Electrochromic layer and devices comprising same
First Claim
1. An electrochromic layer of reversibly variable transmittance to light which comprises:
- (a) a polymer matrix of a polyol polymer which has an hydroxyl functionality of at least 2 and wherein the polyol polymer chains are covalently cross-linked through hydroxyl groups; and
(b) an electrochromic solution which comprises an anodic and a cathodic electrochromic compound interspersed in the polymer matrix.
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Accused Products
Abstract
The present invention provides electrochromic layers, which comprise polymeric matrices with electrochromic solutions interspersed therein. Varying an electrical potential difference across a layer of the invention results in reversible variation in the transmittance of light across the layer because of electrochemical processes in the electrochromic solution of the layer. The invention further provides electrochromic devices, in which the electrochromic layers of the invention provide reversibly variable transmittance to light, and various apparatus in which the devices of the invention provide light-filtering or light-color modulation. Such apparatus include windows, including those for use inside and on the outside walls of buildings and in sunroofs for automobiles, and variable reflectance mirrors, especially rearview mirrors for automobiles.
207 Citations
120 Claims
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1. An electrochromic layer of reversibly variable transmittance to light which comprises:
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(a) a polymer matrix of a polyol polymer which has an hydroxyl functionality of at least 2 and wherein the polyol polymer chains are covalently cross-linked through hydroxyl groups; and (b) an electrochromic solution which comprises an anodic and a cathodic electrochromic compound interspersed in the polymer matrix. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 62, 63, 64, 65, 67, 68, 69, 70)
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57. An electrochromic device which comprises, as the medium of reversibly variable transmittance to light, an electrochromic layer of reversibly variable transmittance to light which comprises:
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(a) a polymer matrix of a polyol polymer which has an hydroxyl functionality of at least 2 and wherein the polyol polymer chains are covalently cross-linked through hydroxyl groups; and (b) an electrochromic solution which comprises an anodic and a cathodic electrochromic compound interspersed in the polymer matrix. - View Dependent Claims (58, 59, 60, 61, 66)
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71. A window which comprises, as the variable transmittance element, an electrochromic device which comprises, as the medium of reversibly variable transmittance to light, an electrochromic layer of reversibly variable transmittance to light which comprises:
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(a) a polymer matrix of a polyol polymer which has an hydroxyl functionality of at least 2 and wherein the polyol polymer chains are covalently cross-linked through hydroxyl groups; and (b) an electrochromic solution which comprises an anodic and a cathodic electrochromic compound interspersed in the polymer matrix.
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72. A variable reflectance mirror which comprises, as the variable transmittance element, an electrochromic device which comprises, as the medium of reversibly variable transmittance to light, an electrochromic layer of reversibly variable transmittance to light which comprises:
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(a) a polymer matrix of a polyol polymer which has an hydroxyl functionality of at least 2 and wherein the polyol polymer chains are covalently cross-linked through hydroxyl groups; and (b) an electrochromic solution which comprises an anodic and a cathodic electrochromic compound interspersed in the polymer matrix.
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73. An electrochromic layer of reversibly variable transmittance to light which comprises:
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(a) a polymer matrix of a polyol polymer which has an hydroxyl functionality of at least 2; and (b) an electrochromic solution which comprises at least one electrochromic compound interspersed in the polymer matrix. - View Dependent Claims (74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97, 98, 99, 100, 101, 102, 103, 104, 105, 106, 107, 108, 109, 110, 111, 112, 113, 114, 115)
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116. An electrochromic layer of reversibly variable transmittance to light which comprises:
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(a) a solvent (b) a polymer matrix, where the polymer matrix comprises a cross-linked polyol polymer having a hydroxyl functionality of at least 2 and where, prior to crosslinking, the polyol polymer is formed in the solvent by polymerization of a monomer; and (c) at least one electrochromic compound interspersed in the polymer matrix and the solvent. - View Dependent Claims (117, 118, 119, 120)
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Specification