Method for capture of chlorine dissociated from a chlorine-containing compound

• US 5,678,244 A
• Filed: 02/14/1995
• Issued: 10/14/1997
• Est. Priority Date: 02/14/1995
• Status: Expired due to Fees

• Current Assignee: Quantum Catalytics LLC
• Original Assignee: Molten Metal Technology Incorporated
• Inventors: Shaw, Cathy M., Johnston, James E.
• Primary Examiner(s): MAI, NGOCLAN THI
• Application Number:
  US08/388,941
• Time in Patent Office: 973 Days
• Field of Search: 588/201, 588/206, 588/207, 110/237, 423/DIG. 12
• US Class Current: 588/314
• CPC Class Codes: A62D 2101/22 containing halogen
• CPC Class Codes: A62D 3/32 by treatment in molten chemical reagent, e.g. salts or metals
• CPC Class Codes: C03C 1/002 Use of waste materials, e.g. slags
• CPC Class Codes: C03C 10/16 Halogen containing crystalline phase
• CPC Class Codes: C03C 3/062 with less than 40% silica by weight
• CPC Class Codes: C03C 3/11 containing halogen or nitrogen

Abstract

A method is disclosed for capture of chlorine dissociated from a chlorine-containing compound. A molten metal bath has a molten metal phase, which includes a metal or salt, and a fluid vitreous phase including calcium oxide, aluminum oxide, and sufficient silicon dioxide to cause the vitreous phase to remain fluid during exposure to chlorine dissociated from the chlorine-containing compound. The chlorine-containing compound is directed into the molten phase to cause the chlorine to dissociate from the compound, whereby the chlorine migrates to the fluid vitreous layer and interacts with the vitreous phase including calcium oxide to form an inorganic chlorinated compound, thereby capturing the chlorine from the chlorine-containing compound.

Claims

1. A method for capture of chlorine dissociated from a chlorine-containing compound while maintaining a fluid vitreous phase, comprising the steps of:

a) providing a molten bath having a molten metal phase and a fluid vitreous phase, said fluid vitreous phase including concentrations of calcium oxide, aluminum oxide, and silicon dioxide that cause the vitreous phase to remain fluid during exposure to chlorine dissociated from the chlorine-containing compound;

b) directing the chlorine-containing compound into the molten metal phase to cause the chlorine to dissociate from said compound, whereby the chlorine migrates to the fluid vitreous phase and interacts with the calcium oxide in the fluid vitreous phase to form an inorganic chlorinated compound, while causing the vitreous phase to remain fluid during exposure to chlorine dissociated from the chlorine-containing compound, thereby capturing the chlorine dissociated from the chlorine-containing compound; and

c) adjusting the concentrations of the calcium oxide, aluminum oxide and silicon dioxide to maintain the fluidity of the vitreous layer in the presence of captured chlorine.

2. The method of claim 1 wherein the concentration of calcium oxide is in the range of between about 35 and 70 percent, by weight.

3. The method of claim 2 wherein the concentration of silicon dioxide is in the range of between about 25 and 50 percent, by weight.

4. The method of claim 3 wherein the aluminum oxide in the vitreous phase has a concentration up to about 40 percent, by weight.

5. The method of claim 1 wherein the molten metal phase includes iron.

6. The method of claim 1 wherein the molten metal phase includes nickel.

7. The method of claim 1 wherein the molten bath has a temperature in the range of between about 1,400°

and 1,700°

C.

8. The method of claim 7 wherein the chlorine-containing compound is an organic chlorinated compound.

9. The method of claim 8 wherein the organic chlorinated compound is a chlorinated aromatic.

10. The method of claim 9 wherein the chlorinated aromatic is a polychlorinated biphenyl.

11. The method of claim 9 wherein the chlorinated aromatic is a dioxin.

12. The method of claim 8 wherein the organic chlorinated compound is a chlorinated alkane.

13. The method of claim 1 wherein the inorganic chlorinated compound is calcium chloride.

14. The method of claim 1 wherein the vitreous phase further includes at least one compound selected from the group consisting of magnesium oxide, strontium oxide, lithium oxide, sodium oxide and potassium oxide.

15. A method for capture of chlorine dissociated from a chlorine-containing compound, comprising the steps of:

a) providing a molten bath having a molten metal phase and a fluid vitreous phase wherein said fluid vitreous phase includes concentrations of a calcium-containing composition, aluminum oxide and silicon dioxide to cause the vitreous phase to remain fluid during exposure to chlorine dissociated from the chlorine-containing compound;

b) directing the chlorine-containing compound into the molten metal phase, whereby the chlorine dissociates from the chlorine-containing compound and migrates to the vitreous phase to interact with the vitreous phase and form an inorganic chlorinated compound or complex, while causing the vitreous phase to remain fluid during exposure to chlorine dissociated from the chlorine-containing compound, thereby capturing the chlorine of the chlorine-containing compound;

c) removing a portion of the vitreous phase containing the inorganic chlorinated compound from the molten portion of the bath; and

d) replacing the removed portion of the vitreous phase with a vitreous phase having a reduced content of said inorganic chlorinated compound.

16. The method of claim 15 wherein the calcium-containing composition includes calcium oxide and at least one compound selected from the group consisting of magnesium oxide, strontium oxide, lithium oxide, sodium oxide and potassium oxide.

17. A method for capture of chlorine dissociated from a chlorinated organic compound to prevent the formation of hydrogen chloride gas, comprising the steps of:

a) providing a molten bath having a molten metal phase and a fluid vitreous phase, said fluid vitreous phase including concentrations of calcium oxide, aluminum oxide and silicon dioxide to cause the vitreous phase to remain fluid during exposure to chlorine dissociated from the chlorinated organic compound;

b) directing the chlorinated organic compound into the molten metal phase to cause hydrogen and chlorine to dissociate from said compound, whereby the chlorine migrates to the fluid vitreous phase and interacts with the calcium oxide to form an inorganic chlorinated compound and the hydrogen migrates to a gas phase above the molten bath, while causing the vitreous phase to remain fluid during exposure to chlorine dissociated from the chlorinated organic compound, thereby capturing the chlorine dissociated from the chlorinated organic compound to prevent the formation of hydrogen chloride gas;

c) removing a portion of the vitreous phase containing the inorganic chlorinated compound from the molten bath; and

d) replacing the removed portion of the vitreous phase with a vitreous phase having a reduced content of said inorganic chlorinated compound, thereby continuing to capture the chlorine dissociated from the chlorinated organic compound to prevent the formation of hydrogen chloride gas, while maintaining the vitreous phase fluid.

18. A method for capture of chlorine dissociated from a chlorine-containing compound, comprising the steps of:

a) providing a molten bath having a fluid vitreous phase, said fluid vitreous phase including a concentration of aluminum oxide of up to about five percent and concentrations of calcium oxide and silicon dioxide that cause the vitreous phase to remain fluid during exposure to chlorine dissociated from the chlorine-containing compound; and

b) directing the chlorine-containing compound into the molten bath to cause the chlorine to dissociate from said compound whereby the chlorine migrates to the fluid vitreous phase and interacts with the calcium oxide in the fluid vitreous phase to form an inorganic chlorinated compound, while causing the vitreous phase to remain fluid during exposure to chlorine dissociated from the chlorine-containing compound, thereby capturing the chlorine dissociated from the chlorine-containing compound.