Bitetrazoleamine gas generant compositions

• US 5,682,014 A
• Filed: 08/02/1993
• Issued: 10/28/1997
• Est. Priority Date: 08/02/1993
• Status: Expired due to Term

• Current Assignee: Northrop Grumman Innovation Systems, Inc. (Northrop Grumman Corporation)
• Original Assignee: Thiokol Corporation (Howmet Aerospace, Inc.)
• Inventors: Lund, Gary K., Blau, Reed J., Highsmith, Thomas K.
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US08/101,396
• Time in Patent Office: 1,548 Days
• Field of Search: 149/36, 149/37, 149/109.2, 149/61, 149/77, 149/46, 149/76, 149/18
• US Class Current: 149/36
• CPC Class Codes: C06B 21/0066 by granulation, e.g. flaking
• CPC Class Codes: C06B 43/00 Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

A solid composition for generating a nitrogen containing gas is provided. The composition includes an oxidizer and a non-azide fuel selected from a bitetrazoleamine or a derivative or a salt or complex thereof and mixtures thereof. The preferred bitetrazole-amine is bis-(1(2)H-tetrazol-5-yl)-amine, a metal salt, a salt with a nonmetallic cation of a high nitrogen content base or a complex thereof. The salts and complexes are generally metal salts and complexes. The metal can be a transition metal. Metals that have been found to be particularly useful include copper, boron, cobalt, zinc, potassium, sodium, and strontium. The oxidizer is generally a metal oxide or a metal hydroxide. The composition can include certain other components such as secondary oxidizers, burn rate modifiers, slag formers, and binders.

Claims

1. A solid gas generating composition comprising a fuel and an oxidizer therefor, said fuel comprising a bitetrazoleamine or a salt or complex thereof, having the formula ##STR4## wherein X, R₁ and R₂, each independently, represent hydrogen, methyl, ethyl, cyano, nitro, amino, tetrazolyl, a metal from Group Ia, Ib, IIa, IIb, IlIa, IVb, VIb, VIIb or VIII of the Periodic Table (Merck Index (9th Edition 1976)), or a nonmetallic cation of a high nitrogen-content base, and said oxidizer consisting essentially of metal oxides, metal hydroxides, or mixtures thereof.

2. The solid gas generating composition according to claim 1 wherein R₁, R₂, and X are hydrogen.

3. The solid gas generating composition according to claim 1 wherein X, R₁, or R₂, is selected from the group consisting of ammonium, hydroxylammonium, hydrazinium, guanidinium, aminoguanidinium, diaminoguanidinium, triaminoguanidinium, and biguanidinium.

4. The solid gas generating composition according to claim 1 wherein at least one of X, R₁, and R₂ is a metal.

5. The solid gas generating composition according to claim 4 wherein said metal is a transition metal.

6. The solid gas generating composition according to claim 4 wherein said metal is selected from the group consisting of cobalt, copper, iron, potassium, sodium, strontium, magnesium, calcium, boron, aluminum, titanium and zinc.

7. The solid gas generating composition according to claim 1 wherein said bitetrazoleamine is bis(1(2)H-tetrazol-5-yl)-amine.

8. The solid gas generating composition according to claim 1 wherein said oxidizer is a transition metal oxide or a transition metal hydroxide.

9. The solid gas generating composition according to claim 1 wherein said oxidizer is an oxide or hydroxide of a metal selected from the group consisting of copper, molybdenum, bismuth, cobalt and iron.

10. Th&

solid gas generating composition according to claim 1 which also includes a secondary oxidizer selected from the group consisting of a metal nitrate, a metal nitrite, a metal peroxide, a metal carbonate, a metal chlorate, a metal perchlorate, ammonium nitrate, and ammonium perchlorate.

30. The solid gas generating composition according to claim 1 wherein the bitetrazoleamine is present in an amount ranging from about 10 to about 50 weight percent thereof.

31. The solid gas generating composition according to claim 1 wherein the nonmetallic cation is an ammonium, hydroxyl ammonium, hydrazinium, guanidinium, aminoguanidinium, diaminoguanidinium, triaminoguanidinium, or biguanidinium cation.

11. The solid gas generating composition comprising a fuel selected from the group consisting of bis-(1(2)H-tetrazol-5-yl)-amine, a salt thereof, a complex thereof, and a mixture thereof, and an oxidizer, said oxidizer consisting essentially of at least the of a metal oxide and a metal hydroxide.

12. The solid gas generating composition according to claim 11 wherein said metal oxide or said metal hydroxide is a transition metal oxide or a transition metal hydroxide.

