Solid polymer electrolyte, battery and solid-state electric double layer capacitor using the same as well as processes for the manufacture thereof
First Claim
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1. A solid polymer electrolyte comprising a composite of:
- (a) a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of;
(i) a polymer obtained from at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxy groups is replaced by a unit represented by general formula (X);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 -- (X)wherein R1 represents a hydrogen or a methyl group;
R2 represents a divalent organic group containing at least one oxyalkylene group and said organic group may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen;
x and y each represents zero or an integer of between 1 and 5;
z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero;
wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (X) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, provided that each of R1, R2, x, y and z of each said unit of formula (X) are as defined above and each unit may be the same or different; and
(ii) a copolymer comprising at least one of said compounds as a co-monomer; and
(b) at least one electrolyte salt.
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Abstract
A solid polymer electrolyte comprising a composite of (a) a polymeric component which comprises (i) a polymer obtained from at least one compound represented by general formula (IA), (IIA) and/or (IIIA) as described in the specification; or (ii) a polymer obtained from at least one compound having alcoholic hydroxyl groups wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (X) or (XI) as described in the specification, and (b) at least one electrolyte salt, which has a high ionic conductivity and can be made into a thin film. The present invention is also directed to an electrode comprising the solid polymer electrolyte and an electroactive substance or polarizable material; as well as a process for manufacturing the same. In addition, the present invention is directed to a primary and secondary battery having the solid polymer electrolyte, as well as a process for manufacturing the same. The battery of the present invention has a high battery, has good cyclability. Finally, the present invention is directed to a solid-state electric double layer capacitor comprising the solid polymer electrolyte, as well as a process for manufacturing the same. The electric double layer capacitor has a high output voltage and a large take-out current.
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Citations
53 Claims
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1. A solid polymer electrolyte comprising a composite of:
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(a) a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of; (i) a polymer obtained from at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxy groups is replaced by a unit represented by general formula (X);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 -- (X)wherein R1 represents a hydrogen or a methyl group; R2 represents a divalent organic group containing at least one oxyalkylene group and said organic group may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (X) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, provided that each of R1, R2, x, y and z of each said unit of formula (X) are as defined above and each unit may be the same or different; and (ii) a copolymer comprising at least one of said compounds as a co-monomer; and (b) at least one electrolyte salt. - View Dependent Claims (5, 9, 13, 17, 18, 19, 20, 40)
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2. A solid polymer electrolyte comprising a composite of:
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(a) a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of; (i) a polymer obtained from at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (XI);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)(OR.sup.3).sub.n -- (XI)wherein R1 represents a hydrogen or a methyl group; R3 each represent --(CH2)2 --, --CH(CH3)CH2 -- or --CH2 CH(CH3)--; x and y each represent zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; n represents an integer of one or more; wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (XI) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, provided that each of R1, R3, x, y and z of each said unit of formula (XI) are as defined above and each unit may be the same or different; and (ii) a copolymer comprising at least one of said compounds as a co-monomer; and (b) at least one electrolyte salt. - View Dependent Claims (6, 10, 14)
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3. A solid polymer electrolyte comprising a composite of:
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(a) a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of; (i) a polymer obtained from at least one compound represented by general formula (IA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(C.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 (IA)wherein R1 represents a hydrogen or a methyl group; R2 represents an organic chain containing at least one oxyalkylene group and said organic chain may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; wherein subunit {O(CH2)x (CH(CH3))y }z of said formula (IA) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, and (ii) a copolymer comprising at least one of said compounds as a co-monomer; and (b) at least one electrolyte salt. - View Dependent Claims (7, 11, 15)
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4. A solid polymer electrolyte comprising a composite of:
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(a) a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of; (i) a polymer obtained from at least one compound represented by general formula (IIA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O(R.sup.3 O).sub.n R.sup.4 (IIA)wherein R3 represents --(CH2)2 -- or --CH(CH3)CH2 --; R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2 or --C(═
O)NHC(═
O)CH═
