Time-temperature integrating indicator device

• US 5,667,303 A
• Filed: 03/10/1995
• Issued: 09/16/1997
• Est. Priority Date: 03/10/1995
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Company
• Inventors: Labuza, Theodore P., Arens, Robert P., Yarusso, David J., Birkholz, Russell D., Larson, Curtis L., Johnson, Dee Lynn
• Primary Examiner(s): Bennett, G. Bradley
• Application Number:
  US08/402,133
• Time in Patent Office: 921 Days
• Field of Search: 374/100, 374/102, 374/106, 374/159, 374/160, 374/161, 374/162, 426/88, 116/217, 116/218, 116/219
• US Class Current: 374/102
• CPC Class Codes: G01K 3/04 in respect of time

Abstract

A selectively activated time-temperature integrating device for providing a visually observable indication of cumulative thermal exposure, in which a viscoelastic material migrates into a diffusely light-reflective porous matrix at a rate which varies with temperature to progressively change the light transmissivity of the porous matrix and thereby provide the visually observable indication. The viscoelastic material can comprise a pressure sensitive adhesive. The visually observable indication can comprise latent indicia which initially are not visible and become visible, obscurable indicia which initially are visible and become obscured, or a combination of both. Various actuating means for selectively switching the indicator from an unactivated state to an activated state are described. Also disclosed are a method for providing a visually observable indication of cumulative thermal exposure and a method for providing a time and temperature integrating device for providing a visually observable indication of cumulative thermal exposure of an object.

Claims

1. A time and temperature integrating device for providing a visually observable indication of cumulative thermal exposure, said device comprising:

a) a first substrate comprising a first side and a second side, said second side including a diffusely light-reflective porous matrix, wherein said porous matrix includes an exposed surface;

b) a first backing comprising a first surface and a second surface, wherein said first surface of said backing includes a viscoelastic material disposed thereon, and wherein said viscoelastic material includes an exposed surface; and

c) actuating means for selectively switching said device from an unactivated state to an activated state;

wherein when said device is in said unactivated state, said viscoelastic material is substantially out of contact with said porous matrix;

wherein when said device is in said activated state, said actuating means maintains said exposed surface of said viscoelastic material and said exposed surface of said porous matrix in substantial contact with one another such that said viscoelastic material progressively migrates into said porous matrix at a rate which increases with increasing temperature; and

wherein migration of said viscoelastic material into said porous matrix progressively increases the light transmissivity of said porous matrix to provide said visually observable indication of cumulative thermal exposure.

2. The device of claim 1, wherein said viscoelastic material comprises a pressure sensitive adhesive.

3. The device of claim 2, wherein said pressure sensitive adhesive bonds itself to said porous matrix in response to engaging said actuating means.

4. The device of claim 1, wherein said visually observable indication comprises latent indicia, wherein said latent indicia is not visually observable when said indicator is in its unactivated state, and wherein migration of said viscoelastic material into said porous matrix sufficiently increases the light transmissivity of said porous matrix such that said latent indicia becomes visually observable.

5. The device of claim 4, wherein said latent indicia comprises a bar code which is not readable by a bar code reader when said indicator is in its unactivated state, and wherein migration of said viscoelastic material into said porous matrix renders said porous matrix sufficiently light transmissive to allow a bar code reader to read said bar code.

6. The device of claim 4, wherein said latent indicia is disposed on at least one of said first side of said substrate, said second side of said substrate, said exposed surface of said porous matrix, and said exposed surface of said viscoelastic material.

7. The device of claim 6, wherein said latent image comprises a repellent disposed on a first portion of at least one of said exposed surface of said porous matrix and said exposed surface of said viscoelastic material to attenuate migration of said viscoelastic material into said porous matrix at said first portion, and wherein migration of said viscoelastic material at a second portion of said porous matrix sufficiently increases the light transmissivity of said second portion of said porous matrix such that said substrate becomes visible through said porous matrix at said second portion.

8. The device of claim 4, further comprising a second substrate disposed on said first side of said first substrate, said second substrate including said latent indicia, wherein said first substrate is light transmissive.

9. The device of claim 4, further comprising a comparison image, wherein said visually observable indication comprises said latent indicia having a density substantially the same as or greater than the density of said comparison image when said viscoelastic material migrates into said porous matrix.

10. The device of claim 4, further comprising a plurality of comparison images of increasing density, wherein said visually observable indication comprises said latent indicia having a density substantially the same as or greater than the density of one of said plurality of comparison images when said viscous material migrates into said porous matrix.

