Multiple stage suspended reactive stripping process and apparatus

• US 5,679,312 A
• Filed: 10/30/1995
• Issued: 10/21/1997
• Est. Priority Date: 02/17/1993
• Status: Expired due to Term

• Current Assignee: China Petrochemical Corporation, Tianjin University
• Original Assignee: China Petrochemical Corporation, Tianjin University
• Inventors: Yuan, Jitang, Jin, Shiyi, Lu, Huisheng, Zhang, Zongli, Yin, Jinzhu, Wang, Lianshun
• Primary Examiner(s): BHAT, NINA NMN
• Application Number:
  US08/505,311
• Time in Patent Office: 722 Days
• Field of Search: 422/189, 422/190, 422/191, 422/192, 422/194, 422/212, 202/158, 203/DIG. 6, 261/114.1, 568/727
• US Class Current: 422/605
• CPC Class Codes: B01D 3/009 in combination with chemical reactions
• CPC Class Codes: B01J 8/048 the beds being superimposed one above the other
• CPC Class Codes: C07C 37/20 using aldehydes or ketones
• CPC Class Codes: C07C 39/16 Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes
• CPC Class Codes: Y02P 20/10 Process efficiency
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials
• CPC Class Codes: Y10S 203/06 Reactor-distillation

Abstract

A reactive stripping process for continuously carrying out chemical reactions while separating the reactants from the reaction products is provided. The process comprises passing liquid reactants and an inert stripping gaseous stream in a reactor column (1) having a plurality of perforated trays (2) provided therein and interconnected by a plurality of downcomers (3), screens (4 and 5) provided on the trays (2) and the top openings of the downcomers (3). The trays (2) and downcomers (3) are associated with the screens (4 and 5) to form a chamber optionally provided with a solid particulate or liquid catalyst (6) therein. A reactive stripping apparatus for performing such a process is also provided. According to the invention, at least one reaction product and the reaction mixture having different boiling points can be separated in order that chemical reactions proceed continuously as desired.

Claims

1. A reactive stripping process for continuously carrying out chemical reactions while separating the reactants from at least one of the reaction products in a reactor column, the process comprising:

(a) allowing liquid reactants to flow concurrently and downwardly in a reactor column having a side wall and having;

(i) a plurality of perforated trays provided therein, and

(ii) a plurality of downcomers interconnecting the trays, a portion of each said downcomer, a portion of the side wall of the reactor column and one of the perforated trays in combination defining a chamber with a catalyst contained therein in order to form a liquid reaction mixture including at least a lower boiling reaction product, said reactor column additionally having, when the catalyst is other than a liquid catalyst, a first screen located on each tray and each of the downcomers having a second screen connected to the top thereof,

(b) simultaneously allowing a nitrogen stream to pass upwardly through the trays and chambers for agitating the content of the chambers, wherein, when the catalyst is other than a liquid catalyst, a suspension of the catalyst is formed in the liquid reaction mixture,

(c) withdrawing at least the lower boiling reaction product from an upper portion of the reactor column with the nitrogen stream, and

(d) discharging the remainder of the reaction mixture from a lower portion of the reactor column.

2. A reactive stripping process according to claim 1 wherein the catalyst is a solid particulate catalyst.

3. A reactive stripping process according to claim 1 wherein the catalyst is a liquid catalyst.

4. A reactive stripping process according to claim 1 wherein the velocity of the rising nitrogen stream is in the range of from about 0.006 to about 0.075 m/s.

5. A reactive stripping process according to claim 1 wherein liquid reactants are introduced into the reactor column through several inlets.

6. A reactive stripping process according to claim 1 wherein at least one reactant is introduced into the reactor column through several inlets provided at different heights of the column above the lowermost tray.

7. A reactive stripping process according to claim 1 wherein the nitrogen stream which is the entrained substance has been removed from the upper portion of the reactor column with at least the lower boiling reaction product is purified and is recycled to the bottom of the reactor column.

8. A reactive stripping apparatus for continuously carrying out chemical reactions while separating at least a lower boiling reaction product form a reaction mixture, the apparatus comprising:

(a) a reactor column having a lower portion and an upper portion with a top,

(b) a plurality of perforated trays provided in the reactor column, the porosity of the trays being from about 5 to about 50%,

(c) a plurality of downcomers interconnecting the trays, the length of each downcomer above the tray associated therewith being from about 1/2 to about 3/4 of the height between the tray associated therewith and the adjacent tray which is positioned above the downcomer, a portion of each said downcomer, the tray associated therewith and a portion of the side wall of the reactor column, in combiantion defining a chamber,

(d) inlets in the upper portion and along the side wall of the reactor column above the lower most tray for the introduction of liquid reactants,

(e) an inlet and an outlet located in the lower portion of the reactor column for introducing a nitrogen stream and discharging the reaction mixture, respectively, and

(f) an outlet at the top of the reactor column for withdrawing the nitrogen stream with at least one lower boiling reaction product from the reaction mixture.

9. A reactive stripping apparatus according to claim 8 wherein the column trays are sieve trays or float valve trays.

10. A reactive stripping apparatus according to claim 8 wherein each chamber contains solid catalyst particles and the trays have screens placed thereon with a mesh which is smaller than the particle size of the catalyst particles.

11. A reactive stripping apparatus according to claim 8 wherein the apparatus contains catalyst particles and the catalyst load for each tray provided in the reactor column is in the range of from about 3% to about 30% by volume of the total volume of the whole mixture including the catalyst and reaction liquid.

12. A reactive stripping apparatus according to claim 8 wherein the porosity of the perforated trays is from about 10% to about 30%.

13. A reactive stripping apparatus according to claim 8 wherein the screens on the trays are of the same type as the screens connected to the top of the downcomers.

14. A reactive stripping apparatus according to claim 8 wherein a catalyst is contained in the chambers.

15. A reactive stripping apparatus according to claim 14 wherein a first screen is located on each tray and a second screen is connected to the top of each downcomer when the catalyst is other than a liquid catalyst.

16. A reactive stripping apparatus according to claim 8, wherein the reactor column includes a first screen located on each tray and a second screen connected to the top of each of the downcomers, the second screen, a portion of each said downcomer, a portion of the side all of the reactor column and one of the perforated trays with the first screen thereon in combination defining the chamber.

17. A reactive stripping apparatus according to claim 16, wherein the chamber contains a solid particulate catalyst.

18. A reactive stripping process for the production of a reaction mixture having a high bisphenol-A concentration by reacting excess phenol with acetone in the presence of catalyst wherein from about 4 to about 12 times molar excess of phenol is reacted with acetone in the presence of a modified cation-exchange resin catalyst in the form of a particulate solid in a substantially vertical, multiple stage suspended reactive stripping apparatus comprising a reactor column with a side wall, the reactor column having:

(i) a plurality of perforated trays provided therein,

(ii) a first screen located on each tray,

(iii) a plurality of downcomers interconnecting the trays, each of the downcomers having a second screen connected to the top thereof, the second screen, a portion of each said downcomer, a portion of the side wall of the reactor column and one of the perforated trays with the first screen thereon in combination defining a catalyst chamber, and

(iv) a solid particulate catalyst contained within the catalyst chamber, the reactive stripping process taking place at a temperature in the range of from about 60°

C. to about 130°

C. in which process all of the phenol necessary for the condensation reaction thereof with acetone is charged to the reactor column from above the uppermost tray, portions of all the required acetone are charged to the tray next to the upper most tray and some of all of lower trays and a nitrogen stream is upwardly passed through the catalyst chambers to form solid-liquid suspensions and to strip water from the reaction mixture.