Silver halide emulsion and photographic material using the same

• US 5,665,530 A
• Filed: 08/30/1995
• Issued: 09/09/1997
• Est. Priority Date: 08/30/1994
• Status: Expired due to Term

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Shiozawa, Takekimi, Yamashita, Seiji, Oyamada, Takayoshi
• Primary Examiner(s): Huff, Mark F.
• Application Number:
  US08/521,579
• Time in Patent Office: 741 Days
• Field of Search: 430/139, 430/508, 430/509, 430/524, 430/512, 430/567, 430/966, 430/603, 430/605
• US Class Current: 430/567
• CPC Class Codes: G03C 1/0051 Tabular grain emulsions
• CPC Class Codes: G03C 1/46 having more than one photosensitive layer G03F7/0952 takes precedence
• CPC Class Codes: G03C 1/815 characterised by means for filtering or absorbing ultraviolet light, e.g. optical bleaching for photoprinting G03C5/10; for intensifying X-ray images G03C5/17
• CPC Class Codes: G03C 1/853 Inorganic compounds, e.g. metals
• CPC Class Codes: G03C 2001/0056 Disclocations
• CPC Class Codes: G03C 2200/01 100 crystal face
• CPC Class Codes: G03C 2200/43 Process
• CPC Class Codes: G03C 5/17 using screens to intensify X-ray images X-ray conversion screens G21K4/00
• CPC Class Codes: Y10S 430/167 X-ray

Abstract

A silver halide emulsion which comprises at least one dispersion medium and silver halide grains, wherein not less than 30% of the total projected area of the silver halide grains accounts for tabular grains each (i) having a {100} face as a major face, (ii) having an aspect ratio (diameter/thickness) of not less than 1.5, and (iii) having a nucleus during nucleus formation, the nucleus being present within the square of not more than 10% of the entire projected area of each of said silver halide grains when viewed the silver halide grains from the vertical direction to the major faces, the square containing one corner of each of said silver halide grains.

Claims

1. A silver halide emulsion which comprises at least one dispersion medium and a plurality of silver halide grains, wherein at least 30% of the total grain projected area of said silver halide grains is accounted for by tabular grains having (i) a {100} face as a major face, (ii) a diameter/thickness aspect ratio of at least 1.5, (iii) a nucleus formed during nucleus formation, said nucleus being present within a square of not more than 10% of the entire projected area of each of said silver halide grains upon viewing said silver halide grains from a direction perpendicular to the major faces, the square containing one corner of each of said silver halide grains, and (iv) a dislocation line, there occurring only one edge intersection of said dislocation line or an extension line of said dislocation line at or within 15% edge length from the nucleus-containing corner upon viewing the silver halide grains from a direction perpendicular to the major faces.

2. The silver halide emulsion as claimed in claim 1, wherein each tabular grain has two dislocation lines thereon.

3. The silver halide emulsion as claimed in claim 1, wherein the only one edge intersection of said dislocation line or the extension line of said dislocation line is at or within 7% edge length from the nucleus-containing corner upon viewing the silver halide grains from a direction perpendicular to the major faces.

4. The silver halide emulsion as claimed in claim 1, wherein at least 40% of the total grain projected area of said silver halide grains is accounted for by said tabular grains.

5. A silver halide emulsion as claimed in claim 1 which comprises at least one dispersion medium and a plurality of silver halide grains, wherein, after nucleus formation, and during physical ripening and/or during grain growth, and when 5 to 99% of silver amount is added based on the silver amount of the completed silver halide grains, at least one of a nucleus and a dislocation line are observed upon viewing said silver halide grains from a direction perpendicular to the major faces,

said nucleus being present within a square of not more than 10% of the entire projected area of each of said silver halide grains, the square containing one corner of each of said silver halide grains,

there occurring only one edge intersection of said dislocation line or an extension line of said dislocation line at or within 15% edge length from the nucleus-containing corner of each of said silver halide grains.

6. The silver halide emulsion as claimed in claim 1, which is gold and/or chalcogen sensitized.

7. A silver halide photographic material comprising a support having provided thereon at least one emulsion layer, wherein a dissolution resistant electrically conductive material is contained in the emulsion layer side of the support, and wherein said at least one emulsion layer containing a silver halide emulsion comprises at least one dispersion medium and a plurality of silver halide grains, wherein at least 30% of the total grain projected area of said silver halide grains is accounted for by tabular grains having (i) a {100} face as a major face, (ii) a diameter/thickness aspect ratio of at least 1.5, (iii) a nucleus formed during nucleus formation, said nucleus being present within a square of not more than 10% of the entire projected area of each of said silver halide grains upon viewing said silver halide grains from a direction perpendicular to the major faces, the square containing one corner of each of said silver halide grains, and (iv) a dislocation line, there occurring only one edge intersection of said dislocation line or an extension line of said dislocation line at or within 15% edge length from the nucleus-containing corner upon viewing the silver halide grains from a direction perpendicular to the major faces.

8. The silver halide photographic material claimed in claim 7, wherein said dissolution resistant electrically conductive material is a metal oxide.

