Erasable ink composition containing a polymer-encapsulated colorant derived from monomer containing dissolved colorant

• US 5,661,197 A
• Filed: 05/20/1996
• Issued: 08/26/1997
• Est. Priority Date: 12/20/1994
• Status: Expired due to Term

• Current Assignee: BIC Corporation (Societe BIC)
• Original Assignee: BIC Corporation (Societe BIC)
• Inventors: Banning, Jeffery H., Wang, Aiying, Chadwick, Barry W., Chandler, Wayne A., Villiger, David C.
• Primary Examiner(s): Michl, Paul R.
• Assistant Examiner(s): Guarriello, John J.
• Application Number:
  US08/650,597
• Time in Patent Office: 463 Days
• Field of Search: 523/161, 523/200, 523/205, 524/458, 524/460, 260/DIG. 38, 106/21 A, 106/22 R, 106/23 R, 106/23 B, 401/209
• US Class Current: 523/161
• CPC Class Codes: C09B 67/0097 Dye preparations of special physical nature; Tablets, films, extrusion, microcapsules, sheets, pads, bags with dyes
• CPC Class Codes: C09D 11/16 Writing inks
• CPC Class Codes: Y10S 260/38 Ink

Abstract

An erasable ink composition contains an aqueous dispersion of water-insoluble polymer-encapsulated colorant obtained from the emulsion polymerization of at least one hydrophobic emulsion-polymerizable monomer with at least a portion of the monomer containing colorant dissolved therein. The ink is intended for use in any of a variety of marking instruments, in particular, a ball-point pen.

Claims

1. An erasable ink composition which comprises an aqueous dispersion of a water-insoluble polymer-encapsulated colorant obtained by polymerizing under emulsion polymerization conditions at least one hydrophobic emulsion-polymerizable monomer containing dissolved colorant, the erasable ink composition when applied to a substrate and upon drying thereon exhibiting less than about 30 weight percent flaking based on the weight of the dried ink and an erasability value delta E*ab of less than about 4.0.

2. The erasable ink composition of claim 1 exhibiting less than about 20 weight percent flaking based on the weight of the dried ink and an erasability value delta E*ab of less than about 3.5.

3. The erasable ink composition of claim 1 exhibiting less than about 10 weight percent flaking based on the weight of the dried ink and an erasability value delta E*ab of less than about 3.0.

4. The erasable ink composition of claim 1 wherein the composition possesses a viscosity of from about 1 to about 80,000 centipoises.

5. The erasable ink composition of claim 1 wherein the composition possesses a viscosity of from about 3 to about 30,000 centipoises.

6. The erasable ink of claim 1 wherein the water-insoluble polymer-encapsulated colorant possesses an average particle size of from about 25 to about 1000 nanometers.

7. The erasable ink of claim 1 wherein the water-insoluble polymer-encapsulated colorant possesses an average particle size of from about 50 to about 250 nanometers.

8. The erasable ink composition of claim 1 wherein the monomer is selected from the group consisting of styrene, vinyl toluene, t-butyl styrene, chlorostyrene, vinyl benzyl chloride, vinyl pyridene, ethyl acrylate, methyl methacrylate, butyl acrylate, 2-ethylhexyl acrylate, vinyl acetate, vinyl chloride, vinylidene chloride, acrylonitrile, butadiene and isoprene.

9. The erasable ink composition of claim 1 wherein the colorant is a water-insoluble solvent dye.

10. The erasable ink composition of claim 9 wherein the water-insoluble solvent dye is selected from the group consisting of Sudan Red 380, Sudan Blue 670, Baso Red 546, Baso Blue 688, Sudan Yellow 150, Base Blue 645, Flexo Yellow 110, Flexo Blue 630, Oil Red 235, Morfast Yellow 101, Nitro Fast Yellow B, Macrolex Yellow 6G, Solvent Yellow 14, Solvent Yellow 16, Solvent Yellow 21, Solvent Orange 45, Solvent Orange 62, Solvent Red 1, Solvent Red 7, Solvent Red 8, Solvent Red 119, Solvent Red 125, Solvent Blue 5, Solvent Blue 14, Solvent Blue 25, Solvent Blue 36, Solvent Black 5, Solvent Black 34 and mixtures thereof.

11. The erasable ink composition of claim 1 wherein the colorant is a dyestuff precursor selected from the group consisting of triphenylmethane compounds, diphenylmethene compounds, xanthene compounds, thiazine compounds, spiropyran compounds and mixtures thereof.

12. The erasable ink composition of claim 1 further comprising at least one component selected from the group consisting of natural latices, synthetic latices, rheological modifiers, suspension agents, humectants, emulsifiers, surfactants, plasticizers, spreading agents, drying agents, release agents, parting agents, preservatives, antimicrobial agents, anticorrosion agents, antioxidants and coalescing aids.

13. The erasable ink composition of claim 1 wherein the monomer and dye are dissolved in a common solvent.

14. A marking instrument containing the erasable ink composition of claim 1.

15. The marking instrument of claim 14 which is a ball-point pen.