Electrophotographic photoreceptor

• US 5,677,097 A
• Filed: 01/15/1997
• Issued: 10/14/1997
• Est. Priority Date: 01/18/1996
• Status: Expired due to Term

• Current Assignee: Fuji Xerox Company Limited (Xerox Holdings Corp.)
• Original Assignee: Fuji Xerox Company Limited (Xerox Holdings Corp.)
• Inventors: Nukada, Hidemi, Nukada, Katsumi
• Primary Examiner(s): MARTIN, ROLAND E
• Application Number:
  US08/779,645
• Time in Patent Office: 272 Days
• Field of Search: 430/58, 430/59, 430/60, 430/61
• US Class Current: 430/58.7
• CPC Class Codes: G03G 5/0609 containing oxygen
• CPC Class Codes: G03G 5/0655 containing six relevant rings
• CPC Class Codes: G03G 5/0657 containing seven relevant rings
• CPC Class Codes: G03G 5/0659 containing more than seven relevant rings
• CPC Class Codes: G03G 5/0672 containing two or more methine or polymethine groups
• CPC Class Codes: G03G 5/0681 containing hetero rings in the part of the molecule between the azo-groups
• CPC Class Codes: G03G 5/0696 Phthalocyanines
• CPC Class Codes: G03G 5/075 obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds G03G5/078 takes precedence
• CPC Class Codes: G03G 5/0764 triarylamine
• CPC Class Codes: G03G 5/0766 benzidine
• CPC Class Codes: G03G 5/142 Inert intermediate layers
• CPC Class Codes: G03G 5/144 comprising inorganic material

Abstract

In an electrophotographic photoreceptor in which an undercoating layer and a photosensitive layer are provided on a conductive substrate, the undercoating layer preferably contains at least one electron transporting pigment and a reactive organometallic compound, the electron transporting pigment being selected from a group consisting of an electron transporting polycyclic quinone pigment such as brominated anthoanthrone, an electron transporting perylene pigment, an electron transporting phthalocyanine pigment, and an electron transporting azo pigment, and the surface of the electrophotographic photoreceptor contains at least one resin selected from electric charge transporting polycarbonate and electric charge transporting polyester. As a result, it is possible to provide an electrophotographic organic photoreceptor having stabilized performance and durability, which is not affected by environmental changes even when used for a long period of time and in which deterioration of the performance and electric characteristics thereof is prevented.

Claims

1. An electrophotographic photoreceptor in which an undercoating layer and a photosensitive layer are provided on a conductive substrate,

wherein the undercoating layer contains an electron transporting pigment and a reactive organometallic compound, and a surface layer of the electrophotographic photoreceptor contains at least one resin selected from electric charge transporting polycarbonate and electric charge transporting polyester.

2. An electrophotographic photoreceptor according to claim 1, wherein an electron transporting polycyclic quinone pigment is used as said electron transporting pigment.

3. An electrophotographic photoreceptor according to claim 2, wherein said electron transporting polycyclic quinone pigment is brominated anthoanthrone.

4. An electrophotographic photoreceptor according to claim 1, wherein an electron transporting perylene pigment is used as said electron transporting pigment.

5. An electrophotographic photoreceptor according to claim 1, wherein an electron transporting phthalocyanine pigment is used as said electron transporting pigment.

6. An electrophotographic photoreceptor according to claim 1, wherein an electron transporting azo pigment is used as said electron transporting pigment.

7. An electrophotographic photoreceptor according to claim 1, wherein the resin selected from the electric charge transporting polycarbonate resin and the electric charge transporting polyester resin has an aryl-amine structure.

8. An electrophotographic photoreceptor according to claim 1, wherein the resin selected from the electric charge transporting polycarbonate resin and the electric charge transporting polyester resin has at least one structure selected from the group consisting of the following general formula (I-1) and (I-2) as a partial structure of a repeating unit:

##STR111## wherein R¹ to R⁴ each independently is a hydrogen atom, an alkyl group, an alkoxy group, a substituted amino group, a halogen atom, or a substituted or an unsubstituted aryl group;

X represents a substituted or an unsubstituted arylene group;

k and l each independently is an integer selected from 0 and 1; and

T represents an optionally branched, divalent hydrocarbon group having 1 to 10 carbon atoms.

