Single compartment self-erasing electrochromic device

• US 5,671,082 A
• Filed: 08/25/1994
• Issued: 09/23/1997
• Est. Priority Date: 08/25/1994
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Babinec, Susan J.
• Primary Examiner(s): Epps, Georgia Y.
• Assistant Examiner(s): Robbins, Thomas
• Application Number:
  US08/296,299
• Time in Patent Office: 1,125 Days
• Field of Search: 359/265, 359/270, 359/272
• US Class Current: 359/272
• CPC Class Codes: G02F 1/1503 caused by oxidation-reduction reactions in organic liquid solutions, e.g. viologen solutions

Abstract

An electrochromic device comprising three elements. The first element is a first electrode. The second element is a second electrode. The second electrode is spaced apart from the first electrode so that there is a space between the first electrode and the second electrode. The third element is a dispersion positioned in the space. The dispersion is in electrical contact with the first electrode and with the second electrode. The dispersion comprises a transition metal surface substituted polyoxometalate and a solvent. The first and second electrodes can be a transparent electronically conducting layer of indium-tin oxide coated upon a panel of glass. The transition metal surface substituted polyoxometalate can be Li_x MnPW₁₁ O₄₀. The dispersion is resistant to photodegradation such as discoloring in sunlight.

Claims

1. A photostable electrochromic device comprising:

(a) a first electrode;

(b) a second electrode, the second electrode spaced apart from the first electrode so that there is a space between the first electrode and the second electrode; and

(c) a dispersion positioned in the space between the first electrode and the second electrode, the dispersion being in electrical contact with the first electrode and with the second electrode, the dispersion comprising a transition metal surface substituted polyoxometalate and a solvent.

2. The electrochromic device of claim 1 wherein the solvent is a liquid solvent.

3. The electrochromic device of claim 2 wherein the liquid solvent is selected from the group consisting of alcohols, ethers, amides, amines, esters, carbonates, nitriles, water, nitrated hydrocarbons, inorganic acids, inorganic bases, organic acids, hydrocarbons, sulfones and sulfolanes, aldehydes, ketones and chlorinated hydrocarbons.

4. The electrochromic device of claim 3 the dispersion further comprising a thickening agent.

5. The electrochromic device of claim 2 the dispersion further comprising a thickening agent.

6. The electrochromic device of claim 1 wherein the solvent is a solid solvent.