9. A silver halide photographic material containing an ultraviolet absorbing agent, which comprises a support having provided thereon an emulsion layer containing a silver halide emulsion which comprises at least one dispersion medium and a plurality of silver halide grains, wherein at least 30% of the total grain projected area of said silver halide grains is accounted for by tabular grains having (i) a {100} face as a major face, (ii) a diameter/thickness aspect ratio of at least 1.5, (iii) a nucleus formed during nucleus formation, said nucleus being present within a square of not more than 10% of the entire projected area of each of said silver halide grains upon viewing said silver halide grains from a direction perpendicular to the major faces, the square containing one corner of each of said silver halide grains, and (iv) a dislocation line, there occurring only one edge intersection of said dislocation line or an extension line of said dislocation line at or within 15% edge length from the nucleus-containing corner upon viewing the silver halide grains from a direction perpendicular to the major faces.

10. A silver halide photographic material comprising a support having at least two silver halide emulsion layers provided on at least one side of a support, wherein a first emulsion layer and a second emulsion layer both selected from said at least two silver halide emulsion layers satisfy the following 1) and 2):

1) said first and second emulsion layers both contain a silver halide emulsion which comprises at least one dispersion medium and a plurality of silver halide grains, wherein at least 30% of the total grain projected area of said silver halide grains is accounted for by tabular grains having (i) a {100} face as a major face, (ii) a diameter/thickness aspect ratio of at least 1.5, (iii) a nucleus formed during nucleus formation, said nucleus being present within a square of not more than 10% of the entire projected area of each of said silver halide grains upon viewing said silver halide grains from a direction perpendicular to the major faces, the square containing one corner of each of said silver halide grains, and (iv) a dislocation line, there occurring only one edge intersection of said dislocation line or an extension line of said dislocation line at or within 15% edge length from the nucleus-containing corner upon viewing the silver halide grains from a direction perpendicular to the major faces; and

2) said second emulsion layer is farther from the support than said first emulsion layer, and said second emulsion layer has a higher sensitivity than said first emulsion layer.

11. A silver halide radiographic material used in combination with a fluorescent intensifying screen which emits a light having a peak at a wavelength of 400 nm or less by X-ray exposure, which comprises a support having provided thereon at least one emulsion layer, wherein a dissolution resistant electrically conductive material is contained in the emulsion layer side of the support, and wherein said at least one emulsion layer containing a silver halide emulsion comprises at least one dispersion medium and a plurality of silver halide grains, wherein at least 30% of the total grain projected area of said silver halide grains is accounted for by tabular grains having (i) a {100} face as a major face, (ii) a diameter/thickness aspect ratio of at least 1.5, (iii) a nucleus formed during nucleus formation, said nucleus being present within a square of not more than 10% of the entire projected area of each of said silver halide grains upon viewing said silver halide grains from a direction perpendicular to the major faces, the square containing one corner of each of said silver halide grains, and (iv) a dislocation line, there occurring only one edge intersection of said dislocation line or an extension line of said dislocation line at or within 15% edge length from the nucleus-containing corner upon viewing the silver halide grains from a direction perpendicular to the major faces.

12. The silver halide radiographic material claimed in claim 11, wherein said dissolution resistant electrically conductive material is a metal oxide.

13. A silver halide radiographic material containing an ultraviolet absorbing agent, which comprises a support having provided thereon an emulsion layer containing a silver halide emulsion which comprises at least one dispersion medium and a plurality of silver halide grains, wherein at least 30% of the total grain projected area of said silver halide grains is accounted for by tabular grains having (i) a {100} face as a major face, (ii) a diameter/thickness aspect ratio of at least 1.5, (iii) a nucleus formed during nucleus formation, said nucleus being present within a square of not more than 10% of the entire projected area of each of said silver halide grains upon viewing said silver halide grains from a direction perpendicular to the major faces, the square containing one corner of each of said silver halide grains, and (iv) a dislocation line, there occurring only one edge intersection of said dislocation line or an extension line of said dislocation line at or within 15% edge length from the nucleus-containing corner upon viewing the silver halide grains from a direction perpendicular to the major faces,

wherein said silver halide radiographic material is used in combination with a fluorescent intensifying screen which emits a light having a peak at a wavelength of 400 nm or less by X-ray exposure.

14. A silver halide radiographic material used in combination with a fluorescent intensifying screen which emits a light having a peak at a wavelength of 400 nm or less by X-ray exposure, which comprises a support having at least two silver halide emulsion layers provided on at least one side of a support, wherein a first emulsion layer and a second emulsion layer both selected from said at least two silver halide emulsion layers satisfy the following 1) and 2):

1) said first and second emulsion layers both contain a silver halide emulsion which comprises at least one dispersion medium and a plurality of silver halide grains, wherein at least 30% of the total grain projected area of said silver halide grains is accounted for by tabular grains having (i) a {100} face as a major face, (ii) a diameter/thickness aspect ratio of at least 1.5, (iii) a nucleus formed during nucleus formation, said nucleus being present within a square of not more than 10% of the entire projected area of each of said silver halide grains upon viewing said silver halide grains from a direction perpendicular to the major faces, the square containing one corner of each of said silver halide grains, and (iv) a dislocation line, there occurring only one edge intersection of said dislocation line or an extension line of said dislocation line at or within 15% edge length from the nucleus-containing corner upon viewing the silver halide grains from a direction perpendicular to the major faces; and

2) said second emulsion layer is farther from the support than said first emulsion layer, and said second emulsion layer has a higher sensitivity than said first emulsion layer.