11. The device of claim 4, wherein at least one of said porous matrix and said viscoelastic material is applied in a pattern, and wherein said pattern comprises said latent indicia.

12. The device of claim 1, wherein said visually observable indication comprises obscurable indicia, wherein said second surface of said substrate comprises a color and optical density sufficiently similar to the color and optical density of said obscurable indicia such that migration of said viscoelastic material into said porous matrix sufficiently increases the light transmissivity of said porous matrix such that said second surface of said substrate becomes progressively visible through said porous matrix and thereby progressively reduces the contrast between said obscurable indicia and said substrate to thereby obscure said obscurable indicia.

13. The device of claim 12, wherein said obscurable indicia comprises a bar code, wherein said bar code is readable by a bar code reader when said porous matrix is opaque, and wherein migration of said viscoelastic material into said porous matrix sufficiently increases the light transmissivity of said porous matrix such that said bar code becomes sufficiently obscured so as not to be readable by a bar code reader.

14. The device of claim 12, wherein said obscurable indicia is disposed on at least one of said exposed surface of said porous matrix, said exposed surface of said viscoelastic material, said first surface of said backing, and said second surface of said backing.

15. The device of claim 14, wherein said obscurable indicia comprises a permanently transparentized portion of said porous matrix.

16. The device of claim 12, further comprising a second backing disposed over said first backing, and wherein said obscurable indicia is disposed on said second backing.

17. The device of claim 4, wherein said visually observable indication further comprises obscurable indicia, wherein said second surface of said substrate comprises a color and optical density sufficiently similar to the color and optical density of said obscurable indicia such that migration of said viscoelastic material into said porous matrix sufficiently increases the light transmissivity of said porous matrix such that said second surface of said substrate becomes progressively visible through said porous matrix and thereby progressively reduces the contrast between said obscurable indicia and said substrate to thereby obscure said obscurable indicia.

18. The device of claim 17, wherein said latent indicia comprises a first bar code which is not readable by a bar code reader when said indicator is in its unactivated state, wherein said obscurable indicia comprises a second bar code readable by a bar code reader;

and

wherein migration of said viscoelastic material into said porous matrix sufficiently increases the light transmissivity of said porous matrix so as to;

(a) allow a bar code reader to read said first bar code, and (b) sufficiently obscure said second bar code so as not to be readable by a bar code reader.

19. The device of claim 4, wherein the optical density of said latent indicia increases by at least 0.2 as the light transmissivity of said porous matrix increases.

20. The device of claim 12 wherein the difference between the optical density of said obscurable indicia and the optical density of said substrate decreases by at least 0.2 as the light transmissivity of said porous matrix increases.

21. The device of claim 1, wherein said porous matrix comprises a plurality of particles held to said substrate in an open pore manner by a binder.

22. The device of claim 21, wherein the index of refraction of said particles is sufficiently close to the index of refraction of said viscoelastic material such that said porous matrix is rendered sufficiently light transmissive to provide said visually observable indication when said viscoelastic material migrates into said porous matrix.

23. The device of claim 22, wherein the index of refraction of said viscoelastic material is from 1.3 to 2.2 and the index of refraction of said particles is from 1.3 to 2.2.

24. The device of claim 22, wherein said index of refraction of said viscoelastic material is within 0.4 of the index of refraction of said particles.

25. The device of claim 1, wherein said viscoelastic material has an effective activation energy selected such that said device indicates a predetermined allowable cumulative thermal exposure.

26. The device of claim 25, wherein said effective activation energy is selected such that said device indicates a predetermined allowable cumulative thermal exposure for an object whose cumulative thermal exposure is to be indicated by said device.

27. The device of claim 26 in combination with an object whose cumulative thermal exposure is to be indicated by said device, wherein said device is thermally coupled with said object.

28. The device of claim 25, wherein said viscoelastic material has an effective activation energy of from 5 to 70 kilocalories per mole.

29. The device of claim 25, wherein said viscoelastic material has an effective activation energy of from 8 to 40 kilocalories per mole.

30. The device of claim 25, wherein said viscoelastic material has an effective activation energy of from 12 to 30 kilocalories per mole.

31. The device of claim 25, wherein said viscoelastic material has an effective activation energy of at least 30 kilocalories per mole.

32. The device of claim 1, wherein said porous matrix comprises a microporous polymeric film.

33. The device of claim 1, wherein said viscoelastic material comprises a viscoelastic liquid state at 50°

C.

34. The device of claim 33, wherein said viscoelastic material comprises a viscoelastic liquid state at 20°

C.

