Electrochromic thin film state-of-charge detector for on-the-cell application

• US 5,667,538 A
• Filed: 06/08/1995
• Issued: 09/16/1997
• Est. Priority Date: 01/31/1991
• Status: Expired due to Term

• Current Assignee: Eveready Battery Company Incorporated (Energizer Holdings, Inc.)
• Original Assignee: Eveready Battery Company Incorporated (Energizer Holdings, Inc.)
• Inventors: Bailey, John C.
• Primary Examiner(s): KALAFUT, STEPHEN J
• Application Number:
  US08/482,467
• Time in Patent Office: 831 Days
• Field of Search: 429/91-93, 359/271, 29/623.4, 29/623.5
• US Class Current: 29/623.5
• CPC Class Codes: G01R 13/403 using passive display devices, e.g. liquid crystal display or Kerr effect display devices
• CPC Class Codes: G02F 1/1525 characterised by a particular ion transporting layer, e.g. electrolyte
• CPC Class Codes: G02F 1/153 Constructional details
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 10/488 Cells or batteries combined with indicating means for external visualization of the condition, e.g. by change of colour or of light density
• CPC Class Codes: H01M 6/505 Cells combined with indicating means for external visualization of the condition, e.g. by change of colour or of light intensity
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10T 29/49115 including coating or impregnating

Abstract

A tester for use in determining the voltage and state-of-charge of a battery. The tester can be permanently mounted on the battery and employs an electrochromic cell which changes visual appearance, for example, color or intensity of color when electrically connected across the terminals of a battery. The electrochromic cell undergoes an oxidation/reduction reaction on direct application of the DC potential of the battery. The color of the electrochromic cell can be compared with a color comparison chart to determine the condition of the battery.

The tester can be permanently electrically connected to the battery or, preferably, can be connected momentarily to determine the state of the battery.

Claims

1. A method of forming an electrochromic thin film, battery state-of-charge detector, said method comprising:

providing a substrate suitable for affixment to a battery;

depositing a first electrically conductive pattern on said substrate;

depositing an electrochromic layer and an electrolyte layer on said substrate;

depositing a second electrically conductive pattern on at least one of said electrochromic layer and said electrolyte layer, wherein at least one of said electrically conductive materials is a material through which said electrochromic material can be viewed.

2. The method of claim 1 whereby said first electrically conductive pattern is deposited on said substrate by printing.

3. The method of claim 1 whereby said electrochromic layer is deposited on said substrate by printing.

4. The method of claim 1 whereby said electrolyte layer is deposited on said substrate by printing.

5. The method of claim 1 whereby said second electrically conductive pattern is deposited on at least one of said electrochromic layer and said electrolyte layer by printing.

6. The method of claim 1 wherein said electrochromic material is a member selected from the group consisting of WO₃, MoO₃, TiO₂, SnO₂, Cr₂ O₃, NiO₂, Mn₂ O₃, MnO₂, and Prussian blue.

7. The method of claim 1 wherein said electrochromic material is a member selected from the group consisting of phenolphthalein, methyl violet, ethyl red, methylene blue, naphthol blue black, N,N-dimethylindoaniline, and N,N'"'"'-diphenylbenzidine.

8. The method of claim 1 wherein at least a portion of said substrate is transparent.

9. The method of claim 1 wherein one of said first and second electrically conductive patterns is formed from a transparent metal oxide.

10. The method of claim 1 further comprising:

connecting a load resistor in parallel to said detector.

19. The method of claim 1 wherein said substrate is provided in the form of a web, said web is printed with repeat graphics to form many labels, said first electrically conductive pattern for each label is deposited on said substrate by printing, said electrochromic layer for each label is deposited on said substrate by printing, said electrolyte layer for each layer is deposited on said substrate by printing, said second electrically conductive layer for each label is deposited on said substrate by printing, and said web is subsequently separated into individual labels with detectors.

11. A method of forming labeled batteries, each comprising an integral battery and electrochromic thin film state-of-charge detector, said method comprising:

providing a plurality of batteries, each battery having a first terminal, a second terminal, and an exterior surface;

providing a web of label substrate;

applying repeated label graphics on said web of label substrate;

applying repeated label testers at each label graphics, comprising the steps of;

a) depositing a thin layer of a first electrically conductive material on said web of label substrate;

b) depositing an electrochromic material and an ionically conductive electrolyte on said first electrically conductive material;

c) applying to said electrochromic material and said electrolyte a thin layer of a second electrically conductive material, wherein at least one of said electrically conductive materials is a material through which said electrochromic material can be viewed, to thereby form said electrochromic thin film state-of-charge detector;

d) providing a first electrical conductor for connecting said first electrically conductive material to said first terminal of said battery, and providing a second electrical conductor for connecting said second electrically conductive material to said second terminal of said battery;

separating said web into individual labels and detectors; and

affixing each said electrochromic thin film state-of-charge detector and label to said exterior surface of one of said batteries to thereby form each integral battery and electrochromic thin film state-of-charge detector.

12. The method of claim 11 further comprising:

applying a color scale on at least one of said exterior surface of said battery and said label substrate, whereby said scale can be viewed and compared to said detector to determine the state-of-charge of said battery.

13. The method of claim 11 further comprising:

printing graphics on said label substrate.

14. The method of claim 11 whereby said depositing of said thin layer of said first electrically conductive material is performed by printing conductive ink or paint on said label substrate.

15. The method of claim 11 whereby said depositing of said electrochromic material is performed by printing said electrochromic material.

16. The method of claim 11 wherein prior to affixing said electrochromic thin film state-of-charge detector to said battery, said web of substrate material containing said plurality of detectors is run through a suitable punch or die cutting operation to separate said plurality of detectors.

17. A method of forming an electrochemichromic thin film state-of-charge detector for on-the-cell application, said method comprising:

providing a label substrate;

depositing a layer of a first electrically conductive material on said substrate;

depositing a layer of an electrochemichromic material on said first electrically conductive material; and

applying a layer of a second electrically conductive material on said electrochemichromic material, whereby said layers are in a stacked arrangement.

18. A method for preparing a label having a battery condition taster for a battery, said battery including a first and a second external terminal, comprising the following steps:

providing a label substrate as a film;

forming on said substrate a layer of a first electronically conductive material;

applying so as to contact said first electronically conductive material an electrochromic material and an ionically conductive electrolyte;

applying so as to contact said electrochromic material and said electrolyte a layer of a second electronically conductive material, to thereby form said battery condition tester; and

providing on said substrate a first electrically conductive means for connecting one of said first and second electronically conductive materials of said battery condition tester to one external terminal of said battery and a second electrically conductive means for connecting the other electronically conductive material to the other external terminal of said battery, and mounting said label substrate to said battery in a manner to be left there in place and to connect at least one of said first and second electrically conductive means to one of said battery terminals and whereby said tester is disposed on said battery;

said substrate being provided in the form of a web, said web being printed with repeat graphics to form many labels, and a tester for each label, and including the step of separating individual labels from said web and then practicing said step of mounting an individual label to a battery.