Process for making wire

• US 5,679,232 A
• Filed: 04/18/1996
• Issued: 10/21/1997
• Est. Priority Date: 04/19/1993
• Status: Expired due to Term

• Current Assignee: Nikko Materials USA, Inc. (Eternal Materials Co., Ltd.)
• Original Assignee: Electrocopper Products Limited
• Inventors: Eamon, Michael A., Peckham, Peter, Young, Sharon K., Kohut, Stephen J., Hasegawa, Craig J., DeWitt, Robert D., Fedor, Robert J., Enos, Susan S., Wright, Roger N.
• Primary Examiner(s): Tsai, Jey
• Assistant Examiner(s): Mee, Brendan
• Application Number:
  US08/634,271
• Time in Patent Office: 551 Days
• Field of Search: 205/77, 29/412, 29/413, 29/17.1, 29/17.2, 29/17.8, 29/DIG. 12, 29/DIG. 33
• US Class Current: 205/77
• CPC Class Codes: C25D 1/04 Wires; Strips; Foils
• CPC Class Codes: C25D 3/38 of copper
• CPC Class Codes: C25D 7/0614 Strips or foils
• CPC Class Codes: Y10T 29/301 Method
• CPC Class Codes: Y10T 29/307 by shaving or longitudinal cutting
• CPC Class Codes: Y10T 29/49789 Obtaining plural product pieces from unitary workpiece
• CPC Class Codes: Y10T 29/4979 Breaking through weakened portion

Abstract

This invention relates to a process for making metal wire, comprising: (A) forming metal foil; (B) cutting said foil to form at least one strand of metal wire; and (C) shaping said strand of wire to provide said strand with desired cross-sectional shape and size. This process is particularly suitable for making copper wire, especially copper wire having a very thin diameter (e.g., about 0.0002 to about 0.02 inch).

Claims

1. A process for making metal wire, comprising:

(A) forming a thin web of metal foil having a thickness of about 0.001 to about 0.05 inch, said metal being selected from the group consisting of copper, gold, silver, tin, chromium, zinc, nickel, platinum, palladium, iron, aluminum, steel, lead, brass, or an alloy of one or more of the foregoing metals;

(B) cutting said foil to form at least one strand of wire; and

(C) shaping said strand of wire to provide said strand with desired cross-sectional shape and size.

2. The process of claim 1 wherein said metal is an alloy selected from the group consisting of copper/zinc, copper/silver, copper/tin/zinc, copper/phosphorus, chromium/molybdenum, nickel/chromium and nickel/phosphorus.

3. The process of claim 1 wherein said metal is copper or a copper-based alloy.

4. The process of claim 1 wherein said metal foil is wrought copper foil.

5. The process of claim 1 with the step of cleaning said strand of wire from step (B) prior to step (C).

6. The process of claim 1 wherein said wire has a round cross-sectional shape.

7. The process of claim 1 wherein said wire has a square or rectangular cross-sectional shape.

8. The process of claim 1 wherein said wire has a cross-sectional shape in the form of a cross, star, semi-circle, polygon, race track, oval, flat or ribbed-flat.

9. The process of claim 1 wherein said wire has a cross-sectional shape in a form substantially as illustrated in any one of FIGS. 3-20.

10. The process of claim 1 wherein said metal foil is electro-deposited copper foil.

11. The process of claim 10 wherein said foil is formed in an electroforming cell comprising an anode and a cathode, said cathode being horizontally mounted.

12. The process of claim 10, wherein said foil is formed in an electroforming cell comprising an anode and a cathode, said cathode being vertically mounted.

13. The process of claim 10 wherein said forming step (A) comprises flowing an electrolyte solution between an anode and a cathode and applying an effective amount of voltage across said anode and said cathode to deposit copper foil on said cathode.

14. The process of claim 13 wherein said electrolyte solution has a free chloride ion concentration of up to about 5 ppm.

15. The process of claim 13 wherein said electrolyte solution has a free chloride ion concentration of up to about 1 ppm.

16. The process of claim 13 wherein said electrolyte solution has a free chloride ion concentration of zero.

17. The process of claim 13 wherein said electrolyte solution is free of organic additives.

18. The process of claim 13 wherein said electrolyte solution further comprises at least one organic additive.

19. The process of claim 18 wherein said organic additive is a gelatin or an active sulfur containing material.

20. The process of claim 18 wherein said organic additive is selected from the group consisting of saccharin, caffeine, molasses, guar gum, gum arabic, polyethylene glycol, polypropylene glycol, polyisopropylene glycol, dithiothreitol, proline, hydroxyproline, cysteine, acrylamide, sulfopropyl disulfide, tetraethylthiuram disulfide, benzyl chloride, epichlorohydrin, chlorohydroxylpropylsulfonate, ethylene oxide, propylene oxide, sulfonium alkane sulfonate, thiocarbamoyldisulfide and selenic acid.

21. The process of claim 13 wherein said electrolyte solution has a copper ion concentration in the range of about 40 to about 150 grams per liter, a free sulfuric acid concentration in the range of about 70 to about 170 grams per liter, and a chloride ion concentration of up to about 5 ppm.

22. The process of claim 13 wherein the current density during step (A) is in the range of about 50 to about 3000 amps per square foot.

23. The process of claim 13 wherein the flow velocity of electrolyte between said anode and said cathode is in the range of about 0.2 to about 5 meters per second.

24. A process for making copper wire, comprising:

(A) forming a thin web of copper foil having a thickness of about 0.001 to about 0.05 inch;

(B) cutting said foil to form at least one strand of copper wire; and

(C) shaping said strand of copper wire to provide said strand with desired cross-sectional shape and size.

25. A process for making copper wire comprising:

(A) flowing an electrolyte solution between an anode and a cathode in an electroforming cell and applying an effective amount of voltage across said anode and said cathode to deposit copper on said cathode, said electrolyte solution being characterized by a free chloride ion concentration of up to about 5 ppm;

(B) score-cutting said copper to form a strand of copper wire and removing said strand of copper from said cathode; and

(C) shaping said strand of copper wire to provide copper wire with desired cross-sectional shape and size.

26. A process for making copper wire comprising:

(A) flowing an electrolyte solution between an anode and a cathode in an electroforming cell and applying an effective amount of voltage across said anode and said cathode to deposit a thin web of copper foil having a thickness of about 0.001 to about 0.05 inch on said cathode, said electrolyte solution being characterized by a free chloride ion concentration of up to about 5 ppm;

(B) removing said copper foil from said cathode;

(C) cutting said copper foil to form at least one strand of copper wire; and

(D) shaping said strand of copper wire to provide copper wire with desired cross-sectional shape and size.

27. A process for making metal wire, comprising:

.

(A) forming metal foil;

(B) cutting said foil to form at least one strand of wire; and

(C) shaping said strand of wire to provide said strand with desired cross-sectional shape and size;

wherein said metal foil is electrodeposited copper foil and is formed in an electroforming cell on a cathode during step (A), and said cutting step (B) comprises score cutting said foil while on said cathode to form said strand of wire and removing said strand from said cathode.

28. The process of claim 27 wherein prior to step (B), said cathode is removed from said electroforming cell.