CH2 ;n represents an integer of 1 or more; wherein subunits {O(CH2)x (CH(CH3))y }z and {O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements; x'"'"' and y'"'"' each represent zero or an integer of between 1 and 5; z'"'"' represents zero or an integer of between 1 to 10, provided that z'"'"' is zero when both x'"'"' and y'"'"' are zero; R1 represents a hydrogen or a methyl group, x and y each represent zero or an integer between 1 and 5; and z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; (ii) a polymer obtained from at least one compound represented by general formula (IIIA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O {(R.sup.6 O).sub.m C(═
O)NHR.sup.5 NHC(═
O)O}.sub.k (R.sup.3 O).sub.n R.sup.4 (IIIA)wherein R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2, --C (═
O)NHC(═
O)CH═
CH2 or --{C(═
O)NHR5 NHC(═
O)(OR6)m }k OC(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(R1)═
CH2;
wherein subunits {O(CH2)x (CH(CH3))y }z and --{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements;R5 represents an alkylene, allylene, arylene or oxyalkylene group having 1 to 20 carbon atoms; n, m and k respectively represent an integer of 1 or more; R6 represents --(CH2)2 -- or --CH(CH3)CH2 --; R1, R3, x, y, z, x'"'"', y'"'"' and z'"'"' each means the same as above; and (iii) a copolymer comprising at least one of said compounds represented by general formula (IIA) or (IIIA) as a co-monomer; and (b) at least one electrolyte salt. - View Dependent Claims (8, 12, 16)
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21. An electrode comprising:
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(a) a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of; (i) a polymer obtained from at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (X);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 -- (X)wherein R1 represents a hydrogen or a methyl group; R2 represents a divalent organic group containing at least one oxyalkylene group and said organic group may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (X) may comprise substituents (CH2) and (CH(CH3)) in various arrangements provided that each of R1, R2, x, y and z of each said unit of formula (X) are as defined above and each unit may be the same or different; and (ii) a copolymer comprising at least one of said compounds as a co-monomer; and (b) at least one electroactive substance or polarizable material. - View Dependent Claims (25)
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22. An electrolyte comprising:
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(a) a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of; (i) a polymer obtained from at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (XI);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)(OR.sup.3).sub.n -- (XI)wherein R1 represents a hydrogen or a methyl group; R3 each represent --(CH2)2 --, --CH(CH3)CH2 -- or --CH2 CH (CH3)--; x and y each represent zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; n represents an integer of one or more; wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (XI) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, provided that each of R1, R3, x, y and z of each said unit of formula (XI) are as defined above and each unit may be the same or different; and (ii) a copolymer comprising at least one of said compounds as a co-monomer; and (b) at least one electroactive substance or polarizable material.
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23. An electrode comprising:
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(a) a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of; (i) a polymer obtained from at least one compound represented by general formula (IA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 (IA)wherein R1 represents a hydrogen or a methyl group; R2 represents an organic chain containing at least one oxyalkylene group and said organic chain may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; wherein subunit {O(CH2)x (CH(CH3))y }z of said formula (IA) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, and (ii) a copolymer comprising at least one of said compounds as a co-monomer; and (b) at least one electroactive substance or polarizable material.
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24. An electrode comprising:
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(a) a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of; (i) a polymer obtained from at least one compound represented by general formula (IIA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O(R.sup.3 O).sub.n R.sup.4 (IIA)wherein R3 represents --(CH2)z -- or --CH(CH3)CH2 --; R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2 or --C(═
O)NHC(═
O)CH═
CH2 ;n represents an integer of 1 or more; wherein subunits {O(CH2)x (CH(CH3))y }z and {O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements; x'"'"' and y'"'"' each represent zero or an integer of between 1 and 5; z'"'"' represents zero or an integer of between 1 to 10, provided that z'"'"' is zero when both x'"'"' and y'"'"' are zero; R1 represents a hydrogen or a methyl group, x and y each represent zero or an integer between 1 and 5; and z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero, (ii) a polymer obtained from at least one compound represented by general formula (IIIA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O {(R.sup.6 O).sub.m C(═
O)NHR.sup.5 NHC(═
O)O}.sub.k (R.sup.3 O).sub.n R.sup.4 (IIIA)wherein R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)CH═
CH2 or --{C(═
O)NHR5 NHC(═
O)(OR6)m }k OC(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(R1)═
CH2 ;
wherein subunits {O(CH2)x (CH(CH3))y }z and {O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements;R5 represents an alkylene, allylene, arylene or oxyalkylene group having 1 to 20 carbon atoms; n, m and k respectively represent an integer of 1 or more; R6 represents --(CH2)2 -- or --CH(CH3)CH2 --; R1, R3, x, y, z, x'"'"', y'"'"' and z'"'"' each means the same as above, and (iii) a copolymer comprising at least one of said compound represented by general formula (IIA) or (IIIA) as a co-monomer; and (b) at least one electroactive substance or polarizable material.