35. The device of claim 34, wherein said viscoelastic material comprises a viscoelastic liquid state at 0°

C.

36. The device of claim 35, wherein said viscoelastic material comprises a viscoelastic liquid state at -45°

C.

37. The device of claim 27, wherein said viscoelastic material comprises a viscoelastic liquid state throughout the temperature range at which appreciable change in the object to be monitored occurs.

38. The device of claim 1, wherein said viscoelastic material comprises a viscoelastic liquid state at the time said actuating means switches said indicator to said activated state.

39. The device of claim 1, further comprising a plurality of said viscoelastic materials, wherein each of said viscoelastic materials indicates a respective predetermined allowable cumulative thermal exposure.

40. The device of claim 1, further comprising a plurality of said porous matrices, wherein each of said porous matrices indicates a respective predetermined allowable cumulative thermal exposure.

41. The device of claim 2, wherein said pressure sensitive adhesive is selected from the group consisting essentially of polyisoprene based adhesive, atactic polypropylene based adhesive, polybutadiene based adhesive, polyisobutylene based adhesive, silicone based adhesive, ethylene vinyl acetate based adhesive, and acrylate based adhesive, and mixtures thereof.

42. The device of claim 2, wherein said pressure sensitive adhesive is selected from the group consisting essentially of isooctyl acrylate based adhesive, isooctyl acrylate/acrylic acid based adhesive, isooctyl acrylate methacrylate based adhesive, ethyl acrylate/methyl acrylate based adhesive, and isooctyl acrylate/isobornyl acrylate based adhesive, and mixtures thereof.

43. The device of claim 2, wherein said pressure sensitive adhesive comprises an isooctyl acrylate/acrylic acid based adhesive having an isooctyl acrylate/acrylic acid weight ratio of from about 80/20 to 98/2.

44. The device of claim 42, wherein said isooctyl acrylate/acrylic acid based adhesive has an isooctyl acrylate/acrylic acid weight ratio of from about 90/10 to 94/6.

45. The device of claim 2, wherein said pressure sensitive adhesive further comprises a tackifier in a tackifier to adhesive base weight ratio of up to 2:

1.

46. The device of claim 45, wherein said tackifier comprises a hydrogenated rosin ester.

47. The device of claim 2, wherein said pressure sensitive adhesive further comprises a plasticizer in a plasticizer to adhesive base weight ratio of up to 2:

1.

48. The device of claim 47, wherein said plasticizer is selected from the group consisting essentially of mineral oil, hydrocarbon oil, alkyl phthalates, and allyl phthalates.

49. The device of claim 21, wherein said particles are selected from the group consisting essentially of aluminum oxide, hydrated aluminum oxide, glass, silica, silane-treated silica, silicon dioxide, rice starch, titanium dioxide, zinc oxide, calcium fluoride, and calcium carbonate.

50. The device of claim 21, wherein said particles have an average diameter of from 0.01 to 750 micrometers.

51. The device of claim 50, wherein said particles have an average diameter of from 0.5 to 40 micrometers.

52. The device of claim 51, wherein said particles have an average diameter of about 8 micrometers.

53. The device of claim 21, wherein said binder is selected from the group consisting essentially of acrylic binder, epoxy binder, polyurethane binder, and thermoset alkyd binder.

54. The device of claim 21, wherein said porous matrix comprises a binder to particle volume ratio in the range of about 1:

20 to 2;

3.

55. The device of claim 54, wherein said porous matrix comprises a binder to particle volume ratio in the range of about 1:

5 to 1;

2.

56. The device of claim 1, wherein said viscoelastic material has a migration rate into said porous matrix which increases a predetermined amount with increasing temperature such that said device indicates a predetermined allowable cumulative thermal exposure.

57. The device of claim 1, wherein said actuating means comprises a spacer having a top surface, a bottom surface opposite said top surface, and an opening therethrough, wherein said first substrate is disposed on said bottom surface with said exposed surface of said porous matrix at least partially overlying said opening, said first backing is disposed on said top surface with exposed surface of said viscoelastic material at least partially overlying said opening and said porous matrix, wherein said spacer maintains said viscoelastic material substantially out of contact with said porous matrix when said indicator is in said unactivated state, and wherein said viscoelastic material and said porous matrix substantially contact one another through said opening when said indicator is in said activated state.

