Star polymers having a well-defined siloxane core and multiple polyisobutylene arms and a method for the synthesis thereof

• US 5,663,245 A
• Filed: 03/22/1996
• Issued: 09/02/1997
• Est. Priority Date: 03/22/1996
• Status: Expired due to Fees

• Current Assignee: University of Akron
• Original Assignee: University of Akron
• Inventors: Omura, Naoki, Kennedy, Joseph P., Lubnin, Alexander
• Primary Examiner(s): DEAN JR, RALPH H
• Application Number:
  US08/620,421
• Time in Patent Office: 529 Days
• Field of Search: 528/15, 528/25, 528/31, 525/106, 525/475
• US Class Current: 525/479
• CPC Class Codes: C08G 77/442 containing vinyl polymer sequences
• CPC Class Codes: C08G 81/024 Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G

Abstract

The synthesis and characterization of novel multi-arm star polymers comprising polyisobutylene arms connected to a well-defined, siloxane core are described. The synthesis has been achieved by hydrosilating olefin-capped (e.g., allyl- or isopropenyl-terminated) polyisobutylene with siloxanes carrying a plurality of Si--H groups.

Claims

1. A star polymer comprising:

a core component selected from the group consisting of siloxanes containing at least two Si--H groups; and

a plurality of arms attached to said core component and selected from the group consisting of olefin-terminated polyisobutylenes.

2. The star polymer of claim 1, wherein said siloxanes are cyclosiloxanes.

3. The star polymer of claim 1, wherein said olefin-terminated polyisobutylenes are selected from the group consisting of allyl-terminated polyisobutylenes and isopropenyl-terminated polyisobutylenes.

4. The star polymer of claim 1, wherein said polyisobutylenes have a number average molecular weight of from about 500 g/mol to about 50,000 g/mol.

5. The star polymer of claim 4, wherein said polyisobutylenes have a number average molecular weight of about 1000 g/mol to about 20,000 g/mol.

6. A star polymer having a higher molecular weight than the star polymer of claim 1, formed by the coupling of at least two star polymers of claim 1.

7. The star polymer of claim 1 wherein said core component is an octasilsesquioxane (T₈) core.

8. A composition comprising the star polymer of claim 1.

9. A star polymer comprising:

a core, wherein said core includes a plurality of siloxane groups; and

a plurality of polyisobutylene arms attached to said core.

10. The star polymer of claim 9, wherein each of said polyisobutylene arms has a number average molecular weight of from about 500 g/mol to about 50,000 g/mol.

11. The star polymer of claim 10, wherein each of said polyisobutylene arms has a number average molecular weight of about 1000 g/mol to about 20,000 g/mol.

12. A method for synthesizing a star polymer containing a well-defined, siloxane core and a plurality of olefin-terminated polyisobutylene arms emanating from said siloxane core, comprising the step of:

linking said polyisobutylene arms to said core by hydrosilation.

13. The method of claim 12 wherein said siloxane core is selected from the group consisting of cyclosiloxanes.

14. The method of claim 12 wherein said siloxane core has at least two Si--H groups.

15. The method of claim 13 wherein said polyisobutylene arms are selected from the group consisting of allyl-terminated polyisobutylenes and isopropenyl-terminated polyisobutylenes.

16. The method of claim 12 further comprising the step of increasing the ratio of C═

C groups to Si--H groups so as to eliminate star-star coupling.