Optical information recording medium

• US 5,681,632 A
• Filed: 02/08/1996
• Issued: 10/28/1997
• Est. Priority Date: 02/13/1995
• Status: Expired due to Fees

• Current Assignee: Matsushita Electric Industrial Company Limited (Panasonic Holdings Corporation)
• Original Assignee: Matsushita Electric Industrial Company Limited (Panasonic Holdings Corporation)
• Inventors: Yamada, Noboru, Akiyama, Tetsuya, Kitaura, Hideki, Nagata, Ken'ichi, Ohta, Takeo, Kawahara, Katsumi
• Primary Examiner(s): MULVANEY, ELIZABETH EVANS
• Application Number:
  US08/598,749
• Time in Patent Office: 628 Days
• Field of Search: 428/64.1, 428/64.2, 428/64.3, 428/64.4, 428/64.5, 428/64.6, 428/457, 428/913, 369/283, 369/288, 430/270.1, 430/270.11, 430/270.12, 430/270.13, 430/495.1, 430/945
• US Class Current: 428/64.1
• CPC Class Codes: G11B 2007/24312 group 14 elements (e.g. Si, Ge, Sn)
• CPC Class Codes: G11B 2007/24314 group 15 elements (e.g. Sb, Bi)
• CPC Class Codes: G11B 2007/24316 group 16 elements (i.e. chalcogenides, Se, Te)
• CPC Class Codes: G11B 2007/25706 containing transition metal elements (Zn, Fe, Co, Ni, Pt)
• CPC Class Codes: G11B 2007/25708 containing group 13 elements (B, Al, Ga)
• CPC Class Codes: G11B 2007/2571 containing group 14 elements except carbon (Si, Ge, Sn, Pb)
• CPC Class Codes: G11B 2007/25711 containing carbon
• CPC Class Codes: G11B 2007/25713 containing nitrogen
• CPC Class Codes: G11B 2007/25715 containing oxygen
• CPC Class Codes: G11B 2007/25716 containing sulfur
• CPC Class Codes: G11B 2007/25718 containing halides (F, Cl, Br, l)
• CPC Class Codes: G11B 7/0052 involving reflectivity, absorption or colour changes
• CPC Class Codes: G11B 7/2403 Layers; Shape, structure or physical properties thereof
• CPC Class Codes: G11B 7/252 of layers other than recording layers
• CPC Class Codes: G11B 7/2531 comprising glass
• CPC Class Codes: G11B 7/2533 comprising resins
• CPC Class Codes: G11B 7/2534 polycarbonates [PC]
• CPC Class Codes: G11B 7/2578 consisting essentially of inorganic materials
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10S 430/146 Laser beam
• CPC Class Codes: Y10T 428/21 : Circular sheet or circular blank

Abstract

On a substrate, a recording layer which reversibly transforms between two states with different optical properties--a crystalline phase and an amorphous phase--by the irradiation of a laser beam, a first and a second dielectric layer on the bottom and the top surfaces of the recording layer, and a third dielectric layer on one surface of the first or the second dielectric layers and on the opposite side with respect to the recording layer are successively laminated, thus preparing an optical information recording medium. The third dielectric layer has a smaller coefficient of thermal expansion than the first and the second dielectric layers, so that the thermal deformation of the first and the second dielectric layers is reduced and the mass transfer of the recording layer is controlled. As a result, the overwrite cycle characteristics of the optical information recording medium are excellent.

Claims

1. An optical information recording medium comprising on a substrate:

a recording layer which reversibly transforms between optically detectable crystalline and amorphous states by the irradiation of a laser beam; and

a first dielectric layer and a second dielectric layer formed on a bottom and a top surface of said recording layer;

said optical information recording medium further comprising a third dielectric layer on an outside surface of at least one layer selected from the group consisting of said first dielectric layer and second dielectric layer;

said third dielectric layer having a coefficient of thermal expansion smaller than coefficients of thermal expansion of said first dielectric layer and said second dielectric layer; and

wherein said optical information recording medium comprises no metallic reflection layer, wherein

a difference of reflectances (Δ

R=Rcry-Ramo) is 15% or more where Rcry is a reflectance of the light beam reflected by said recording layer which is in a crystalline state, and Ramo is the reflectance of said recording layer in an amorphous state; and

wherein a difference of absorptivities (Δ

A=Acry-Aamo) is 5% or more where Acry is an absorption coefficient of the light beam absorbed by said recording layer which is in the crystalline state, and Aamo is the absorption coefficient of said recording layer in the amorphous state.