58. The device of claim 1, wherein said actuating means comprises a barrier film having a first portion at least partially overlying said exposed surface of said viscoelastic material and a second portion at least partially overlying said exposed surface of porous matrix for maintaining said viscoelastic material substantially out of contact with said porous matrix when said indicator is in said unactivated state, and wherein said barrier film may be removed from said indicator for allowing said viscous material and said porous matrix to contact one another when said indicator is in said activated state.

59. The indicator of claim 58 in combination with a container, wherein:

said container comprises a first member and a second member;

said first substrate is mounted on one of said first member and said second member; and

said barrier film is operatively attached to the other of said first member and said second member, such that upon separating said first and second members, said barrier film is removed from said indicator thereby switching said indicator to its activated state.

60. The device of claim 1, wherein said actuating means comprises a plurality of proximate portions and a plurality of remote portions formed in at least one of said first substrate and said first backing, wherein when said indicator is in said unactivated state, said exposed surface of said porous matrix and said exposed surface of said viscoelastic material contact one another at said proximate portions, and said remote portions maintain said viscoelastic material and said porous matrix substantially out of contact at said remote portions, and wherein said remote portions may be deformed to contact said viscoelastic material and said porous matrix with one another at said plurality of remote portions when said indicator is in said activated state.

61. The device of claim 1, wherein said actuating means comprises an actuating substrate having a first portion and a second portion, wherein said first substrate is disposed on said first portion with said exposed surface of said porous matrix opposite said actuating substrate, wherein said first backing is disposed on said second portion with said exposed surface of said viscoelastic material opposite said actuating substrate, wherein when said indicator is in said unactivated state, said activating substrate maintains said viscoelastic material substantially out of contact with said porous matrix, and wherein said indicator may be switched to said activated state by folding said activating substrate in such a manner and degree as to bring said viscoelastic material and said porous matrix into substantial contact with one another.

62. The device of claim 1, wherein said actuating means comprises a plurality of spacing bodies disposed between said exposed surface of said porous matrix and said exposed surface of said viscoelastic material to maintain said viscoelastic material out of contact with said porous matrix when said indicator is in said unactivated state, and wherein when said indicator is in said activated state, said viscoelastic material and said porous matrix are maintained in substantial contact with one another between said spacing bodies.

63. The device of claim 1, wherein said actuating means comprises a transparent cover overlying said first backing and said first substrate, said cover including a shallowly curved, exteriorly convex dome having an inner surface, extending in an unactivated position of stability away from said first backing and said first substrate when said indicator is in said unactivated state;

wherein said cover has a profile selected to permit a snap movement of said cover from said unactivated position to an activated position upon the application of force to said cover, thereby forcing said cover to curve towards said first backing and said first substrate and force said viscoelastic material into pressure contact with said porous matrix to switch said indicator to said activated state.

64. The device of claim 1, further comprising mounting means for mounting said indicator to an object whose cumulative thermal exposure is to be indicated.

65. The device of claim 64, wherein said mounting means comprises a pressure sensitive adhesive.

66. A time and temperature integrating device for providing a visually observable indication of cumulative thermal exposure, said device comprising:

a) a first substrate comprising a first side and a second side, said second side including a diffusely light-reflective porous matrix, wherein said porous matrix includes an exposed surface;

b) a first backing comprising a first surface and a second surface, wherein said first surface of said backing includes a viscoelastic material disposed thereon, wherein said viscoelastic material includes an exposed surface; and

c) actuating means for selectively switching said device from an unactivated state to an activated state;

wherein when said device is in said unactivated state, said viscoelastic material is substantially out of contact with said porous matrix;

wherein when said device is in said activated state, said actuating means maintains said exposed surface of said viscoelastic material and said exposed surface of said porous matrix in substantial contact with one another such that said viscoelastic material progressively migrates into said porous matrix at a rate which increases with increasing temperature;

wherein migration of said viscoelastic material into said porous matrix progressively decreases the light transmissivity of said porous matrix to provide said visually observable indication of cumulative thermal exposure.

67. A time and temperature integrating device for providing a visually observable indication of cumulative thermal exposure, said device comprising:

a) a first substrate comprising a first side and a second side, said second side including a diffusely light-reflective porous matrix, wherein said porous matrix includes an exposed surface;

b) a first backing comprising a first surface and a second surface, wherein said first surface of said backing includes a pressure sensitive adhesive disposed thereon, said pressure sensitive adhesive including at least one of a tackifier and a plasticizer as a component thereof, and wherein said pressure sensitive adhesive includes an exposed surface; and

c) actuating means for selectively switching said device from an unactivated state to an activated state;

wherein when said device is in said unactivated state, said pressure sensitive adhesive is substantially out of contact with said porous matrix;

wherein when said device is in said activated state, said actuating means maintains said exposed surface of said pressure sensitive adhesive and said exposed surface of said porous matrix in substantial contact with one another such that all of the components of said pressure sensitive adhesive together progressively migrate into said porous matrix at a rate which increases with increasing temperature;

wherein migration of said pressure sensitive adhesive into said porous matrix progressively increases the light transmissivity of said porous matrix to provide said visually observable indication of cumulative thermal exposure.

