Processes for coating molded plastic substrates with aqueous coating compositions

• US 5,665,434 A
• Filed: 01/17/1997
• Issued: 09/09/1997
• Est. Priority Date: 12/23/1993
• Status: Expired due to Fees

• Current Assignee: Herberts Gesellschaft Mit Beschrankter Haftung
• Original Assignee: Herberts Gesellschaft Mit Beschrankter Haftung
• Inventors: Mass, Manfred, Kerber, Herrmann, Stegen, Helga
• Primary Examiner(s): Sweet, Mark D.
• Application Number:
  US08/785,697
• Time in Patent Office: 235 Days
• Field of Search: 427/393.5, 524/839, 524/840, 525/123, 525/124, 525/131
• US Class Current: 427/393.5
• CPC Class Codes: C08G 18/0814 containing ammonium groups or groups forming them
• CPC Class Codes: C08G 18/6266 Polymers of amides or imides from alpha-beta ethylenically unsaturated carboxylic acids
• CPC Class Codes: C08G 18/6283 Polymers of nitrogen containing compounds having carbon-to-carbon double bonds C08G18/6262, C08G18/6266 take precedence
• CPC Class Codes: C09D 175/12 from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group

Abstract

Aqueous coating composition based on polyols with ammonium groups and polyisocyanates, which coating composition may contain pigments and/or extenders, customary lacquer additives and one or more organic solvents, and contains

A) as binder at least one (meth)acrylic copolymer with a hydroxyl value of 20 to 150 mg KOH/g and with an amine value of 10 to 150 mg KOH/g, both values being related to solid resin, wherein 2 to 50 wt.% of the solid binder resin may be replaced with one or more other binders, wherein the (meth)acrylic copolymer is neutralised with an acid containing at least one isocyanate-reactive group; and

B) as crosslinking agent at least one polyisocyanate, which may be blocked,

wherein components A) and B) are present in quantities such that the ratio of the sum of isocyanate-reactive groups in the binder component A) to the blocked and unblocked isocyanates in component B) is 1:0.5 to 1:3. The coating composition is in particular suitable for use in the production of coatings on plastic substrates.

Claims

1. A method of coating plastic components including the steps of:

(i) forming a molded plastic substrate;

(ii) applying an aqueous coating composition to said substrate;

(iii) such aqueous coating composition being based on polyols with ammonium groups and polyisocyanates, which coating composition may contain pigments and/or extenders, customary lacquer additives and one or more organic solvents, characterized in that it contains;

A) as binder at least one (meth)acrylic copolymer with a hydroxyl value of 20 to 150 mg KOH/g and with an amine value of 10 to 150 mg KOH/g, both values being related to solid resin, wherein 2 to 50 wt. % of the solid binder resin may be replaced with one or more other binders, wherein the (meth)acrylic copolymer is neutralized with an acid containing at least one isocyanate-reactive group; and

B) as crosslinking agent at least one polyisocyanate, which may be blocked,

wherein components A) and B) are present in quantities such that the ratio of the sum of isocyanate-reactive groups in the binder component A) to the blocked and unblocked isocyanates in component B) is 1;

0.5 to 1;

3.

2. The method of claim 1 in which said coating composition of step (iii) is characterized in that the acid having at least one isocyanate-reactive group for neutralizing the (meth)acrylic copolymer is selected from the group consisting of mono- or polybasic carboxylic acids, phosphonic acids and sulfonic acids with at least one primary amine and/or secondary amine and/or hydroxy and/or mercapto group in the molecule.

3. The method of claim 2 in which the coating composition of step (iii) is characterized in that a hydroxycarboxylic acid, dihydroxycarboxylic acid or polyhydroxycarboxylic acid is present as the acid having at least one isocyanate-reative group.

4. The method of claim 3 in which the coating composition of step (iii) is characterized in that the (meth)acrylic copolymer of component A) has a weight average molecular weight (M_W) of 2000 to 15000.

5. The method of claim 4 in which the coating composition of step (iii) is characterized in that the (meth)acrylic copolymer of component A) may be obtained by free-radical initiated polymerization of 0.5 to 40 wt. % of one or more (meth)acrylamides of -tert.-aminoalkylamines and/or one or more (meth)acrylates of -tert.-amino alcohols, 5 to 40 wt. % of one or more hydroxyalkyl (meth)acrylates and/or one or more hydroxyalkyl (meth)acrylamides and 20 to 94.5 wt. % of one or more different co-monomers.

6. The method of claim 5 in which the coating composition of step (iii) is characterized in that the acids having at least one isocyanate-reactive group are added in a quantity such that 0.6 to 1.5 equivalents of acid are present per amine equivalent in the (meth)acrylic copolymer (A).

7. The method of claim 6 in which the coating composition of step (iii) is characterized in that ocmponent A) contains as an additional binder one or more polyesters, polyurethanes and/or different (meth)acrylic copolymers.