said modifying agent is selected from rheological or electrorheological fluids.

27. A shaped article as defined in claim 1, wherein said article is a containment structure for radioactivity or chemical waste materials.

28. A shaped article as defined in claim 1, further comprising at least one optical fiber disposed in said matrix.

29. A shaped article as defined in claim 1, comprising a plurality of modifying agent filled hollow fibers in a web arrangement.

30. A shaped article as defined in claim 1, wherein the hollow fiber is a shape memory alloy material.

31. A shaped articule as defined in claim 1, wherein the hollow fiber is magnetostrictive.

32. A shaped article as defined in claim 1, wherein the hollow fiber is electrostrictive.