13. The solid gas generating composition according to claim 11 wherein said oxidizer is an oxide or hydroxide of a metal selected from the group consisting of copper, molybdenum, bismuth, cobalt and iron.

14. The solid gas generating composition according to claim 11 wherein said fuel is present in an amount ranging from about 10 to about 40 percent by weight, and said oxidizer is present in an amount ranging from about 90 to about 60 percent by weight.

15. The solid gas generating composition according to claim 11 wherein said salt or complex of bis-(1(2)H-tetrazol-5-yl)-amine is a transition metal salt or complex thereof.

16. The solid gas generating composition according to claim 11 wherein said salt or complex of bis-(1(2)H-tetrazol-5-yl)-amine is a salt or complex of a metal selected from the group consisting of iron, boron, copper, cobalt, zinc, potassium, sodium, strontium, and titanium.

17. The solid gas generating composition according to claim 11 which also includes a burn rate modifier.

18. The solid gas generating composition according to claim 14 which also includes a binder.

19. The solid gas generating composition according to claim 14 which also includes a slag forming agent.

34. The solid gas generating composition according to claim 11, which also includes a secondary oxidizer selected from the group consisting of metal nitrates, metal nitrites, metal peroxides, metal carbonates, metal chlorates, metal perchlorates, ammonium nitrate, and ammonium perchlorate.

20. An automobile air bag system comprising:

a collapsed, inflatable air bag; and

a gas generating device connected to said air bag for inflating said air bag, said gas generating device containing a gas generating composition comprising a fuel and an oxidizer therefor, said fuel comprising a bitetrazoleamine or a salt or complex thereof, having the formula ##STR5## wherein X, R₁ and R₂, each independently, represent hydrogen, methyl, ethyl, cyano, nitro, amino, tetrazolyl, a metal from Group Ia, Ib, IIa, lIb, IIIa, IVb, VIb, VIIb or VIII of the Periodic Table (Merck Index (9th Edition

     1976)), or a nonmetallic cation of a high nitrogen-content base; and

said oxidizer consisting essentially of metal oxides, metal hydroxides, or mixtures thereof.

21. The automobile air bag system according to claim 20 where R₁, R₂, and X are hydrogen.

22. The automobile air bag system according to claim 20 wherein at least one of X, R₁, and R₂ is a metal.

23. The automobile air bag system according to claim 22 wherein said metal is a transition metal.

24. The automobile air bag system according to claim 22 wherein said metal is selected from the group consisting of iron, copper, cobalt, zinc, potassium, sodium, strontium, and titanium.

25. The automobile air bag system according to claim 22 wherein X, R₁, or R₂, is selected from the group consisting of ammonium, hydroxylammonium, hydrazinium, guanidinium, aminoguanidinium, diaminoguanidinium, triaminoguanidinium, and biguanidinium.

26. The automobile air bag system according to claim 20 wherein said fuel is bis-(1(2)H-tetrazol-5-yl)-amine and is present in said gas generating composition in an amount ranging from about 10 to about 50 percent by weight of said gas generating composition.

27. The automobile air bag system according to claim 20 wherein said metal oxide or said metal hydroxide is a transition metal oxide or a transition metal hydroxide.

28. The automobile air bag system according to claim 27 wherein said oxidizer is an oxide or hydroxide of a metal selected from the group consisting of copper, molybdenum, bismuth, cobalt and iron.

29. The automobile air bag system according to claim 20 wherein said gas generating composition also includes a secondary oxidizer selected from the group consisting of a metal nitrate, a metal nitrite, a metal peroxide, a metal carbonate, a metal chlorate, a metal perchlorate, ammonium nitrate, and ammonium perchlorate.

32. An automobile air bag system according to claim 20 wherein the nonmetallic cation is an ammonium, hydroxyl ammonium, hydrazinium, guanidinium, aminoguanidinium, diaminoguanidinium, triaminoguanidinium, or biguanidinium cation.

33. A vehicle containing a supplemental restraint system having an air bag system comprising:

a collapsed inflatable air bag and a gas generating device connected to said air bag for inflating said air bag, said gas generating device containing a solid gas generating composition comprising a fuel and an oxidizer therefor, said fuel comprising a bitetrazoleamine or a salt or complex thereof, having the formula ##STR6## wherein X, R₁ and R₂, each independently, represent hydrogen, methyl, ethyl, cyano, nitro, amino, tetrazolyl, a metal from Group Ia, Ib, IIa, IIb;

IIIa, IVb;

VIb, VIIb or VIII of the Periodic Table (Merck Index (9th Edition

     1976)), or a nonmetallic cation of a high nitrogen-content base, and said oxidizer consisting essentially of metal oxides, metal hydroxides, or mixtures thereof.