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26. A process for manufacturing an electrode comprising a step of polymerizing a polymerizable monomer mixture comprising
(a) at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (X): -
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 -- (X)wherein R1 represents a hydrogen or a methyl group; R2 represents a divalent organic group containing at least one oxyalkylene group and said organic group may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (X) may comprise substituents (CH2) and (CH (CH3)) in various arrangements, provided that each of R1, R2, x, y and z of each said unit of formula (X) are as defined above and each unit may be the same or different; and (b) an electroactive substance or polarizable material. - View Dependent Claims (27, 34)
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28. A process for manufacturing an electrode comprising a step of polymerizing a polymerizable monomer mixture comprising
(a) at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (XI): -
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)(OR.sup.3).sub.n -- (XI)wherein R1 represents a hydrogen or a methyl group; R3 each represent --(CH2)2, --CH(CH3)CH2 -- or --CH2 CH(CH3)--; x and y each represent zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; n represents an integer of one or more; wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (XI) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, provided that each of R1, R3, x, y and z of each said unit of formula (XI) are as defined above and each unit may be the same or different; and (b) an electroactive substance or polarizable material. - View Dependent Claims (29)
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30. A process for manufacturing an electrode which comprises a step of polymerizing a polymerizable monomer mixture comprising
(a) at least one compound represented by general formula (IA): -
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 (IA)wherein R1 represents a hydrogen or a methyl group; R2 represents an organic chain containing at least one oxyalkylene group and said organic chain may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero;
wherein subunit {O(CH2)x (CH(CH3))y}z of said formula (IA) may comprise substituents (CH2) and (CH(CH3)) in various arrangements; and(b) at least one electroactive substance or polarizable material. - View Dependent Claims (31)
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32. A process for manufacturing an electrode which comprises a step of polymerizing a polymerizable monomer mixture comprising
(a) at least one compound represented by (i) general formula (IIA): -
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O(R.sup.3 O).sub.n R.sup.4 (IIA)wherein R3 represents --(CH2)2 -- or --CH(CH3)CH2 --; R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2 or --C(═
O)NHC(═
O)CH═
CH2 ;n represents an integer of 1 or more; wherein subunits {O(CH2)x (CH(CH3))y }z and {O(CHz)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements; x'"'"' and y'"'"' each represent zero or an integer of between 1 and 5; z'"'"' represents zero or an integer of between 1 to 10, provided that z'"'"' is zero when both x'"'"' and y'"'"' are zero; R1 represents a hydrogen or a methyl group, x and y each represent zero or an integer between 1 and 5; and z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero, or by (ii) general formula (IIIA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O {(R.sup.6 O).sub.m C(═
O)NHR.sup.5 NHC(═
O)O}.sub.k (R.sup.3 O).sub.n R.sup.4 (IIIA)wherein R4 represents an alkyl group having 1 to 10 carbon atoms, C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)CH═
CH2 or --{C(═
O)NHR5 NHC(═
O)(OR6)m }k OC(═
O)NH{O(CH2)x'"'"' (CH (CH3))y'"'"' }z'"'"' OC(═
O)C(R1)═
CH2 ;
wherein subunits {O(CH2)x (CH(CH3))y }z and {O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements;R5 represents an alkylene, allylene, arylene or oxyalkylene group having 1 to 20 carbon atoms; n, m and k respectively represents an integer of 1 or more; R6 represents --(CH2)2 -- or --CH(CH3)CH2 --; R1, R3, x, y, z, x'"'"', y'"'"' and z'"'"' each means the same as above, and (b) at least one electroactive substance or polarizable material. - View Dependent Claims (33)
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35. A process for manufacturing a battery comprising the steps of:
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(a) placing a polymerizable monomer mixture in a frame for construction of a battery or on a support; and (b) polymerizing said polymerizable monomer mixture, wherein said mixture comprises (i) at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (X);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 -- (X)wherein R1 represents a hydrogen or a methyl group; R2 represents a divalent organic group containing at least one oxyalkylene group and said organic group may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (X) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, provided that each of R1, R2, x, y and z of each said unit of formula (X) are as defined above and each unit may be the same or different, and (ii) at least one electrolyte salt. - View Dependent Claims (39)
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36. A process for manufacturing a battery comprising the steps of:
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(a) placing a polymerizable monomer mixture in a frame for construction of a battery or on a support, and (b) polymerizing said polymerizable monomer mixture, wherein said mixture comprises (i) at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (XI);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)(OR.sup.3).sub.n -- (XI)wherein R1 represents a hydrogen or a methyl group; R3 each represent --(CH2)2 --, --CH(CH3)CH2 -- or --CH2 CH(CH3)--; x and y each represent zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; n represents an integer of one or more; wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (XI) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, provided that each of R1, R3, x, y and z of each said unit of formula (XI) are as defined above and each unit may be the same or different; and (ii) at least one electrolyte salt.
