Preparation and polymerization of initiators containing multiple oxetane rings: new routes to star polymers

• US 5,663,289 A
• Filed: 10/28/1994
• Issued: 09/02/1997
• Est. Priority Date: 12/11/1992
• Status: Expired due to Fees

• Current Assignee: Aerojet-General Corporation (L3Harris Technologies, Inc.)
• Original Assignee: Aerojet-General Corporation (L3Harris Technologies, Inc.)
• Inventors: Carlson, Roland P., Archibald, Thomas G., Malik, Aslam A., Manser, Gerald E.
• Primary Examiner(s): Acquah, Samuel A.
• Application Number:
  US08/330,480
• Time in Patent Office: 1,040 Days
• Field of Search: 528/414, 528/415, 528/416, 528/417, 525/410
• US Class Current: 528/414
• CPC Class Codes: C07D 305/06 with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring atoms
• CPC Class Codes: C08G 65/12 containing organo-metallic compounds or metal hydrides
• CPC Class Codes: C08G 65/18 Oxetanes
• CPC Class Codes: C08G 65/22 Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
• CPC Class Codes: C08G 65/2645 Metals or compounds thereof, e.g. salts

Abstract

This invention relates to novel multifunctional oxetanes, i.e., compounds having multiple oxetane groups, which are useful as initiators in the preparation of star polymers and polymer cascades containing energetic groups. In addition, this invention relates to a process for the preparation of star polymers and polymer cascades, whereby novel multifunctional oxetanes act as initiators in the formation of theses polymers. The reaction of these initiators with various propagating, high-energy oxetanes, such as 3,3-bis-(azidomethyl)oxetane (BAMO) and 3-nitratomethyl-3-methyloxetane (NMMO), gives star polymers with varying molecular weights and functionalities. The star polymers and polymer cascades of the present invention are useful as binders in high-energy formulations.

Claims

1. A process for the preparation of a star polymer, said process comprising:

(a) forming an initiator compound by reacting a preinitiator precursor with a catalyst, said preinitiator precursor being an organic compound that forms an adduct with said catalyst, and said catalyst being a substance that causes cationic polymerization;

(b) combining said initiator compound with a multioxetane compound to form an initiating species;

said multioxetane compound having the general formula ##STR16## in which;

R¹ and R² are members independently selected from the group consisting of H, lower alkyl, lower alkoxy, Br, Cl, I, NF₂, ONO₂, NO₂, N₃, and N(R³)NO₂, where R³ is H or a lower alkyl; and

n is an integer having a value ranging from 1 to 8;

(c) contacting said initiating species with a monomer that undergoes cationic polymerization; and

(d) allowing polymerization to proceed by chain elongation until the supply of available monomer is substantially exhausted.

2. A process in accordance with claim 1 in which said multioxetane compound is 1,4-bis-[(3-methyl-3-oxetanyl)methyloxy]butane.

3. A process in accordance with claim 1 in which said multioxetane compound is 1,4-bis-[(3-nitratomethyl-3-oxetanyl)methyloxy]butane.

4. A process in accordance with claim 1 in which said multioxetane compound is 1,4-[(3-azidomethyl-3-oxetanyl)methyloxy]butane.

5. A process in accordance with claim 1 in which said multioxetane compound is 1,6-bis-[(3-methyl-3-oxetanyl)methyloxy]hexane.

6. A process for the preparation of a star polymer, said process comprising:

(a) forming an initiator compound by reacting a preinitiator precursor with a catalyst, said preinitiator precursor being an organic compound that forms an adduct with said catalyst, and said catalyst being a substance that causes cationic polymerization;

(b) combining said initiator compound with a multioxetane compound to form an initiating species, said multioxetane compound having the formula ##STR17## in which;

R¹ is a lower alkyl;

R² is a members independently selected from the group consisting of H, lower alkyl, lower alkoxy, Br, Cl, I, NF₂, ONO₂, NO₂, N₃, and N(R³)NO₂, where R³ is H or a lower alkyl; and

n is an integer having a value ranging from 2 to 4;

(c) contacting said initiating species with a monomer that undergoes cationic polymerization; and

(d) allowing polymerization to proceed by chain elongation until the supply of available monomer is substantially exhausted.

7. A process in accordance with claim 6 in which said multioxetane compound is 1,1,1-tris-[(3-methyl-3-oxetanyl)methyloxymethyl]propane.

8. A process in accordance with claim 6 in which said multioxetane compound is tetrakis-[(3-methyl-3-oxetanyl)methyloxymethyl]methane.

9. A process for the preparation of a star polymer, said process comprising:

(a) forming an initiator compound by reacting a preinitiator precursor with a catalyst, said preinitiator precursor being an organic compound that forms an adduct with said catalyst, and said catalyst being a substance that causes cationic polymerization;

(b) combining said initiator compound with a multioxetane compound to form, an initiating species, said multioxetane compound having the formula ##STR18## in which;

R¹ and R² are members independently selected from the group consisting of H, lower alkyl, lower alkoxy, Br, Cl, I, NF₂, ONO₂, NO₂, N₃, and N(R³)NO₂, where R³ is H or a lower alkyl;

(c) contacting said initiating species with a monomer that undergoes cationic polymerization; and

(d) allowing polymerization to proceed by chain elongation until the supply of available monomer is substantially exhausted.

10. A process in accordance with claim 9 in which said multioxetane compound is 3-methyl-3-[3-methyl-3-oxetanyl)methyloxymethyl]oxetane.

11. A process for the preparation of a star polymer, said process comprising:

(a) forming an initiator compound by reacting a preinitiator precursor with a catalyst, said preinitiator precursor being an organic compound that forms an adduct with said catalyst, and said catalyst being a substance that causes cationic polymerization;

(b) combining said initiator compound with a multioxetane compound to form an initiating species, said multioxetane compound having the formula ##STR19## in which;

R¹ and R² are members independently selected from the group consisting of H, lower alkyl, lower alkoxy, Br, Cl, I, NF₂, ONO₂, NO₂, N₃, and N(R³)NO₂, where R³ is H or a lower alkyl;

(c) contacting said initiating species with a monomer that undergoes cationic polymerization; and

(d) allowing polymerization to proceed by chain elongation until the supply of available monomer is substantially exhausted.

12. A process in accordance with claim 11 in which said multioxetane compound is 3,3-bis-[(3-methyl-3-oxetanyl)methyloxymethyl]oxetane.