Electrode and secondary battery using the same

• US 5,677,084 A
• Filed: 11/21/1994
• Issued: 10/14/1997
• Est. Priority Date: 12/25/1992
• Status: Expired due to Fees

• Current Assignee: Toray Industries Incorporated
• Original Assignee: Toray Industries Incorporated
• Inventors: Suzuki, Tatsuhiko, Kidai, Masayuki, Nakae, Takeji, Nii, Mikio, Tsukamoto, Jun
• Primary Examiner(s): Willis, Jr., Prince
• Assistant Examiner(s): CHANEY, CAROL DIANE
• Application Number:
  US08/290,907
• Time in Patent Office: 1,058 Days
• Field of Search: 429/235, 429/232, 429/238, 429/237, 429/213, 429/218, 423/447.2, 423/447.1
• US Class Current: 429/231.3
• CPC Class Codes: D01F 11/14 with organic compounds, e.g. macromolecular compounds
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/587 for inserting or intercalating light metals
• CPC Class Codes: H01M 4/663 containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
• CPC Class Codes: H01M 4/667 in the form of layers, e.g. coatings
• CPC Class Codes: H01M 4/74 Meshes or woven material; Expanded metal
• CPC Class Codes: H01M 4/806 Nonwoven fibrous fabric containing only fibres
• CPC Class Codes: H01M 4/96 Carbon-based electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

The invention relates to an electrode suitable for a chargeable/dischargeable secondary battery in which a carbonaceous material capable of doping and dedoping of lithium ions is used as a negative electrode active material, wherein carbon fibers are used as the carbonaceous material in a form of an uni-directionally arranged body or in combination of electrically conductive foil or fibers, and further relates to a secondary battery using the electrode. The invention enables to provide a secondary battery having high capacitance and high outputtng property.

Claims

1. An electrode which comprises a sheet of uni-directionally arranged carbon fibers extending be essentially in a single direction, which sheet is placed on a metal foil, wherein the electrode is rolled up so that the arranged direction of the carbon fibers is approximately perpendicular to the rolling direction of the electrode.

2. The electrode according to claim 1, wherein the metal foil is a copper foil.

3. The electrode according to claim 1, wherein electroconducting wires are further arranged in the carbon fibers in a direction parallel to the axial direction of the fibers or in a direction perpendicular to the axial direction of the fibers.

4. The electrode according to claim 1, wherein the carbon fibers are pasted and coated with a resin.

5. The electrode according to claim 4, wherein the resin is a thermoplastic resin.

6. The electrode according to claim 4, wherein the resin is a thermosetting resin.

7. The electrode according to claim 4, wherein the amount of the resin used is not smaller than 3% by weight and not larger than 17% by weight based on the amount of the carbon fibers.

8. The electrode according to claim 4, wherein the amount of the resin used is not smaller than 5% by weight and not larger than 10% by weight based on the amount of the carbon fibers.

9. The electrode according to claim 4, wherein the resin is poly(vinylidene fluoride).

10. The electrode according to claim 1, wherein the carbon fibers which have been previously charged and discharged are used as active material.

11. The electrode according to claim 1, which is used as a negative electrode.

12. A secondary battery which uses the electrode according to claim 1.

13. The secondary battery according to claim 12 which uses a non-aqueous electrolytic solution containing lithium salt and a positive electrode capable of taking in and out of lithium.

14. The secondary battery according to claim 12, wherein a transition metal oxide is used for a positive electrode.

15. The secondary battery according to claim 12, wherein the transition metal oxide is LiCoO₂ or LiNiO₂.

16. An electrode which comprises a sheet of uni-directionally arranged carbon fibers extending essentially in a single direction, which sheet is placed on a metal foil, wherein the electrode is rolled up so that the arranged direction of the carbon fibers is approximately parallel to the rolled direction of the electrode.