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37. A process for manufacturing a battery comprising the steps of:
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(a) placing a polymerizable monomer mixture in a frame for construction of a battery or on a support, and (b) polymerizing said polymerizable monomer mixture, wherein said mixture comprises (i) at least one compound represented by general formula (IA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 (IA)wherein R1 represents a hydrogen or a methyl group; R2 represents an organic chain containing at least one oxyalkylene group and said organic chain may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represent zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero, wherein subunit {O(CH2)x (CH(CH3))y }z of said formula (IA) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, and (ii) at least one electrolyte salt.
-
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38. A process for manufacturing a battery comprising the steps of:
-
(a) placing a polymerizable monomer mixture in a frame for construction of a battery or on a support, and (b) polymerizing said polymerizable monomer mixture, wherein said mixture comprises (i) at least one compound represented by general formula (IIA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O(R.sup.3 O).sub.n R.sup.4 (IIA)wherein R3 represents --(CH2)2 -- or --CH(CH3)CH2 --; R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2 or --C(═
O)NHC(═
O)CH═
CH2 ;n represents an integer of 1 or more; wherein subunit {O(CH2)x (CH(CH3))y }z and {O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements; x'"'"' and y'"'"' each represent zero or an integer of between 1 and 5; z'"'"' represents zero or an integer of between 1 to 10, provided that z'"'"' is zero when both x'"'"' and y'"'"' are zero; R1 represents a hydrogen or a methyl group, x and y each represent zero or an integer between 1 and 5; and z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero, or by general formula (IIIA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O {(R.sup.6 O).sub.m C(═
O)NHR.sup.5 NHC(═
O)O}.sub.k (R.sup.3 O).sub.n R.sup.4 (IIIA)wherein R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)CH═
CH2 or --{C(═
O)NHR5 NHC(═
O)(OR6)m }k OC(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(R1)═
CH2 ;
wherein subunits {O(CH2)x (CH(CH3))y }z and {O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements;R5 represents an alkylene, allylene, arylene or oxyalkylene group having 1 to 20 carbon atoms; n, m and k respectively represent an integer of 1 or more; R6 represents --(CH2)2 -- or --CH(CH3)CH2 --; R1, R3, x, y, z, x'"'"', y'"'"' and z'"'"' each means the same as above; and (ii) at least one electrolyte salt.
-
-
41. An electric double layer capacitor comprising polarizable electrodes and an ionic conducting substance arranged between the electrodes, wherein said polarizable electrodes comprise a carbon material and a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of:
-
(a) a polymer obtained from at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (X);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 -- (X)wherein R1 represents a hydrogen or a methyl group; R2 represents a divalent organic group containing at least one oxyalkylene group and said organic group may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (X) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, provided that each of R1, R2, x, y and z of each said unit of formula (X) are as defined above and each unit may be the same or different, and (b) a copolymer comprising at least one of said compounds as a co-monomer.
-
-
42. An electric double layer capacitor comprising polarizable electrodes and an ionic conducting substance arranged between the electrodes, wherein said polarizable electrodes comprise a carbon material and a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of:
-
(a) a polymer obtained from at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (XI);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)(OR.sup.3).sub.n -- (XI)wherein R1 represents a hydrogen or a methyl group; R3 each represent --(CH2)2 --, --CH(CH3)CH2 -- or --CH2 CH(CH3)--; x and y each represent zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; n represents an integer of one or more; wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (XI) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, provided that each of R1, R3, x, y and z of each said unit of formula (XI) are as defined above and each unit may be the same or different; and (b) a copolymer comprising at least one of said compounds as a co-monomer.
