Method and system for injection of a vaporizable material into a molten bath

• US 5,679,132 A
• Filed: 06/07/1995
• Issued: 10/21/1997
• Est. Priority Date: 06/07/1995
• Status: Expired due to Term

• Current Assignee: Quantum Catalytics LLC
• Original Assignee: Molten Metal Technology Incorporated
• Inventors: Rauenzahn, Rick M., Nagel, Christopher J.
• Primary Examiner(s): KASTLER, SCOTT R
• Application Number:
  US08/475,982
• Time in Patent Office: 867 Days
• Field of Search: 266/216, 266/222, 266/268, 266/221, 266/267, 75/528, 588/210, 423/DIG. 12
• US Class Current: 75/528
• CPC Class Codes: A62D 2203/10 Apparatus specially adapted for treating harmful chemical agents; Details thereof
• CPC Class Codes: B01J 10/005 carried out at high temperatures in the presence of a molten material
• CPC Class Codes: B01J 2219/0009 Coils
• CPC Class Codes: B01J 4/002 Nozzle-type elements nozzle-type reactors B01J19/26
• CPC Class Codes: F27B 3/08 heated electrically, with or without any other source of heat
• CPC Class Codes: F27B 3/22 Arrangements of air or gas supply devices
• CPC Class Codes: F27B 3/26 Arrangements of heat-exchange apparatus
• CPC Class Codes: F27D 17/004 Systems for reclaiming waste heat
• CPC Class Codes: F27D 17/008 cleaning gases
• CPC Class Codes: F27D 2003/166 the fluid being a treatment gas
• CPC Class Codes: F27D 2003/167 the fluid being a neutral gas
• CPC Class Codes: F27D 2027/002 Gas stirring
• CPC Class Codes: F27D 2099/0015 Induction heating
• CPC Class Codes: F27D 3/1518 Tapholes
• CPC Class Codes: F27D 3/16 Introducing a fluid jet or current into the charge porous elements for gas flushing of molten metals B22D1/005
• CPC Class Codes: F27D 3/18 Charging particulate material using a fluid carrier
• CPC Class Codes: F27D 99/0006 Electric heating elements or system
• CPC Class Codes: F27M 2001/05 Waste materials, refuse
• CPC Class Codes: F27M 2003/11 Incineration
• CPC Class Codes: Y02P 10/25 Process efficiency
• CPC Class Codes: Y10S 423/12 : Molten media

Abstract

A method and apparatus are disclosed for injecting vaporizable material, such as a vaporizable waste, into a molten bath. A gas is injected into the molten bath at a rate which is sufficient to cause the gas and the molten bath to form a gaseous dispersion. The gas component of the gaseous dispersion occupies a sufficient fraction of said dispersion to cause a significant portion of the vaporizable material, at a rate at which the vaporizable material is injected into the molten bath, to volatilize, combust or decompose during exposure to said gas component. A vaporizable material, such as a particulate solid or hazardous liquid waste, is injected into the gaseous dispersion at a rate which cases a significant portion of the vaporizable material to volatilize, combust or decompose during exposure of said vaporizable material to the gas component of said gaseous dispersion.

Claims

1. A method for injecting a vaporizable material into a molten bath having a temperature which is significantly higher than the nucleation, combustion or decomposition temperature of the vaporizable material, comprising the steps of:

a) injecting a gas into the molten bath at a rate which is sufficient to cause the gas and the molten bath to form a gaseous dispersion, the gas component of the gaseous dispersion occupying a sufficient fraction of said dispersion to cause a significant portion of the vaporizable material, at a rate at which the vaporizable material is injected into the molten bath, to volatilize, combust or decompose during exposure to said gas component, and thereby ensure that the molten bath will not explode; and

b) injecting the vaporizable material into the gaseous dispersion at a rate which causes a significant portion of the vaporizable material to volatilize, combust or decompose during exposure of said material to the gas component of said gaseous dispersion, thereby ensuring that the molten bath will not explode.

2. The method of claim 1 wherein the vaporizable material is injected into the molten bath at a point beneath the molten bath upper surface which is remote from the point where the gas is injected into the molten bath.

3. The method of claim 2 wherein the gas is injected into the molten bath at a plurality of points beneath the molten bath surface.

4. The method of claim 3 wherein the points at which the gas is injected into the molten bath are disposed radially about the point where the vaporizable material is injected into the molten bath.

5. The method of claim 4 when the vaporizable material is injected into the molten bath at a plurality of points beneath the molten bath surface.

6. The method of claim 1 wherein the gas and the vaporizable material are directed into the molten bath through a tuyere which is disposed beneath the molten bath upper surface.

7. The method of claim 6 wherein the gas and the vaporizable material are directed into the molten bath jointly and continuously.

8. The method of claim 1 wherein the vaporizable material is a particulate solid.

9. The method of claim 1 wherein the vaporizable material is a liquid.

10. The method of claim 9 wherein the liquid is atomized to form a liquid dispersion which is subsequently injected into the molten bath beneath the molten bath upper surface.

11. The method of claim 10 further including the step of agitating the molten bath in an amount sufficient to significantly increase the surface area of the gas component of the gaseous dispersion.

12. The method of claim 11 wherein the liquid dispersion is directed into the molten bath at a plurality of points beneath an upper surface of the molten bath.

13. The method of claim 12 wherein the gas component of the liquid dispersion is substantially inert under the operating conditions of the molten bath.