2. The optical information recording medium according to claim 1, wherein the third dielectric layer has a thermal expansion coefficient less than 2.0×

10^-6 K^-1.

3. The optical information recording medium according to claim 1, wherein the third dielectric layer comprises at least one inorganic oxide selected from the group consisting of SiO₂, Ta₂ O₅, and Nb₂ O₅ as main components.

4. The optical information recording medium according to claim 3, wherein the main components of the third dielectric layer at 70-100 mol% and at least one atom selected from the group consisting of N, S, C, F, H add to the third dielectric layer as a sub-component at 0-30 mol %.

5. The optical information recording medium according to claim 1, wherein the third dielectric layer is 10-400 nm thick.

6. The optical information recording medium according to claim 1, wherein the recording layer is 2-300 nm thick.

7. The optical information recording medium according to claim 1, wherein the first dielectric layer is 2-300 nm thick.

8. The optical information recording medium according to claim 1, wherein the second dielectric layer is 2-300 nm thick.

9. The optical information recording medium according to claim 1, wherein the first dielectric layer and the second dielectric layer have a thermal expansion coefficient from 1.0×

10^-6 K^-1 to 30.0×

10^-6 K^-1.

10. The optical information recording medium according to claim 1, wherein the first dielectric layer and the second dielectric layer comprise at least one inorganic material selected from the group consisting of Al₂ O₃, ZrO₂, TiO₂, AlN, Si₃ N₄, TiN, SiC, ZnS, PbS, ZnSe and CaF₂ as main components.

11. The optical information recording medium according to claim 1, wherein the first dielectric layer and the second dielectric layer comprise at least one inorganic oxide selected from the group consisting of SiO₂, Ta₂ O₅ and Nb₂ O₅ at less than 30 mol % as sub-components.

12. The optical information recording medium according to claim 1, wherein the first dielectric layer and the second dielectric layer comprise ZnS at 70-100 mol % and SiO₂ at 30-0 mol %.

13. The optical information recording medium according to claim 1, wherein the recording layer comprises a chalcogen compound selected from the group consisting of Ge-Sb-Te, Ge-Sb-Te-Pd, Ge-Sb-Te-Bi, Ge-Sb-Te-Se, Ge-Te, Ge-Te-Bi, Ge-Te-Sn, Ge-Te-Bi-Se, Ge-Te-Sn-Au, Sb-Te, In-Sb-Te, Ag-In-Sb-Te and In-Se, or said chalcogen compound added with at least one element selected from the group consisting of nitrogen, oxygen, sulphur, carbon, fluorine and hydrogen.

14. The optical information recording medium according to claim 1, wherein the recording layer comprises a Ge-Sb-Te type chalcogen compound, or said chalcogen compound to which is added at least one element selected from the group consisting of nitrogen, oxygen, sulphur, carbon, fluorine and hydrogen.

15. The optical information recording medium according to claim 1, wherein the substrate comprises at least one material selected from the group consisting of polycarbonate resin, polymethylmethacrylate resin, polyolefin resin and glass.

16. The optical information recording medium according to claim 1, wherein said third dielectric layer having a reflectance smaller than said first dielectric layer and said second dielectric layer.

17. The optical information recording medium according to claim 1, wherein the third dielectric layer has 1.2-1.8 reflectance (n).

18. The optical information recording medium according to claim 1, wherein the reflectance of the optical information recording medium measured from the side of the substrate before and after a process of recording information is less than 50%.

19. The optical information recording medium according to claim 18, wherein the reflectance measured from the side of the substrate before and after a process of recording information is less than 30%.