-
-
43. An electric double layer capacitor comprising polarizable electrodes and an ionic conducting substance arranged between the electrodes, wherein said polarizable electrodes comprise a carbon material and a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of
(a) a polymer obtained from at least one compound represented by general formula (IA): -
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 (IA)wherein R1 represents a hydrogen or a methyl group; R2 represents an organic chain containing at least one oxyalkylene group and said organic chain may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; wherein subunit {O(CH2)x (CH(CH3))y }z of said formula (IA) may comprise substituents (CH2) and (CH(CH3)) in various arrangements; and (b) a copolymer comprising at least one of said compounds as a co-monomer.
-
-
44. An electric double layer capacitor comprising polarizable electrodes and an ionic conducting substance arranged between the electrodes, wherein said polarizable electrodes comprise a carbon material and a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of
(a) a polymer obtained from at least one compound represented by (i) general formula (IIA): -
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O(R.sup.3 O).sub.n R.sup.4 (IIA)wherein R3 represents --(CH2)2 -- or --CH(CH3)CH2 --; R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2 or --C(═
O)NHC(═
O)CH═
CH2 ;n represents an integer of 1 or more; wherein subunit {O(CH2)x (CH(CH3))y }z and {O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements; x'"'"' and y'"'"' each represent zero or an integer of between 1 and 5; z'"'"' represents zero or an integer of between 1 to 10, provided that z'"'"' is zero when both x'"'"' and y'"'"' are zero; R1 represents a hydrogen or a methyl group, x and y each represent zero or an integer between 1 and 5; and z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero, or by (ii) general formula (IIIA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O {(R.sup.6 O).sub.m C(═
O)NHR.sup.5 NHC(═
O)O}.sub.k (R.sup.3 O).sub.n R.sup.4 (IIIA)wherein R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)CH═
CH2 or --{C(═
O)NHR5 NHC(═
O)(OR6)m }k OC(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(R1)═
CH2 ;
wherein subunits {O(CH2)x)(CH(CH3))y }z and {O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements, R5 represents an alkylene, allylene, arylene or oxyalkylene group having 1 to 20 carbon atoms;n, m and k respectively represent an integer of 1 or more; R6 each independently represents --(CH2)2 -- or --CH(CH3)CH2 --; R1, R3, x, y, z, x'"'"', y'"'"' and z'"'"' each means the same as above, and (b) a copolymer comprising at least one of said compounds as a co-monomer.
-
-
45. An electric double layer capacitor comprising polarizable electrodes and an ionic conducting substance arranged between the electrodes, wherein said polarizable electrodes are those manufactured by polymerizing a polymerizable monomer mixture comprising a carbon material and at least one compound represented by general formula (IA):
-
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 (IA)wherein R1 represents a hydrogen or a methyl group; R2 represents an organic chain containing at least one oxyalkylene group and said organic chain may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero;
wherein subunit {O(CH2)x (CH(CH3))y }z of said formula (IA) may comprise substituents (CH2) and (CH(CH3)) in various arrangements.
-
-
46. An electric double layer capacitor comprising polarizable electrodes and an ionic conducting substance arranged between the electrodes, wherein said polarizable electrodes are those manufactured by polymerizing a polymerizable monomer mixture comprising a carbon material and at least one compound represented by
(i) general formula (IIA): -
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O(R.sup.3 O).sub.n R.sup.4 (IIA)wherein R3 represents --(CH2)2 -- or --CH(CH3)CH2 --; R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2 or --C(═
O)NHC(═
O)CH═
CH2 ;n represents an integer of 1 or more; wherein subunit {O(CH2)x (CH(CH3))y }z and {O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements; x'"'"' and y'"'"' each represent zero or an integer of between 1 and 5; z'"'"' represents zero or an integer of between 1 to 10, provided that z'"'"' is zero when both x'"'"' and y'"'"' are zero; R1 represents a hydrogen or a methyl group, x and y each represent zero or an integer between 1 and 5; and z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero, or by (ii) general formula (IIIA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O {(R.sup.6 O).sub.m C(═
O)NHR.sup.5 NHC(═
O)O}.sub.k (R.sup.3 O).sub.n R.sup.4 (IIIA)wherein R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2 or --C(═
O)NHC(═
O)CH═
CH2 or --{C(═
O)NHR5 NHC(═
O)(OR6)m }k OC(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(R1)═
CH2 ;
wherein subunits {O(CH2)x (CH(CH3))y }z and {O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements, R5 represents an alkylene, allylene, arylene or oxyalkylene group having 1 to 20 carbon atoms;n, m and k respectively represent an integer of 1 or more; R6 each independently represents --(CH2)2 -- or --CH(CH3)CH2 --; R1, R3, x, y, z, x'"'"', y'"'"' and z'"'"' each means the same as above.
