Hose for fuel handling systems

• US 5,679,425 A
• Filed: 05/06/1996
• Issued: 10/21/1997
• Est. Priority Date: 11/23/1994
• Status: Expired due to Fees

• Current Assignee: Dana Corporation (Dana, Inc.)
• Original Assignee: Plumley Companies, Inc. (Dana, Inc.)
• Inventors: Plumley, Stephen
• Primary Examiner(s): CHOI, KATHLEEN L
• Application Number:
  US08/643,402
• Time in Patent Office: 533 Days
• Field of Search: 428/35.7, 428/36.1, 428/36.8, 428/36.91, 428/421, 138/126, 138/137, 138/141
• US Class Current: 428/35.7
• CPC Class Codes: B32B 1/08 Tubular products
• CPC Class Codes: B32B 2307/306 Resistant to heat
• CPC Class Codes: B32B 25/10 next to a fibrous or filamentary layer
• CPC Class Codes: B32B 2605/00 Vehicles
• CPC Class Codes: B32B 27/12 next to a fibrous or filamentary layer
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: F16L 11/081 comprising one or more layers of a helically wound cord or wire in combination with braided layers F16L11/088
• CPC Class Codes: F16L 11/12 with arrangements for particular purposes, e.g. specially profiled, with protecting layer, heated, electrically conducting F16L11/11 takes precedence
• CPC Class Codes: F16L 2011/047 with a diffusion barrier layer
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/1362 Textile, fabric, cloth, or pile containing [e.g., web, net, woven, knitted, mesh, nonwoven, matted, etc.]
• CPC Class Codes: Y10T 428/1386 Natural or synthetic rubber or rubber-like compound containing
• CPC Class Codes: Y10T 428/1393 Multilayer [continuous layer]
• CPC Class Codes: Y10T 428/3154 Of fluorinated addition polymer from unsaturated monomers

Abstract

A laminated hose is present which is suitable for a fuel conducting hose or other hose, or diaphragm, used for example in an automotive vehicle, which structure is required to have excellent heat resistance and gasoline permeation resistance while maintaining suitable properties of bonding and flexibility. The hose is constituted by an inner veneer layer of THV, a terpolymer of tetrafluoroethylene, hexafluoropropylene and vinylidene fluoride, as a permeation barrier layer. This inner layer is reinforced by an elastomeric tie layer, a reinforcing layer and an elastomeric cover.

Claims

1. A hose for containing a fuel, comprising:

a thermoplastic inner layer which is resistant to permeation of hydrocarbon fuels, said thermoplastic inner layer being formed of a terpolymer comprising tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride;

a tie layer bonded to said inner layer;

a tubular reinforcing layer of a fibrous material covering said tie layer;

a tubular protective layer of a synthetic rubber intimately covering said reinforcing layer; and

a bonding chemistry bonding said inner layer to said tie layer, said bonding chemistry comprising a cyanate compound, an epoxy and a complex decene compound.

2. The hose according to claim 1, wherein said tie layer defines an elastomer copolymerized with a polar comonomer.

3. The hose according to claim 1, wherein said terpolymer comprises a mole percent of approximately 60% tetrafluoroethylene, 20% hexafluoropropylene, and 20% vinylidene fluoride.

4. The hose according to claim 1, wherein adhesion of said tie layer to said inner layer is enhanced by a peroxide vulcanization system comprising an organic peroxide.

5. The hose according to claim 4, wherein said organic peroxide is 2,5-Dimethyl-2,5-bis(t-butylperoxy)hexane.

6. The hose according to claim 1, wherein said cyanate compound is triallyl isocyanurate.

7. The hose according to claim 1, wherein said complex decene compound is 1,8-Diazabicyclo 5,4,0!undec-7-ene, 98%.

8. The hose according to claim 1, wherein said tubular reinforcing layer comprises braided synthetic fibers, and said tubular protective layer defines a seamless protective covering.

9. A laminated extruded material for containing a fuel, comprising:

a thermoplastic inner layer formed of a terpolymer comprising tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride;

a tie layer bonded to said inner layer;

a protective covering layer comprising an organic rubber covering said tie layer;

and wherein a bonding chemistry bonds said inner layer to said tie layer, said bonding chemistry comprising a cyanate compound, an epoxy and a complex decene compound.

10. The laminated extruded material according to claim 9, wherein said inner layer comprises a mole percent of approximately 60% tetrafluoroethylene, 20% hexafluoropropylene, and 20% vinylidene fluoride.

11. The laminated extruded material according to claim 9, wherein said inner layer has a thickness ranging from about 0.01" to 0.015".

12. The laminated extruded material according to claim 9, wherein said protective covering layer comprises:

a tubular reinforcing layer of a heat resistant fibrous material covering said tie layer; and

a tubular protective layer of a synthetic rubber intimately covering said reinforcing layer.

13. The laminated extruded material according to claim 9, where said bonding chemistry further comprises a peroxide vulcanization system comprising an organic peroxide.

14. The laminated extruded material according to claim 13, wherein said organic peroxide is 2,5-Dimethyl-2,5-bis(t-butylperoxy)hexane.

15. The laminated extruded material according to claim 9, wherein said cyanate compound is triallyl isocyanurate.

16. The laminated extruded material according to claim 9, wherein said complex decene compound is 1,8-Diazabicyclo(5,4,0)undec-7-ene, 98%.

17. The laminated extruded material according to claim 9, wherein said epoxy is chloromethyl oxirane.