Removable adhesive sheet
First Claim
1. A removable adhesive sheet comprising a laminate of a release liner, an adhesive layer and a surface stock, wherein the adhesive layer is formed between the release liner and surface stock by applying an adhesive to the release liner or to the surface stock, followed by drying,said adhesive comprising (i) an aqueous emulsion of a copolymer obtained by emulsion polymerization and (ii) a polyglycidyl compound having two or more epoxy groups within the molecule thereof,said copolymer comprising, on the whole copolymer weight basis,(a) 80-99% by weight of a (meth)acrylic acid C8 -C12 alkyl ester,(b) 0.3-10% by weight of (meth)acrylonitrile,(c) 0.1-5% by weight of an α
- ,β
-unsaturated carboxylic acid and(d) 0-5% by weight of another monomer copolymerizable with the above-mentioned monomers (a), (b) and (c),said copolymer having a polystyrene-equivalent number average molecular weight of not less than 0.1×
104 but less than 5.0×
104, a polystyrene-equivalent weight average molecular weight (Mw)/ polystyrene-equivalent number average molecular weight (Mn) ratio (Mw/Mn) of 40-800, an average particle size of 100-500 nm and a glass transition temperature of not higher than -50°
C., andsaid polyglycidyl compound being used in an amount such that the epoxy groups amount to 0.5 to 2 equivalents relative to the carboxyl groups in said copolymer.
1 Assignment
0 Petitions
Accused Products
Abstract
Disclosed is a removable adhesive sheet comprising a release liner, an adhesive layer and a surface stock as laminated, wherein the adhesive layer being formed by applying an adhesive to the release liner or to the surface stock, followed by drying,
said adhesive comprising (i) an aqueous emulsion of a copolymer obtained by emulsion polymerization and (ii) a polyglycidyl compound having two or more epoxy groups within the molecule thereof,
said copolymer comprising (a) 80-99% by weight of a (meth)acrylic acid C8 -C12 alkyl ester, (b) 0.3-10% by weight of (meth)acrylonitrile, (c) 0.1-5% by weight of an α,β-unsaturated carboxylic acid and (d) 0-5% by weight of another copolymerizable monomer,
said copolymer having a Mn of not less than 0.1×104 but less than 5.0×104, ratio of (Mw/Mn) of 40-800, an average particle size of 100-500 nm and a Tg of not higher than -50° C., and
said polyglycidyl compound being used in an amount such that the epoxy groups amount to 0.5 to 2 equivalents relative to the carboxyl groups in said copolymer.
-
Citations
15 Claims
-
1. A removable adhesive sheet comprising a laminate of a release liner, an adhesive layer and a surface stock, wherein the adhesive layer is formed between the release liner and surface stock by applying an adhesive to the release liner or to the surface stock, followed by drying,
said adhesive comprising (i) an aqueous emulsion of a copolymer obtained by emulsion polymerization and (ii) a polyglycidyl compound having two or more epoxy groups within the molecule thereof, said copolymer comprising, on the whole copolymer weight basis, (a) 80-99% by weight of a (meth)acrylic acid C8 -C12 alkyl ester, (b) 0.3-10% by weight of (meth)acrylonitrile, (c) 0.1-5% by weight of an α - ,β
-unsaturated carboxylic acid and(d) 0-5% by weight of another monomer copolymerizable with the above-mentioned monomers (a), (b) and (c), said copolymer having a polystyrene-equivalent number average molecular weight of not less than 0.1×
104 but less than 5.0×
104, a polystyrene-equivalent weight average molecular weight (Mw)/ polystyrene-equivalent number average molecular weight (Mn) ratio (Mw/Mn) of 40-800, an average particle size of 100-500 nm and a glass transition temperature of not higher than -50°
C., andsaid polyglycidyl compound being used in an amount such that the epoxy groups amount to 0.5 to 2 equivalents relative to the carboxyl groups in said copolymer. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15)
- ,β
Specification