-
-
47. A process for manufacturing an electric double layer capacitor which comprises the steps of:
-
(a) placing a polymerizable monomer mixture in a frame for construction of an electric double layer capacitor or on a support, and (b) polymerizing said polymerizable monomer mixture, wherein said mixture comprises (i) at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (X);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 -- (X)wherein R1 represents a hydrogen or a methyl group; R2 represents a divalent organic group containing at least one oxyalkylene group and said organic group may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (X) may comprise substituents (CH2) and (CH(CH3)) in various arrangements provided that each of R1, R2, x, y and z of each said unit of formula (X) are as defined above and each unit may be the same or different; and (ii) at least one electrolyte salt. - View Dependent Claims (51)
-
-
48. A process for manufacturing an electric double layer capacitor which comprises the steps of:
-
(a) placing a polymerizable monomer mixture in a frame for construction of an electric double layer capacitor or on a support, and (b) polymerizing said polymerizable monomer mixture, wherein said mixture comprises (i) at least one compound having alcoholic hydroxyl groups, wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (XI);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)(OR.sup.3).sub.n -- (XI)wherein R1 represents a hydrogen or a methyl group; R3 each represent --(CH2)2 --, --CH(CH3)CH2 -- or --CH2 CH(CH3)--; x and y each represent zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; n represents an integer of one or more; wherein subunit {O(CH2)x (CH(CH3))y }z of said unit of formula (XI) may comprise substituents (CH2) and (CH(CH3)) in various arrangements, provided that each of R1, R3, x, y and z of each said unit of formula (XI) are as defined above and each unit may be the same or different, and (ii) at least one electrolyte salt.
-
-
49. A process for manufacturing an electric double layer capacitor which comprises the steps of:
-
(a) placing a polymerizable monomer mixture in a frame for construction of an electric double layer capacitor or on a support, and (b) polymerizing said polymerizable monomer mixture, wherein said mixture comprises (i) at least one compound represented by general formula (IA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3).sub.y }.sub.z NHC(═
O)OR.sup.2 (IA)wherein R1 represents a hydrogen or a methyl group; R2 represents an organic chain containing at least one oxyalkylene group and said organic chain may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero; wherein subunit {O(CH2)x (CH(CH3))y }z of said formula (IA) may comprise substituents (CH2) and (CH(CH3)) in various arrangements; and (ii) at least one electrolyte salt.
