Process for producing a dispersed novolac resin and use in a binder system for thermal insulation

• US 5,670,571 A
• Filed: 11/03/1995
• Issued: 09/23/1997
• Est. Priority Date: 11/03/1995
• Status: Expired due to Fees

• Current Assignee: Georgia-Pacific Resins, Inc. (KOCH Industries Incorporated)
• Original Assignee: Georgia-Pacific Resins, Inc. (KOCH Industries Incorporated)
• Inventors: Gabrielson, Kurt D., Conner, Rodney R.
• Primary Examiner(s): Michl, Paul R.
• Assistant Examiner(s): Guarriello, John J.
• Application Number:
  US08/552,563
• Time in Patent Office: 690 Days
• Field of Search: 524/593, 524/594, 524/596, 524/604
• US Class Current: 524/604
• CPC Class Codes: C08J 2361/06 of aldehydes with phenols
• CPC Class Codes: C08J 3/03 in aqueous media
• CPC Class Codes: C08L 2666/26 Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
• CPC Class Codes: C08L 61/06 of aldehydes with phenols
• CPC Class Codes: C08L 89/005 Casein

Abstract

An aqueous dispersion of small particles of a phenol/formaldehyde novolac resin, referred to as a dispersed novolac resin, useful for example as a binder in preparing glass fiber insulation. The dispersed novolac resin is produced by preparing a molten novolac resin, cooling, adding water and optionally a surfactant and then adding a protective colloid. Additional water is added to provide the desired dispersion.

Claims

1. A process for producing a dispersed particulate novolac resin comprising the steps in the following order of:

(a) reacting a phenol with an aldehyde in the presence of a catalyst under acidic conditions to produce a novolac resin;

(b) heating the novolac resin to remove water, unreacted phenol, and other volatile organic materials from the resulting novolac and to produce a molten novolac resin;

(c) cooling the molten novolac resin to a point where water can be added;

(d) adding about 10-30 wt % of water based on the total novolac resin solids and, optionally, a surfactant, to the molten resin, the water being added in an amount sufficient to produce a water-in-oil emulsion;

(e) adding a protective colloid to the emulsion in an amount sufficient to stabilize the dispersed particulate novolac resin; and

(f) adding additional water and agitating to produce the dispersed particulate novolac resin, wherein the particulate novolac resin has a particle size of 0.1μ

to 20μ

.

2. The process of claim 1, wherein the phenol is hydroxybenzene and the aldehyde is formaldehyde.

3. The process of claim 1, wherein the acid catalyst is oxalic acid.

4. The process of claim 2, wherein the mole ratio of formaldehyde to phenol is about 0.5 to 0.95.

5. The process of claim 1, wherein the protective colloid is casein.

6. The process of claim 1, wherein a surfactant is present and is lecithin.

7. The process of claim 1, wherein after (b) heating the novolac resin to produce a molten novolac resin, the free phenol is 0.001-2.0%.

8. The process of claim 1, whereby the a particulate novolac resin has a particle size of 0.1μ

to 5μ

.

9. The process of claim 1, whereby the a particulate novolac resin has a particle size of 0.1μ

to 3μ

.

10. The process of claim 1, further comprising

(g) adding a thickener to further stabilize the dispersed particulate novolac resin.

11. The process of claim 1, further comprising adding a cross-linking agent in (c) or after producing the dispersed particulate novolac resin.