Particulate filter structure

• US 5,662,728 A
• Filed: 12/31/1992
• Issued: 09/02/1997
• Est. Priority Date: 12/31/1992
• Status: Expired due to Term

• Current Assignee: Hollingsworth & Vose Company
• Original Assignee: Hoechst Celanese Corporation (Sanofi )
• Inventors: Groeger, Herbert Gunter
• Primary Examiner(s): Woo, Jay H.
• Assistant Examiner(s): SMITH, DUANE
• Application Number:
  US07/999,029
• Time in Patent Office: 1,706 Days
• Field of Search: 96/153, 96/154, 55/524, 55/527, 55/514, 55/494, 55/528, 428/198, 428/283, 428/288, 428/296, 428/302, 428/323
• US Class Current: 96/153
• CPC Class Codes: B01D 39/163 sintered or bonded
• CPC Class Codes: B01J 20/28028 Particles immobilised within fibres or filaments
• CPC Class Codes: D04H 1/413 containing granules other than absorbent substances
• CPC Class Codes: D04H 1/43828 sheath-core
• CPC Class Codes: D04H 1/43832 side-by-side
• CPC Class Codes: D04H 1/43835 Mixed fibres, e.g. at least two chemically different fibres or fibre blends
• CPC Class Codes: D04H 1/5412 sheath-core
• CPC Class Codes: D04H 1/5414 side-by-side
• CPC Class Codes: D04H 1/72 the fibres being randomly arranged
• CPC Class Codes: D04H 1/732 by fluid current, e.g. air-lay
• CPC Class Codes: D04H 5/06 strengthened or consolidated by welding-together thermoplastic fibres, filaments, or yarns
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 442/2893 Coated or impregnated polyamide fiber fabric
• CPC Class Codes: Y10T 442/635 Synthetic polymeric strand or fiber material
• CPC Class Codes: Y10T 442/641 Sheath-core multicomponent strand or fiber material

Abstract

A particulate filter structure and method for making the structure are disclosed. The structure includes a stable framework of relatively large denier fibers having a lower melting component and a higher melting component. The larger denier fibers have a denier of from about 30 dpf or more and are bonded by the lower melting component at the crossover points. Smaller denier fibers, which preferably are of the same composition as the larger denier fibers are immobilized onto the framework formed by the larger denier fibers by applying heat. Functional particulate such as activated carbon is immobilized primarily onto the smaller denier fibers, also by application of heat.

Claims

1. A particulate filter structure comprising a thermally bonded, three dimensional, fibrous framework comprising composite structural fibers having a denier of at least 30 dpf and comprising a structural component and a first lower melting component, said first lower melting component bonding said fibrous framework together at the cross over points;

composite filtration fibers of relatively smaller denier than said structural fibers distributed within and bonded to said fibrous framework and comprising a higher melting component and a second lower melting component, wherein said filtration fibers have a denier of from about 1 to 30 dpf; and

functional particulate distributed within said fibrous framework and entrapped in interstices formed by said filtration fibers and bonded by said second lower melting component to said filtration fibers;

wherein said structural fibers comprise up to about 10 percent of the total weight of said particulate filter structure.

2. The filter structure of claim 1, wherein said structural fibers and said filtration fibers are crimped staple fibers.

3. The filter structure of claim 1, wherein said first lower melting component is a polyamide that melts at a temperature of from about 175°

to 185°

C.

4. The filter structure of claim 1, wherein said structural fibers have a denier of from about 30 to 10,000 dpf.

5. The filter structure of claim 1, wherein said particulate is bonded by said first lower melting component to said structural fibers and said filter structure substantially is formed of said filtration fibers and said functional particulate.

6. The filter structure of claim 1, wherein said second lower melting component is a polyamide that melts at a temperature of from about 175°

to 185°

C.

7. The filter structure of claim 1, wherein said structural fibers are sheath/core heterofilament fibers comprising a polyamide sheath that melts at a temperature of from about 175°

to 185°

C. as said first lower melting component, and a polyester core as said structural component, and wherein said filtration fibers are sheath/core heterofilament fibers comprising a polyamide sheath that melts at a temperature of from about 175°

to 185°

C. as said second lower melting component, and a polyester core as said higher melting component.

8. The fibrous structure of claim 1, wherein said structural component and said first lower melting component differ in melting point by at least 20°

C., and said higher melting component and said second lower melting component differ in melting point by at least 20°

C.

9. The filter structure of claim 1, wherein said functional particulate is selected from the group consisting of activated carbon, silica, zeolite, molecular sieve, clay, alumina, ion exchange resin, organic metal catalyst, metal oxide, biocide, fungicide and virucide.

10. The filter structure of claim 1, wherein said functional particulate is activated carbon.

15. The filter structure of claim 1, wherein said filter structure has a thickness from about 1.0 mm to 250 mm.

11. A particulate filter structure comprising a thermally bonded, three dimensional, fibrous framework comprising crimped composite structural fibers having a denier of from about 30 to 10,000 dpf and comprising a structural component and a first lower melting component, said first lower melting component bonding said fibrous framework together at the cross over points;

crimped composite filtration fibers of relatively smaller denier than said structural fibers distributed within and bonded to said fibrous framework and comprising a higher melting component and a second lower melting component, wherein said filtration fibers have a denier of from about 1 to 30 dpf, and said first lower melting component and said second lower melting component are the same polymer and have similar melting points; and

functional particulate distributed within said fibrous framework and entrapped in interstices formed by said filtration fibers, and bonded to said fibrous framework by said first lower melting component and to said filtration fibers by said second lower melting component;

wherein said structural fibers comprise up to about 10 percent of the total weight of said filter structure and said filter structure substantially is formed of said filtration fibers and said functional particulate.

12. The filter structure of claim 11, wherein said structural fibers are sheath/core heterofilament fibers comprising a polyamide sheath that melts at a temperature of from about 175°

to 185°

C. as said first lower melting component, and a polyester core as said structural component, and wherein said filtration fibers are sheath/core heterofilament fibers comprising a polyester core as said higher melting component.

13. The fibrous structure of claim 11, wherein said structural component and said first lower melting component differ in melting point by at least 20°

C.

14. The filter structure of claim 11, wherein said functional particulate is activated carbon.

16. The filter structure of claim 11, wherein said filter structure has a thickness from about 1.0 mm to 250 mm.