9. An electrophotographic photoreceptor according to claim 1, wherein the resin selected from the electric charge transporting polycarbonate resin and the electric charge transporting polyester resin is selected from the group the group consisting of any one of the following general formulae (II), (III) and (IV):

##STR112## wherein A is the structure represented by the general formula (I-1) or (I-2);

B represents --O--(Y² O)_m'"'"' or --Z² --;

Y and Y² represent divalent hydrocarbon groups;

Z and Z² represent divalent hydrocarbon groups;

m, m² and m'"'"' each represents an integer of 1 to 5;

n represents an integer selected from 0 and 1; and

p, p² and p³ each represents an integer of 5 to 5000.

10. An electrophotographic photoreceptor according to claim 1, wherein said photosensitive layer contains, as an electric charge generating material, at least one selected from the group consisting of halogenated gallium phthalocyanine crystals, tin-halide phthalocyanine crystals, hydroxygallium phthalocyanine crystals, and oxytitanyl phthalocyanine crystals.

11. An electrophotographic photoreceptor according to claim 1, wherein said reactive organometallic compound is selected from the group consisting of an organic zircon into compounds, organic titanium compounds, and organic aluminum compounds.

12. An electrophotographic photoreceptor according to claim 1, wherein a ratio by weight of the electron transporting pigment to the reactive organometallic compound is set in the range of 100:

1 to 1;

1.

13. An electrophotographic photoreceptor according to claim 1, wherein said photosensitive layer comprises an electric charge generating/electric charge transporting layer, or comprises an electric charge generating layer and an electric charge transporting layer.

14. An electrophotographic photoreceptor according to claim 13, wherein the surface layer is an electric charge generating/electric charge transporting layer, or an electric charge transporting layer.

15. An electrophotographic photoreceptor in which an undercoating layer and a photosensitive layer are provided on a conductive substrate,

wherein the undercoating layer contains an electron transporting pigment and a reactive organometallic compound, the electron transporting pigment being selected from the group consisting of an electron transporting polycyclic quinone pigment, an electron transporting perylene pigment, an electron transporting phthalocyanine pigment, and an electron transporting azo pigment, and

wherein a surface layer of the electrophotographic photoreceptor contains at least one resin selected from the group consisting of electric charge transporting polycarbonate and electric charge transporting polyester, the electrical charge transporting polycarbonate and electrical charge transporting polyester being represented by any of the following general formulae (II), (III) and (IV):

##STR113## wherein A is the structure represented by the following general formula (I-1) or (I-2);

B represents --O--(Y² O)_m'"'"' or --Z² --;

Y and Y² represent divalent hydrocarbon groups;

Z and Z² represent divalent hydrocarbon groups;

m, m² and m'"'"' each represents an integer of 1 to 5;

n represents an integer selected from 0 and 1; and

p, p², p³ each represents an integer of 5 to 5000;

##STR114## wherein R¹ to R⁴ each independently is a hydrogen atom, an alkyl group, an alkoxy group, a substituted amino group, a halogen atom, or a substituted or an unsubstituted aryl group;

X is a substituted or an unsubstituted arylene group;

k and l each independently represents an integer selected from 0 and 1; and

T is an optionally branched, divalent hydrocarbon group having 1 to 10 carbon atoms.

16. An electrophotographic photoreceptor according to claim 15, wherein said reactive organometallic compound is selected from group consisting of an organic zirconium compounds, organic titanium compounds, and organic aluminum compounds.

17. An electrophotographic photoreceptor according to claim 15, wherein said photosensitive layer comprises an electric charge generating/electric charge transporting layer, or comprises an electric charge generating layer and an electric charge transporting layer.

18. An electrophotographic photoreceptor according to claim 17, wherein the surface layer is an electric charge generating/electric charge transporting layer, or an electric charge transporting layer.

19. An electrophotographic photoreceptor according to claim 17, wherein said electric charge generating/electric charge transporting layer, or said electric charge generating layer contains, as an electric charge generating material, at least one selected from the group consisting of halogenated gallium phthalocyanine crystals, tin-halide phthalocyanine crystals, hydroxygallium phthalocyanine crystals, and oxytitanyl phthalocyanine crystals.

20. An electrophotographic photoreceptor according to claim 15, wherein a ratio by weight of the electron transporting pigment to the reactive organometallic compound is set in the range of 100:

1 to 1;

1.