68. A time and temperature integrating device for providing a visually observable indication of cumulative thermal exposure, said device comprising:

a) a diffusely light-reflective porous matrix having an exposed surface;

b) a first backing comprising a first surface and a second surface, wherein said first surface of said backing includes a viscoelastic material disposed thereon, and wherein said viscoelastic material includes an exposed surface; and

c) actuating means for selectively switching said device from an unactivated state to an activated state;

wherein when said device is in said unactivated state, said viscoelastic material is substantially out of contact with said porous matrix;

wherein when said device is in said activated state, said actuating means maintains said exposed surface of said viscoelastic material and said exposed surface of said porous matrix in substantial contact with one another such that said viscoelastic material progressively migrates into said porous matrix at a rate which increases with increasing temperature; and

wherein migration of said viscoelastic material into said porous matrix progressively increases the light transmissivity of said porous matrix to provide said visually observable indication of cumulative thermal exposure.

69. A method for providing a time and temperature integrating device for providing a visually observable indication of cumulative thermal exposure of an object, comprising the steps of:

a) mounting a first substrate onto the object, said substrate comprising a first side and a second side, said second side including a diffusely light-reflective porous matrix; and

b) contacting a first surface of a first backing against said porous matrix, wherein said first surface of said backing includes a viscoelastic material disposed thereon;

wherein said viscoelastic material progressively migrates into said porous matrix at a rate which increases with increasing temperature; and

wherein migration of said viscoelastic material into said porous matrix progressively changes the light transmissivity of said porous matrix to provide said visually observable indication.

70. The method of claim 69, wherein step a) precedes step b).

71. The method of claim 69, wherein step b) precedes step a).

72. The method of claim 69, wherein step a) is performed simultaneously with step b).

73. A method for providing a visually observable indication of cumulative thermal exposure, comprising the steps of:

a) applying a viscoelastic liquid onto an exposed surface of a diffusely light-reflective porous matrix;

wherein said viscoelastic liquid progressively migrates into said porous matrix at a rate which increases with increasing temperature;

b) exposing said viscoelastic liquid to a time and temperature profile; and

c) migrating said viscoelastic liquid into said porous matrix in response to said time and temperature profile to thereby change the light transmissivity of said porous matrix to provide a visually observable indication of cumulative thermal exposure.

74. A method for providing a visually observable indication of cumulative thermal exposure of an object, comprising the steps of:

a) mounting a first substrate onto the object, said substrate comprising a first side and a second side, said second side including a diffusely light-reflective porous matrix;

b) contacting a first surface of a first backing against said porous matrix, wherein said first surface of said backing includes a viscoelastic material disposed thereon, wherein said viscoelastic material progressively migrates into said porous matrix at a rate which increases with increasing temperature;

c) exposing said object to a time and temperature profile; and

d) migrating said viscoelastic material into said porous matrix in response to said time and temperature profile to thereby change the light transmissivity of said porous matrix to provide a visually observable indication of cumulative thermal exposure.

75. The method of claim 74, wherein step a) precedes step b).

76. The method of claim 74, wherein step b) precedes step a).

77. The method of claim 74, wherein step a) is performed simultaneously with step b).

78. A method for providing a time and temperature integrating device for providing a visually observable indication of cumulative thermal exposure, comprising the steps of:

a) forming an opening in a generally planar spacer, said spacer comprising a top side and a bottom side;

b) applying an adhesive to at least said bottom side of the spacer;

c) adhering a first substrate onto said bottom side of the spacer to at least partially overlay said opening, said first substrate comprising a diffusely light-reflective porous matrix overlaying said opening; and

d) applying a first surface of a first backing to said spacer to at least partially overlay said opening and said porous matrix, wherein said first surface of said backing includes a viscoelastic material disposed thereon overlaying said opening;

wherein said viscoelastic material progressively migrates into said porous matrix at a rate which increases with increasing temperature to thereby integrate said temperature over time; and

wherein migration of said viscoelastic material into said porous matrix progressively changes the light transmissivity of said porous matrix to provide said visually observable indication.