14. The method of claim 12 wherein a substantial portion of the gas component of the liquid dispersion reacts with a component of the molten bath under the operating conditions of the molten bath.

15. The method of claim 14 wherein the liquid component of the liquid dispersion is substantially combustible under the operating conditions of the molten bath.

16. The method of claim 1 wherein the molten bath is a molten metal bath.

17. A method for injecting a vaporizable material into a molten bath having a temperature which is significantly higher than the nucleation, combustion or decomposition temperature of the vaporizable material, comprising the steps of:

a) injecting a gas into the molten bath at a rate which is sufficient to cause the gas and the molten bath to form a gaseous dispersion, the gas component of the gaseous dispersion occupying greater than about thirty-five percent of the volume of said dispersion to cause a significant portion of the vaporizable material, at a rate at which the vaporizable material is injected into the molten bath, to volatilize, combust or decompose during exposure to said gas component, and thereby ensure that the molten bath will not explode; and

b) injecting the vaporizable material into the gaseous dispersion at a rate which causes a significant portion of the vaporizable material to volatilize, combust or decompose during exposure of said material to the gas component of said gaseous dispersion, thereby ensuring that the molten bath will not explode.

18. A method for injecting a vaporizable material into a molten bath having a temperature which is significantly higher than the nucleation, combustion or decomposition temperature of the vaporizable material, comprising the steps of:

a) injecting a gas into the molten bath at a rate which is sufficient to cause the gas and the molten bath to form a gaseous dispersion, the gas component of the gaseous dispersion occupying greater than about forty-five percent of the volume of said dispersion to cause a significant portion of the vaporizable material, at a rate at which the vaporizable material is injected into the molten bath, to volatilize, combust or decompose during exposure to said gas component, and thereby ensure that the molten bath will not explode; and

b) injecting the vaporizable material into the gaseous dispersion at a rate which causes a significant portion of the vaporizable material to volatilize, combust or decompose during exposure of said material to the gas component of said gaseous dispersion, thereby ensuring that the molten bath will not explode.

19. A method for injecting a vaporizable material into a molten bath having a temperature which is significantly higher than the nucleation, combustion or decomposition temperature of the vaporizable material, comprising the steps of:

a) injecting a gas into the molten bath at a rate which is sufficient to cause the gas and the molten bath to form a gaseous dispersion, the gas component of the gaseous dispersion occupying a sufficient fraction of said dispersion to cause a significant portion of the vaporizable material, at a rate at which the vaporizable material is injected into the molten bath, to volatilize, combust or decompose during exposure to said gas component, and thereby ensure that the molten bath will not explode; and

thereafter

b) injecting the vaporizable material into the gaseous dispersion at a rate which causes a significant portion of the vaporizable material to volatilize, combust or decompose during exposure of said material to the gas component of said gaseous dispersion, thereby ensuring that the molten bath will not explode.

20. A method for injecting a vaporizable material into a molten bath having a temperature which is significantly higher than the nucleation, combustion or decomposition temperature of the vaporizable material, comprising the steps of:

a) injecting a gas into the molten bath at a rate which is sufficient to cause the gas and the molten bath to form a gaseous dispersion, the gas component of the gaseous dispersion occupying greater than about forty percent of the volume of said dispersion to cause a significant portion of the vaporizable material, at a rate at which the vaporizable material is injected into the molten bath, to volatilize, combust or decompose during exposure to said gas component, and thereby ensure that the molten bath will not explode; and

thereafter

b) injecting the vaporizable material into the gaseous dispersion at a rate which causes a significant portion of the vaporizable material to volatilize, combust or decompose during exposure of said material to the gas component of said gaseous dispersion, thereby ensuring that the molten bath will not explode.

21. A method for injecting a vaporizable material into a molten bath having a temperature which is significantly higher than the nucleation, combustion or decomposition temperature of the vaporizable material, comprising the steps of:

a) injecting a gas into the molten bath at a rate which is sufficient to cause the gas and the molten bath to form a gaseous dispersion, the gas component of the gaseous dispersion occupying greater than about ten percent of the volume of said molten bath, to cause a significant portion of the vaporizable material, at a rate at which the vaporizable material is injected into the molten bath, to volatilize, combust or decompose during exposure to said gas component, and thereby ensure that the molten bath will not explode; and

b) injecting the vaporizable material into the gaseous dispersion at a rate which causes a significant portion of the vaporizable material to volatilize, combust or decompose during exposure of said material to the gas component of said gaseous dispersion, thereby ensuring that the molten bath will not explode.

22. A method for injecting a vaporizable material into a molten bath having a temperature which is significantly higher than the nucleation, combustion or decomposition temperature of the vaporizable material, comprising the steps of:

a) injecting a gas into the molten bath at a rate which is sufficient to cause the gas and the molten bath to form a gaseous dispersion, the gas component of the gaseous dispersion occupying between about ten percent and about thirty percent of the total volume of said bath, to cause a significant portion of the vaporizable material, at a rate at which the vaporizable material is injected into the molten bath, to volatilize, combust or decompose during exposure to said gas component, and thereby ensure that the molten bath will not explode; and

b) injecting the vaporizable material into the gaseous dispersion at a rate which causes a significant portion of the vaporizable material to volatilize, combust or decompose during exposure of said material to the gas component of said gaseous dispersion, thereby ensuring that the molten bath will not explode.