Metal platelet fuel cells production and operation methods

• US 5,683,828 A
• Filed: 10/31/1995
• Issued: 11/04/1997
• Est. Priority Date: 10/12/1994
• Status: Expired due to Fees

• Current Assignee: H Power Corporation (Plug Power Inc.)
• Original Assignee: H Power Corporation (Plug Power Inc.)
• Inventors: Spear, Reginald G., Hodge, Rex, Mueggenburg, H. Harry
• Primary Examiner(s): SKAPARS, ANTHONY
• Application Number:
  US08/551,071
• Time in Patent Office: 735 Days
• Field of Search: 429/12, 429/13, 429/17, 429/26, 429/15, 29/623.1, 29/623.4, 29/623.5, 427/115
• US Class Current: 429/414
• CPC Class Codes: F28D 9/0075 the plates having openings therein for circulation of the heat-exchange medium from one conduit to another
• CPC Class Codes: F28F 2250/102 with change of flow direction
• CPC Class Codes: F28F 2260/02 having microchannels
• CPC Class Codes: F28F 3/04 the means being integral with the element
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 8/0206 Metals or alloys
• CPC Class Codes: H01M 8/021 Alloys based on iron
• CPC Class Codes: H01M 8/0228 in the form of layered or coated products
• CPC Class Codes: H01M 8/0245 in the form of layered or coated products
• CPC Class Codes: H01M 8/0247 characterised by the form characterised by a channel configuration H01M8/0258
• CPC Class Codes: H01M 8/026 characterised by grooves, e.g. their pitch or depth
• CPC Class Codes: H01M 8/0263 having meandering or serpentine paths
• CPC Class Codes: H01M 8/0267 having heating or cooling means, e.g. heaters or coolant flow channels
• CPC Class Codes: H01M 8/04029 Heat exchange using liquids
• CPC Class Codes: H01M 8/04074 Heat exchange unit structures specially adapted for fuel cell
• CPC Class Codes: H01M 8/04119 with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
• CPC Class Codes: H01M 8/2483 characterised by internal manifolds
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y02P 80/10 Efficient use of energy, e.g. using compressed air or pressurized fluid as energy carrier
• CPC Class Codes: Y10T 29/49115 : including coating or impregnating

Abstract

Fuel cell stacks comprising stacked separator/membrane electrode assembly cells in which the separators comprise a series of stacked thin sheet platelets having individually configured serpentine micro-channel reactant gas humidification, active area and cooling fields therein. The individual platelets are stacked with coordinate features precisely aligned in contact with adjacent platelets and bonded to form a monolithic separator. Post bonding processing includes passivation, such as nitriding. Preferred platelet material is 4-25 mil Ti in which the features, serpentine channels, tabs, lands, vias, manifolds and holes, are formed by chemical or laser etching, cutting, pressing or embossing, with combinations of depth and through-etching being preferred. The platelet manufacturing process is continuous and fast. By employing CAD based platelet design and photolithography, rapid change in feature design to accommodate a wide range of thermal management and humidification techniques. 100 cell H₂ -O₂ /Air PEM fuel cell stacks of this IFMT platelet design will exhibit outputs on the order of 0.75 kW/kg, some 3-6 times greater than current graphite plate PEM stacks.

Claims

1. A method for producing fuel cell separator assemblies comprising the steps of:

a) forming in thin sheet stock a plurality of different individual platelets with coordinate features selected from micro-channels, vias and manifolds, said features together forming at least one active area field for oxidant or fuel consumption in contact with a membrane electrode assembly;

b) stacking said platelets with said individual platelet features in precise alignment with corresponding features of a matingly adjacent platelet to provide continuous circulation paths for said oxidant or fuel; and

c) bonding said aligned platelets to form a monolithic separator having internal microchannels and access manifolds thereto.

2. A method as in claim 1 wherein said sheet stock is metal and said forming step includes the step of etch forming said features by a combination of depth etching and through etching.

3. A method as in claim 2 wherein said through etching comprises depth etching selected areas from both sides of said sheet stock to depths greater than 50% of the sheet thickness.

4. A method as in claim 3 wherein said metal is selected from Ti, Al, Cu, W, Niobium, stainless steel, and alloys, laminates, platings and composites thereof.

5. A method as in claim 2 wherein said forming step includes resist coating said sheet metal platelets to define features thereon.