-
-
50. A process for manufacturing an electric double layer capacitor which comprises the steps of:
-
(a) placing a polymerizable monomer mixture in a frame for construction of an electric double layer capacitor or on a support, and (b) polymerizing said polymerizable monomer mixture, wherein said mixture comprises (i) at least one compound represented by (i) general formula (IIA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O(R.sup.3 O).sub.n R.sup.4 (IIA)wherein R3 represents --(CH2)2 -- or --CH(CH3)CH2 --; R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2 --;
--C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)C(CH2)═
CH2 or --C(═
O)NHC(═
O)CH═
CH2 ;n represents an integer of 1 or more; wherein subunit {O(CH2)x (CH(CH3))y }z and {O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements; x'"'"' and y'"'"' each represent zero or an integer of between 1 and 5; z'"'"' represents zero or an integer of between 1 to 10, provided that z'"'"' is zero when both x'"'"' and y'"'"' are zero; R1 represents a hydrogen or a methyl group, x and y each represent zero or an integer between 1 and 5; and z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero;
or by(ii) general formula (IIIA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)O {(R.sup.6 O).sub.m C(═
O)NHR.sup.5 NHC(═
O)O}.sub.k (R.sup.3 O).sub.n R.sup.4 (IIIA)wherein R4 represents an alkyl group having 1 to 10 carbon atoms, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)CH═
CH2, --C(═
O)NH{O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' OC(═
O)C(CH3) ═
CH2, --C(═
O)NHC(═
O)C(CH3)═
CH2, --C(═
O)NHC(═
O)CH═
CH2 or --{C(═
O)NHR5 NHC(═
O)(OR6)m }k OC(═
O)NH{O(CH2)x'"'"' (CH(CH3))y '"'"'}z'"'"' OC(═
O)C(R1)═
CH2 ;
wherein subunits {O(CH2)x (CH(CH3))y }z and {O(CH2)x'"'"' (CH(CH3))y'"'"' }z'"'"' of said formula (IIIA) or above unit representing R4 may comprise substituents (CH2) and (CH(CH3)) in various arrangements;R5 represents an alkylene, allylene, arylene or oxyalkylene group having 1 to 20 carbon atoms; n, m and k respectively represent an integer of 1 or more; R6 each independently represents --(CH2)2 -- or --CH(CH3)CH2 --; R1, R3, x, y, Z, x'"'"' y '"'"' and z each means the same as above, and (ii) at least one electrolyte salt.
-
-
52. A process for manufacturing an electric double layer capacitor which comprises the steps of:
-
(a) arranging a pair of polarizable electrodes so as to face each other, said electrodes comprising a carbon material and a polymeric component, wherein said polymeric component comprises at least one member selected from the group consisting of;
(i) a polymer obtained from at least one compound represented by general formula (IA);
space="preserve" listing-type="equation">CH.sub.2 ═
C(R.sup.1)C(═
O){O(CH.sub.2).sub.x (CH(CH.sub.3)).sub.y }.sub.z NHC(═
O)OR.sup.2 (IA)wherein R1 represents a hydrogen or a methyl group; R2 represents an organic chain containing at least one oxyalkylene group and said organic chain may be linear, branched or cyclic and may contain one or more atoms other than carbon, hydrogen or oxygen; x and y each represents zero or an integer of between 1 and 5; z represents zero or an integer of between 1 and 10, provided that z is zero when both x and y are zero;
wherein subunit {O(CH2)x (CH(CH3))y }z of said formula (IIA) may comprise substituents (CH2) and (CH(CH3)) in various arrangements; and(ii) a copolymer comprising at least one of said compounds as a co-monomer; (b) placing in between said facing electrodes a polymerizable monomer mixture comprising at least one compound represented by general formula (IA) and at least one electrolyte salt; and (c) polymerizing said polymerizable monomer mixture. - View Dependent Claims (53)
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Specification
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- Resources
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Current AssigneeShowa Denko KK (Resonac Holdings Corp.)
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Original AssigneeShowa Denko KK (Resonac Holdings Corp.)
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InventorsTakeuchi, Masataka, Tokita, Koji, Ooga, Kazuhiko, Tamura, Eri, Noguchi, Jun, Ueda, Miyuki, Yashima, Hideo
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Primary Examiner(s)NUZZOLILLO, MARIA
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Application NumberUS08/478,760Time in Patent Office825 DaysField of Search429/191, 429/192, 429/213, 429/212, 429/218, 29/623.1, 361/212, 361/301.1, 361/305, 361/306.3, 361/311, 361/361, 252/62.2, 252/500, 252/518US Class Current429/314CPC Class CodesC08F 290/062 PolyethersC08F 290/142 PolyethersC08G 18/283 Compounds containing ether ...C08G 18/2835 having less than 5 ether gr...C08G 18/4833 Polyethers containing oxyet...C08G 18/4837 and other oxyalkylene unitsC08G 18/4883 containing cyclic groups ha...C08G 18/8116 esters of acrylic or alkyla...C08G 65/329 with organic compoundsC08G 65/3322 acyclicC08G 65/33348 containing isocyanate groupH01B 1/122 Ionic conductorsH01G 11/56 Solid electrolytes, e.g. ge...H01G 11/64 characterised by additivesH01G 9/025 Solid electrolytes H01G11/5...H01M 10/052 Li-accumulatorsH01M 10/0565 Polymeric materials, e.g. g...H01M 4/621 BindersH01M 4/622 being polymersH01M 6/181 with polymeric electrolytesView All
