Multilayered conductive film, and transparent electrode substrate and liquid crystal device using the same

• US 5,667,853 A
• Filed: 03/21/1996
• Issued: 09/16/1997
• Est. Priority Date: 03/22/1995
• Status: Expired due to Term

• Current Assignee: Toppan Printing Co., Ltd. (TOPPAN Holdings, Inc.)
• Original Assignee: Toppan Printing Co., Ltd. (TOPPAN Holdings, Inc.)
• Inventors: Koga, Osamu, Kimura, Yukihiro, Imayoshi, Koji, Horachi, Katsunori, Fukuyoshi, Kenzo
• Primary Examiner(s): THOMAS, ALEXANDER S
• Application Number:
  US08/619,240
• Time in Patent Office: 544 Days
• Field of Search: 428/1, 428/472, 428/702, 349/147, 349/139
• US Class Current: 428/1.62
• CPC Class Codes: C09K 2323/061 Inorganic, e.g. ceramic, metallic or glass
• CPC Class Codes: C23C 14/086 of zinc, germanium, cadmium, indium, tin, thallium or bismuth
• CPC Class Codes: G02F 1/13439 characterised by their electrical, optical, physical properties; materials therefor; method of making
• CPC Class Codes: G02F 2203/02 reflective

Abstract

A multilayered conductive film has a silver-based layer formed of a silver-based metallic material. A first transparent oxide layer is provided on one surface of the silver-based layer, and a second transparent oxide layer is provided on the other surface of the silver-based layer. The first and second transparent oxide layers are independently formed of a compound oxide material of indium oxide with at least one secondary metal oxide whose metallic element has substantially no solid solubility in silver.

Claims

1. A multilayered conductive film comprising:

a silver-based layer formed of a silver-based metallic material and having first and second surfaces;

a first transparent oxide layer provided on said first surface of said silver-based layer; and

a second transparent oxide layer provided on said second surface of said silver-based layer;

said first and second transparent oxide layers being independently formed of a compound oxide material of indium oxide with at least one secondary metal oxide whose metallic element has substantially no solid solubility in silver.

2. The multilayered film according to claim 1, wherein said metallic element having substantially no solid solubility in silver is selected from the group consisting of titanium, zirconium, tantalum, niobium, hafnium, cerium, bismuth, germanium, silicon, chromium, and a combination of two or more of these element.

3. The multilayered film according to claim 1, wherein said metallic element having substantially no solid solubility in silver occupies 5 to 50 atomic percent of a total atomic amount with said indium.

4. The multilayered film according to claim 1, wherein said silver-based metallic material comprises an alloy of silver with a different element which prevents silver migration.

5. The multilayered film according to claim 4, wherein said different element is selected from the group consisting of aluminum, copper, nickel, cadmium, gold, zinc, magnesium, and a combination of two or more of these elements.

6. The multilayered film according to claim 4, wherein said different element is selected from the group consisting of tin, indium, titanium, cerium, silicon, and a combination of two or more of these elements.

7. The multilayered film according to claim 1, wherein said silver-based layer has a thickness of 2 to 20 nm.

8. A transparent electrode substrate comprising the multilayered conductive film of claim 7 provided over a transparent substrate.

9. The electrode substrate according to claim 8, wherein said silver-based metallic material contains 0.1 to 3 atomic percent of copper, gold or mixtures thereof.

10. The electrode substrate according to claim 8, wherein said first and second transparent oxide layers have a refractive index of 2.1 or more.

11. The electrode substrate according to claim 10, wherein said metallic element having substantially no solid solubility in silver is selected from the group consisting of cerium, titanium, zirconium, hafnium, tantalum, and a combination of two or more of these elements.

12. The electrode substrate according to claim 10, wherein said metallic element having substantially no solid solubility in silver comprises cerium or titanium.

13. The electrode substrate according to claim 8, wherein said multilayered conductive film has a small width portion having a minimum width of 50 nm or less.

14. A liquid crystal display device comprising an observer-side electrode substrate, a rear-side electrode substrate arranged opposite to said observer-side electrode substrate, and a liquid crystal material sealed between these electrode substrates, at least one of said electrode substrates being constituted by the transparent electrode substrate according to claim 8.

15. The multilayered film according to claim 1, wherein said silver-based layer has a thickness of 50 nm or more.

16. A liquid crystal display device comprising an observer-side electrode substrate provided with a transparent electrode, a rear-side electrode substrate provided with a light-reflecting electrode and arranged opposite to said observer-side electrode substrate, and a liquid crystal material sealed between these electrode substrates, said light-reflecting electrode being constituted by the multilayered conductive film of claim 15.