6. A method as in claim 2 which includes the step of passivating said separator after bonding.

7. A method as in claim 6 wherein said bonding includes diffusion bonding under heat and pressure, said metal is Ti, and said passivating includes exposure to Nitrogen at an elevated temperature.

8. A method as in claim 5 wherein said resist coating is applied by at least one of direct transfer or photolithographic processing.

17. Method of integrated fluid management (IFM) operation of a fuel cell comprising:

a) providing a fuel cell stack comprising plurality of aligned fuel cell separators as in claim 1 having disposed between each separator an electrode membrane assembly having at least one catalytically active zone where fuel and oxidant electrochemical reaction occur;

b) providing fuel and oxidant to said stack;

c) controlling the flow of fuel, oxidant and the removal of heat at rates integrated to substantially eliminate thermal hot spots while maintaining a substantially uniform preselected temperature throughout said stack.

18. An IFM fuel cell operation method as in claim 17 wherein:

a) said step of removal of the heat includes introduction of a coolant for cooling said stack.

19. An IFM fuel cell operation method as in claim 18 wherein:

a) said coolant includes water.

20. An IFM fuel cell operation method as in claim 19 wherein:

a) at least some of said water is routed to humidify at least one of said fuel or said oxidant.

21. An IFM fuel cell operation method as in claim 20 wherein:

a) at least some of said water is routed through microchannels in a first water zone of said stack on a first side of a water vapor permeable membrane, and at least one of said fuel or said oxidant is routed through microchannels in at least one humidification zone of said stack on the opposite side of said membrane corresponding to said first water zone;

b) osmotically pumping water vapor through said membranes to humidify at least one of said fuel or said oxidant in said humidification zone; and

c) controlling the humidity of said fuel or said oxidant to assist in maintaining the integrity of said electrode membrane assembly in the catalytically active electrochemical reaction zone.

22. An IFM fuel cell operation method as in claim 21 wherein:

a) at least some of said water is routed adjacent said catalytically active electrochemical reaction zone to control the temperature thereof before being muted to said humidification zone.

23. An IFM fuel cell operation method as in claim 22 wherein:

a) said water muted adjacent said catalytically active zone withdraws heat during electrochemical activity of said cell and exits therefrom at a temperature elevated above its inlet temperature; and

b) said elevated temperature water is muted to said humidification zone.

24. An IFM fuel cell operation method as in claim 23 wherein both said fuel and said oxidant are humidified by water of elevated temperature exiting from adjacent said catalytically active zone.

25. An IFM fuel cell operation method as in claim 24 wherein:

a) said fuel and oxidant are gases.

9. A method of designing fuel cell separator assemblies comprising the steps of:

a) developing a plurality of individual platelet drawings as plan views of platelet faces having features selected from at least one of metering orifices, channels, vias and manifolds to provide integrated fluid management of fuel, oxidant, humidification and temperature; and

b) generating photo-tooling masks artwork for said platelets faces from said platelet drawings so that said features are coordinated from platelet to platelet to form a functional separator upon properly aligned stacking of said platelets in proper sequence and bonding them together.

10. A method of fuel cell separator design as in claim 9 which includes the added step of:

a) applying an etch factor to compensate for undercutting to at least one selected feature on selected ones of said platelet drawings in generating said photo-tooling masks.

11. A method of fuel cell separator design as in claim 10 which includes the added step of:

a) generating an inspection database of critical dimensions for verification during mask creation and platelet manufacturing.

12. A method of fuel cell separator design as in claim 10 wherein:

a) said etch factor includes a value for at least one of the type of metal, type of chemical milling equipment, etch speed, type of etchant, strength of etchant or temperature of etchant.

13. A method of fuel cell separator design as in claim 9 which includes the added step of:

a) photoplotting platelet mask artwork on film.

14. A method of fuel cell separator design as in claim 13 wherein:

a) said plotting is at 1;

1 with respect to the size of the platelet.

15. A method of fuel cell separator design as in claim 10 wherein:

a) said etch factor includes a value for at least one of the type of metal, type of chemical milling equipment, etch speed, type of etchant, strength of etchant or temperature of etchant.

16. A method of fuel cell separator design as in claim 15 which includes the added step of:

a) photoplotting platelet mask artwork on film.