Process for introducing a filling gas into an enclosure and installation for employing same

• US 5,676,736 A
• Filed: 02/20/1996
• Issued: 10/14/1997
• Est. Priority Date: 02/17/1995
• Status: Expired due to Fees

• Current Assignee: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploitation Des Procedes Georges Claude (L'Air Liquide SA)
• Original Assignee: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploitation Des Procedes Georges Claude (L'Air Liquide SA)
• Inventors: Crozel, Didier
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US08/604,017
• Time in Patent Office: 602 Days
• Field of Search: 95/45, 95/47-56, 95/90, 95/96, 95/116, 95/149, 95/230, 96/4, 96/7-13, 96/108, 96/130, 96/133, 426/418, 426/419
• US Class Current: 95/45
• CPC Class Codes: B01D 53/00 Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols, recovery of volatile solvents by condensation B01D5/00; sublimation B01D7/00; cold traps, cold baffles B01D8/00; working-up undefined gaseous mixtures obtained by cracking hydrocarbon oils C10G70/00; cleaning coal gas C10K; working-up of natural gas, or synthetic natural gas, C10L3/10; separation of difficult-to-condense gases or air by liquefaction F25J; for investigating materials G01N30/00
• CPC Class Codes: C01B 23/00 Noble gases; Compounds thereof liquefying F25J ; noble gases obtained by rectification F25J3/028
• CPC Class Codes: E06B 3/6775 Evacuating or filling the gap during assembly

Abstract

The process for introducing a filling gas into an enclosure initially containing a holding gas includes a step of introducing the filling gas into the enclosure as well as a step of extracting a specific gas initially contained in the filling gas or the holding gas from a mixture collected at the outlet of the enclosure, and possibly a step of recycling this extracted specific gas. Before the step of introducing the filling gas, the enclosure is purged using a purging gas which differs from the fill and holding gases.

Claims

1. A process for introducing a filling gas into an enclosure initially including a holding gas comprising the steps of:

(i) introducing the filling gas into the enclosure;

(ii) extracting a specific gas initially included in the filling gas or the holding gas from a mixture collected at an outlet of the enclosure;

(iii) optionally recycling the extracted specific gas; and

(iv) purging the enclosure with a purging gas which differs from the filling gas and the holding gas before the step of introducing the filling gas into the enclosure.

2. The process as claimed in claim 1, wherein the purging gas of step (iv) is employed such that the specific gas is more easily extractable from the mixture which said specific gas forms with the purging gas than from a mixture formed by the holding gas and the filling gas in the absence of said purging gas.

3. The process as claimed in claim 1, comprising collecting said mixture during the step of introducing the filling gas, said extracted specific gas being included initially in the filling gas.

4. The process as claimed in claim 3 further comprising, after the step of introducing the filling gas, a succession of alternate steps of:

(i) purging the enclosure with the purging gas and introducing the filling gas into the enclosure; and

(ii) extracting the specific gas from the mixture collected at the outlet of the enclosure at least during each of said purging steps.

5. The process as claimed in claim 1, comprising collecting a mixture of said holding gas and said purging gas at least during the step of purging the enclosure, said specific gas being included in the holding gas.

6. The process as claimed in claim 1, comprising continuing the step of introducing the filling gas until said enclosure is almost totally filled with the filling gas.

7. The process according to claim 1, comprising extracting the purging gas from the mixture collected at the outlet of the enclosure and optionally recycling said purging gas.

8. The process as claimed in claim 7, comprising recovering the purging gas and optionally recycling said purging gas during extraction of the specific gas.

9. The process as claimed in claim 1, wherein the extraction step comprises a selective distillation or a separation by simple cooling and wherein the purging gas and the specific gas have boiling points which are further apart than the specific gas and a mixture of the holding gas and the filling gas.

10. The process as claimed in claim 1, wherein the extraction step comprises selective adsorption by means of an adsorbent having a selectively in relation to the purging gas and the specific gas which is greater than that which it exhibits in relation to the specific gas and to a mixture of the holding gas and the filling gas.

11. The process as claimed in claim 1, wherein the extraction step comprises a selective permeation which employs a permeation membrane having a selectivity in relation to the purging gas and the specific gas which is greater than that which it exhibits in relation to the specific gas and to a mixture of the holding and the filling gas.

12. The process as claimed in claim 1, wherein the extraction step comprises selective absorption, by means of an absorbent having a selectivity in relation to the purging gas and the specific gas which is greater than that which it exhibits in relation to the specific gas and to a mixture of the holding gas and the filling gas.

13. The process as claimed in claim 1, wherein the specific gas comprises argon, neon, krypton, xenon, or sulfur hexafluoride, and wherein the purging gas comprises argon, carbon dioxide, helium, or hydrogen.

14. The process as claimed in claim 1 further comprising the step of filling a gap between multiple glazings with said specific gas.

15. A process of employing a specific gas in an enclosure initially including a holding gas, said process comprising the steps of:

(i) introducing a filling gas comprising the specific gas into the enclosure;

wherein before the step (i) of introducing the filling gas, the enclosure is purged by means of a purging gas which differs from the filling and holding gases;

(ii) extracting the specific gas from a mixture collected at an outlet of the enclosure during the step (i) of introducing the filling gas;

wherein after the step (i) of introducing the filling gas, the enclosure is again purged by means of a second purging gas which differs from the filling and holding gases, before again introducing a second holding gas into the enclosure; and

extracting the specific gas from the mixture collected at the outlet of the enclosure at least during the purging of the enclosure of step (ii).

16. The process as claimed in claim 15 further comprising, after the step of introducing the filling gas, a succession of alternate steps of:

(i) purging the enclosure with the purging gas and introducing the filling gas into the enclosure; and

(ii) extracting the specific gas from the mixture collected at the outlet of the enclosure at least during each of said purging steps.

17. An installation for introducing a filling gas into an enclosure initially including a holding gas, comprising:

(i) an enclosure for employing said filling gas, including an inlet connected to a filling gas feedpipe, an inlet connected to a purging gas feed pipe, and a discharge outlet;

(ii) a source of said filling gas;

(iii) a source of said purging gas; and

(iv) a device for extracting a specific gas initially included in the filling gas or the holding gas, from a mixture collected at said discharge outlet, said device being connected to said discharge outlet of said enclosure;

wherein said source of purging gas is chosen such that said specific gas is more easily extractable from a mixture formed of said specific gas and said purging gas than from a mixture which would be formed by said holding gas and said filling gas in the absence of said purging gas.

18. The installation as claimed in claim 17 wherein said device further comprises a discharge outlet for the extracted specific gas which is connected to the filling gas feed pipe.

19. The installation as claimed in claim 17, wherein the extraction device is a device for separating the purging gas and the specific gas, and wherein said installation further comprises an outlet for discharging the separated purging gas, connected to the purging gas feedpipe.