Curable coating composition for sheet goods

• US 5,679,721 A
• Filed: 02/27/1995
• Issued: 10/21/1997
• Est. Priority Date: 02/27/1995
• Status: Expired due to Term

• Current Assignee: Tarkett Incorporated (Tarkett Holding GmbH)
• Original Assignee: Domco Industries, Inc.
• Inventors: Charest, Claude, Courtoy, Jean-Fran.cedilla.ois
• Primary Examiner(s): Michl, Paul R.
• Assistant Examiner(s): RAJGURU, UMAKANT K
• Application Number:
  US08/394,483
• Time in Patent Office: 967 Days
• Field of Search: 522/95, 522/96, 522/120, 522/121, 525/278, 525/305
• US Class Current: 522/95
• CPC Class Codes: C08F 220/10 Esters
• CPC Class Codes: C08F 222/1063 of alcohol terminated polyethers
• CPC Class Codes: C08F 255/00 Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
• CPC Class Codes: C08F 290/147 Polyurethanes; Polyureas
• CPC Class Codes: C08L 27/04 containing chlorine atoms
• CPC Class Codes: C09D 175/16 having terminal carbon-to-carbon unsaturated bonds
• CPC Class Codes: C09D 4/00 Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
• CPC Class Codes: C09D 4/06 Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
• CPC Class Codes: Y10T 428/269 including synthetic resin or polymer layer or component
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers

Abstract

A radiation-curable coating composition comprising a PVC resin, an acrylic or methacrylic compound and a radiation-reactive urethane oligomer. Also described is a process for coating a material, comprising the steps of applying to the material a coating composition according to the invention, heating to heart-cure the coating composition and irradiating the composition to radiation-cure the coating composition. There is also provided an article comprising a material coated with the composition according to the invention. The invention is particularly useful for coating resilient vinyl flooring materials.

Claims

1. A radiation-curable coating composition comprising a PVC resin, an acrylic or methacrylic compound and a radiation-reactive urethane oligomer, said composition being substantially or completely free from internal or external plasticizers.

2. A composition according to claim 1 wherein the radiation-reactive urethane oligomer comprises an acrylic or methacrylic moiety attached to a urethane prepolymer.

3. A composition according to claim 2 wherein the radiation-reactive urethane oligomer is based on an aliphatic polycarbonate polyol.

4. A coating composition according to claim 1, which composition comprises from 35 to 140 parts by weight of a PVC emulsion resin with a relative viscosity between 2.05 and 3.40, from 30 to 80 parts by weight of an acrylic or methacrylic compound, from 0.5 to 65 parts by weight of a radiation-reactive urethane oligomer, from 0.5 to 10 parts by weight of a heat stabilizer and from 0.1 to 10 parts by weight of a photoinitiator.

5. A coating composition according to claim 1, which composition comprises from 75 to 140 parts by weight of a PVC suspension resin with a relative viscosity between 1.56 and 2.52, from 35 to 80 parts by weight of an acrylic or methacrylic compound, from 0.5 to 65 parts by weight of a radiation-reactive urethane oligomer, from 0.5 to 10 parts by weight of a heat stabilizer and from 0.25 to 15 parts by weight of a photoinitiator.

6. A coating composition according to claim 1, further comprising a photoinitiator.

7. A coating composition according to claim 1, further comprising a heat stabilizer selected from the group consisting of compounds of alkaline earth metals and transition metals.

8. A coating composition according to claim 1, wherein said PVC resin is a PVC emulsion resin having a relative viscosity between 2.05 and 3.40.

9. A coating composition according to claim 1, wherein said PVC resin is a PVC suspension resin having a relative viscosity between 1.56 and 2.52.

10. A radiation-curable coating composition comprising a PVC resin, an acrylic or methacrylic compound and a radiation-reactive urethane oligomer, said composition being substantially or completely free from internal or external plasticizers and being substantially or completely free from solvent.

11. A composition according to claim 10 wherein said radiation-reactive urethane oligomer comprises an acrylic or methacrylic moiety attached to a urethane prepolymer.

12. A composition according to claim 11 wherein said radiation-reactive urethane oligomer is based on an aliphatic polycarbonate polyol.

13. A coating composition according to claim 10, further comprising a photoinitiator.

14. A coating composition according to claim 10, further comprising a heat stabilizer selected from the group consisting of compounds of alkaline earth metals and transition metals.

15. A coating composition according to claim 10, wherein said PVC resin is a PVC emulsion resin having a relative viscosity between 2.05 and 3.40.

16. A coating composition according to claim 15, comprising from 35 to 140 parts by weight of said PVC emulsion resin, from 30 to 80 parts by weight of said acrylic or methacrylic compound, from 0.5 to 65 parts by weight of said radiation-reactive urethane oligomer, from 0.5 to 10 parts by weight of a heat stabilizer and from 0.1 to 10 parts by weight of a photoinitiator.

17. A coating composition according to claim 10, wherein said PVC resin is a PVC suspension resin that has a relative viscosity between 1.56 and 2.52.

18. A coating composition according to claim 17, comprising from 75 to 140 parts by weight of said PVC suspension resin, from 35 to 80 parts by weight of said acrylic or methacrylic compound, from 0.5 to 65 parts by weight of said radiation-reactive urethane oligomer, from 0.5 to 10 parts by weight of a heat stabilizer and from 0.25 to 15 parts by weight of a photoinitiator.