Silicone latex solvent thickening

• US 5,665,804 A
• Filed: 02/05/1996
• Issued: 09/09/1997
• Est. Priority Date: 02/05/1996
• Status: Expired due to Fees

• Current Assignee: Dow, Inc.
• Original Assignee: Dow, Inc.
• Inventors: Joffre, Eric Jude, Madore, Linda Moy, Hill, Michael Philip Louis
• Primary Examiner(s): Dean, Karen A.
• Application Number:
  US08/596,853
• Time in Patent Office: 582 Days
• Field of Search: 524/588, 524/837, 524/457, 524/863, 524/268, 524/731, 424/59, 424/60, 424/63, 424/78.03, 424/407, 424/486, 424/401
• US Class Current: 524/268
• CPC Class Codes: A61K 8/585 Organosilicon compounds
• CPC Class Codes: A61K 8/89 Polysiloxanes
• CPC Class Codes: A61K 8/891 saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• CPC Class Codes: A61K 8/895 containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
• CPC Class Codes: A61Q 13/00 Formulations or additives for perfume preparations essential oils or perfumes per se C11B9/00
• CPC Class Codes: A61Q 15/00 Anti-perspirants or body deodorants deodorisation of air A61L9/00
• CPC Class Codes: A61Q 19/00 Preparations for care of the skin
• CPC Class Codes: A61Q 5/12 Preparations containing hair conditioners
• CPC Class Codes: B01J 19/06 Solidifying liquids making microcapsules B01J13/02
• CPC Class Codes: C08J 2383/04 Polysiloxanes
• CPC Class Codes: C08J 3/09 in organic liquids
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: C09D 7/44 Combinations of two or more thickening agents

Abstract

The viscosity of a solvent is modified by thickening the solvent with a silicone latex. A silicone latex having a plurality of crosslinked polysiloxane particles is first prepared by mixing the siloxane polymer, a surfactant, and water; emulsifying the mixture to a gel phase; diluting the emulsion with water; adding a cure package (i.e., a catalyst, a crosslinker, or both, or a self catalytic crosslinker); and then without removing the water from the latex and after the particles of siloxane polymer in the latex have been cured, mixing the latex and solvent to thicken the solvent, forming viscous liquids, gels, and pastes. These latex thickened solvent compositions have beneficial properties such as clarity, shelf stability, and ease of preparation; and therefore have wide areas of application, especially as additives in antiperspirants, deodorants, and other personal care applications.

Claims

1. A method of modifying the viscosity of a solvent, the method comprising (I) adding a silicone latex containing water and a plurality of cured crosslinked polysiloxane particles to a solvent after the particles have been cured and without removing the water from the cured particles in the latex;

and (II) mixing the latex containing the water and the cured particles and the solvent together to thicken the solvent;

the latex being prepared by a method comprising;

(A) mixing (i) 100 weight parts of a siloxane polymer having a viscosity of greater than 5,000 mPa.s but less than 500,000 mPa.s at 25°

C., (ii) 0.5-10 weight parts of a surfactant, and (iii) 0.5-25 weight parts of water, (B) emulsifying the mixture into a gel phase having a siloxane polymer content of at least 80% by weight;

(C) diluting the emulsion with further water to a siloxane polymer content of at least 75% by weight, (D) adding 0.00001-20 weight parts catalyst either before or after the emulsification, or before or after the dilution;

(E) adding 0.1-20 weight parts crosslinker either before or after the emulsification, or before or after the dilution;

or in place of adding (D) and (E), adding 1-5 weight parts self catalytic crosslinker either before or after the emulsification, or before or after the dilution.

2. A method according to claim 1 in which the latex has a solids content of siloxane polymer of at least 90 percent by weight.

3. A method according to claim 1 in which the siloxane polymer has the formula X_3-n R_n --YO--(R¹₂ SiO)_z --Y--R_n X_3-n where n is 0, 1, 2 or 3;

z is an integer from 500-5,000;

X is hydrogen, a vinyl group, a hydroxyl group, a condensable or hydrolyzable group;

Y is a silicon atom, the group .tbd.Si--(CH₂)_m --SiR¹₂ --, or the group .tbd.Si--(CH₂)_m --SiR¹₂ OSiR¹₂ (CH₂)m--SiR¹₂ --, where m is 1-8;

R is selected from the group consisting of aliphatic alkyl, aminoalkyl, polyaminoalkyl, epoxyalkyl, alkenyl, and an aromatic group; and

R¹ is selected from the group consisting of X, aliphatic alkyl, alkenyl, and an aromatic group.

4. A method according to claim 3 in which the siloxane polymer has at least two vinyl groups per molecule bonded to a silicon atom, the crosslinker having an average of at least two silicon-bonded hydrogen atoms and being a silicon hydride crosslinker present in an amount sufficient to provide at least one hydrogen atom for each vinyl group in the siloxane polymer, and the catalyst is a noble metal catalyst.

5. A method according to claim 1 in which the self catalyzing crosslinker has at least one catalytic leaving group selected from the group consisting of acetoxy, amide, acetamide, aminoxy, and oxime.

6. A method according to claim 5 in which the self catalyzing crosslinker is a compound of the formula ##STR8## where R is the same or a different alkyl group of 1-8 carbon atoms;

a is zero or a positive integer, and b is greater than two.

7. A method according to claim 1 in which the surfactant is selected from the group consisting of nonionic surfactants, cationic surfactants, anionic surfactants, amphoteric surfactants, and mixtures thereof.

8. A method according to claim 1 in which the solvent is selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons, alcohols, aldehydes, ketones, amines, esters, ethers, glycols, glycol ethers, alkyl halides, aromatic halides, petroleum hydrocarbons, lubricating oils, fatty oils, organic polysiloxanes, functional polysiloxanes, volatile methyl siloxanes, and mixtures thereof.

9. A latex thickened solvent composition prepared according to the method described in claim 1.

10. A latex thickened solvent composition according to claim 9 containing 5-40 percent by weight of the silicone latex and 60-95 percent by weight of the solvent.

11. A personal care product containing the latex thickened solvent composition of claim 9 selected from the group consisting of antiperspirants, deodorants, skin creams, skin care lotions, moisturizers, acne removers, wrinkle removers, facial cleansers, bath oils, perfumes, colognes, sachets, sunscreens, pre-shave lotions, after-shave lotions, shaving soaps, shaving lathers, hair shampoos, hair conditioners, hair sprays, mousses, permanents, depilatories, cuticle coats, make-ups, color cosmetics, foundations, blushes, lipsticks, eyeliners, mascaras, oil removers, cosmetic removers, delivery systems for oil and water soluble substances, and powders;

including products in the form of sticks, gels, lotions, aerosols, and roll-ons.

12. A method of treating hair or skin comprising applying to the hair or skin a composition containing the latex thickened solvent composition of claim 9.

13. A product containing the latex thickened solvent composition of claim 9 and a material selected from the group consisting of crosslinked silicone rubber particles, pharmaceuticals, biocides, herbicides, pesticides, water, and water-soluble substances.

14. A method of modifying rheological, physical, or energy absorbing properties, of silicone or organic phases selected from the group consisting of sealants, paints, coatings, greases, adhesives, antifoams, and potting compounds, comprising incorporating therein the latex thickened solvent composition of claim 9 containing crosslinked silicone rubber particles.

15. A method of filling or insulating an electrical cable comprising incorporating therein the latex thickened solvent composition of claim 9.

16. A method of stabilizing in-ground soil or water barriers comprising incorporating into soil the latex thickened solvent composition of claim 9.